4.8 Article

A fast synthetic strategy for high-quality atomically thin antimonene with ultrahigh sonication power

Journal

NANO RESEARCH
Volume 11, Issue 11, Pages 5968-5977

Publisher

TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-018-2110-0

Keywords

antimonene; atomically thin; liquid phase exfoliation; atomic force microscopy sodium-ion batteries

Funding

  1. National Natural Science Foundation of China [21635002, U1505221, 21705023]
  2. Program for Changjiang Scholars and Innovative Research Team in University [IRT15R11]
  3. Independent Research Project of State Key Laboratory of Photocatalysis on Energy and Environment [2014B02]

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Recent theoretical studies revealed that two-dimensional (2D) antimonene has attractive characteristics, such as superior photothermal conductivity, absorption over a wide range, high mobility, and good spintronic properties. Herein, we report a reliable liquid phase exfoliation (LPE) route for the preparation of high-quality high-stability atomically thin (AT) antimonene via high ultrasonic power. The AT antimonene delivers a high specific capacity of up to 860 mAhg(-1), with high rate capability and good cycling stability as an anode of a sodium ion battery (SIB). The good conductivity and 2D structure endow AT antimonene with more active sites for sodium storage, a facilitated pathway for electron transfer and mass transport, and the capability to reduce the volume expansion during the discharge-charge process.

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