4.6 Article

Concentration growth of luminescence intensity of phosphor Zn2-2xMn2xSiO4 (x ≤ 0.13): Crystal-chemical and quantum-mechanical justification

Journal

MATERIALS RESEARCH BULLETIN
Volume 97, Issue -, Pages 182-188

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2017.09.008

Keywords

Optical materials; X-ray diffraction; Crystal structure; Electronic structure; Phosphors

Funding

  1. Institute of Solid State Chemistry, Ural Division of the Russian Academy of Sciences [AAAA-A16-116122810217-0, AAAA-A16-116122810218-7, AAAA-A16-116122810214-9]

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In the present study, the willemite-based Zn2-2xMn2xSiO4 solid solution has been produced by the high-temperature solid-state reaction. The powder samples were characterized by X-ray diffraction, UV-vis spectroscopy and optical emission spectroscopy. A monotonic increase in the luminescence intensity is observed with a growth of the Mn content, but not exceeding x = 0.13. The absence of concentration quenching of luminescence below this limit is explained by stochastic arrangement of the dopant atoms, which is confirmed by crystallographic data. Basic trends in distribution of Mn ions within the willemite lattice and electronic properties were validated by means of DFT calculations. Homogenous distribution of photoactive substituent ion is a key feature in the design of luminescent materials.

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