Metal-free electrophilic phosphination of electron-rich arenes, arenols and aromatic thiols with diarylphosphine oxides

Metal-Free Electrophilic Phosphination/Cyclization of Alkynes

(2017) Yuto Unoh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(i)/Fe(iii)-Catalyzed C–P cross-coupling of styrenes with H-phosphine oxides: a facile and selective synthesis of alkenylphosphine oxides and β-ketophosphonates

(2017) Jian Gu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Acid-induced chemoselective arylthiolations of electron-rich arenes in ionic liquids from sodium arylsulfinates: the reducibility of halide anions in [Hmim]Br

(2017) Zhu-bing Xu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed P–H Insertions of α-Imino Carbenes for the Preparation of 3-Phosphinoylindoles

(2017) Lisheng Wang et al.   ORGANIC LETTERS

Stereoselective Synthesis of Alkenyl Silanes, Sulfones, Phosphine Oxides, and Nitroolefins by Radical C–S Bond Cleavage of Arylalkenyl Sulfides

(2017) Ya-mei Lin et al.   ORGANIC LETTERS

Metal-free O–H/C–H difunctionalization of phenols by o-hydroxyarylsulfonium salts in water

(2017) Dengfeng Chen et al.   Chemical Science

Metal-free phosphonation of benzoxazoles and benzothiazoles under oxidative conditions

(2017) Jiuhan Gong et al.   Organic Chemistry Frontiers

Silver-Catalyzed Direct C$_{sp{^{2$H Phosphorylation of Indoles Leading to Phosphoindoles

(2016) Wang-Bin Sun et al.   ADVANCED SYNTHESIS & CATALYSIS

Odorless, Regioselective Synthesis of Diaryl Sulfides and α-Thioaryl Carbonyls from Sodium Arylsulfinates via a Metal- Free Radical Strategy in Water

(2016) Ya-mei Lin et al.   ADVANCED SYNTHESIS & CATALYSIS

Facile aromatic nucleophilic substitution (SNAr) reactions in ionic liquids: an electrophile–nucleophile dual activation by [Omim]Br for the reaction

(2016) Xiao Zhang et al.   GREEN CHEMISTRY

Manganese(III) Acetate-Promoted Cross-Coupling Reaction of Benzothiazole/Thiazole Derivatives with Organophosphorus Compounds under Ball-Milling Conditions

(2016) Liang Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient Pd-Catalyzed Dehydrogenative Coupling of P(O)H with RSH: A Precise Construction of P(O)–S Bonds

(2016) Yueyue Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Synthesis of Benzo[b]phosphole Derivatives via Direct ortho-Alkenylation and Cyclization of Arylthiophosphinamides

(2016) Yuto Unoh et al.   ORGANIC LETTERS

Phosphorus–Carbon Bond Forming Reactions of Diphenylphosphenium and Diphenylphosphine Triflate Complexes of Tungsten

(2016) Arumugam Jayaraman et al.   ORGANOMETALLICS

Copper-Catalyzed Radical/Radical C sp 3H/PH Cross-Coupling: α-Phosphorylation of Aryl KetoneO-Acetyloximes

(2015) Jie Ke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Paving the Way to Novel Phosphorus-Based Architectures: A Noncatalyzed Protocol to Access Six-Membered Heterocycles

(2015) Carlos Romero-Nieto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-catalysed P–C bond formation via P–H/C–CN cross coupling reactions

(2015) Ji-Shu Zhang et al.   CHEMICAL COMMUNICATIONS

Cu/Fe-Cocatalyzed Formation of β-Ketophosphonates by a Domino Knoevenagel-Decarboxylation-Oxyphosphorylation Sequence from Aromatic Aldehydes and H-Phosphonates

(2015) Mingxin Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

TBPB-promoted metal-free synthesis of thiophosphinate/phosphonothioate by direct P–S bond coupling

(2015) Jichao Wang et al.   GREEN CHEMISTRY

C–P Bond-Forming Reactions via C–O/P–H Cross-Coupling Catalyzed by Nickel

(2015) Jia Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Odorless, One-Pot Regio- and Stereoselective Iodothiolation of Alkynes with Sodium Arenesulfinates under Metal-Free Conditions in Water

(2015) Ya-mei Lin et al.   ORGANIC LETTERS

Recent advances in sulfur- and phosphorous-centered radical reactions for the formation of S–C and P–C bonds

(2015) Xiang-Qiang Pan et al.   TETRAHEDRON

Rhodium(III)-Catalyzed Direct Coupling of Arylphosphine Derivatives with Heterobicyclic Alkenes: A Concise Route to Biarylphosphines and Dibenzophosphole Derivatives

(2015) Yuto Unoh et al.   ACS Catalysis

Chloroform-based Atherton–Todd-type reactions of alcohols and thiols with secondary phosphine oxides generating phosphinothioates and phosphinates

(2015) Shan Li et al.   RSC Advances

Construction of a Highly Distorted Benzene Ring in a Double Helicene

(2014) Sigma Hashimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A unique copper-catalyzed cross-coupling reaction by hydrogen (H2) removal for the stereoselective synthesis of 3-phosphoindoles

(2014) An-Xi Zhou et al.   CHEMICAL COMMUNICATIONS

Peroxides as “Switches” of Dialkyl H-Phosphonate: Two Mild and Metal-Free Methods for Preparation of 2-Acylbenzothiazoles and Dialkyl Benzothiazol-2-ylphosphonates

(2014) Xiao-Lan Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Phosphinate Chemistry in the 21st Century: A Viable Alternative to the Use of Phosphorus Trichloride in Organophosphorus Synthesis.

(2013) Jean-Luc Montchamp   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-catalyzed direct phosphonation of azoles with dialkyl phosphites

(2012) Chaodong Hou et al.   CHEMICAL COMMUNICATIONS

Surface Modification Using Phosphonic Acids and Esters

(2012) Clémence Queffélec et al.   CHEMICAL REVIEWS

Structure-Guided Design, Synthesis, and Evaluation of Guanine-Derived Inhibitors of the eIF4E mRNA–Cap Interaction

(2012) Xiaoqi Chen et al.   JOURNAL OF MEDICINAL CHEMISTRY

Sulfonylation of aromatic compounds with methyl p-toluenesulfonate as a sulfonylating precursor

(2012) M. M. Khodaei et al.   Journal of the Iranian Chemical Society

Asymmetric Organocatalytic Electrophilic Phosphination

(2011) Martin Nielsen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine−Phosphinite and Phosphine−Phosphite Ligands: Preparation and Applications in Asymmetric Catalysis

(2011) Héctor Fernández-Pérez et al.   CHEMICAL REVIEWS

Discovery of a Series of Phosphonic Acid-Containing Thiazoles and Orally Bioavailable Diamide Prodrugs That Lower Glucose in Diabetic Animals Through Inhibition of Fructose-1,6-Bisphosphatase

(2010) Qun Dang et al.   JOURNAL OF MEDICINAL CHEMISTRY

Functionalization of Oxide Surfaces by Terpyridine Phosphonate Ligands: Surface Reactions and Anchoring Geometry

(2010) Valentina Spampinato et al.   LANGMUIR

Preparation of indole-phosphine oxazoline (IndPHOX) ligands and their application in allylic alkylation

(2010) Yu Wang et al.   TETRAHEDRON-ASYMMETRY

Thiophosphorylation of free amino acids and enzyme protein by thiophosphoramidate ions

(2009) Tomasz Ruman et al.   BIOORGANIC CHEMISTRY

Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands

(2008) Ruben Martin et al.   ACCOUNTS OF CHEMICAL RESEARCH