4.4 Article

Synthesis and characterization of novel high-performance polyarylsulfones with 4-(carbazol-9-yl) triphenylamine moieties

Journal

HIGH PERFORMANCE POLYMERS
Volume 27, Issue 8, Pages 1007-1015

Publisher

SAGE PUBLICATIONS LTD
DOI: 10.1177/0954008315606199

Keywords

Polyarylsulfones; triphenylamine; carbazole; N-C coupling reactions

Funding

  1. Science and Technology Development Plan of Jilin Province [20130305013GX, 20130204001GX]

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A novel homopolyarylsulfone with 4-(carbazol-9-yl) triphenylamine moieties was synthesized successfully through N-C coupling reactions under similar conditions to the synthesis of polyarylsulfones (PSU). By using this simple method and adjusting the feed ratio between 9-(4-aminobenzene) carbazole (NH2-Ar-Cz) and bisphenol A, a series of high-performance copolymers with high molecular weight, good film-reforming ability, great thermal stability, and excellent photoelectric characteristics were also prepared, which have good application potential in the field of organic optoelectronics.

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