4.7 Article

Temporal evolution of cadmium, copper and lead concentration in the Venice Lagoon water in relation with the speciation and dissolved/particulate partition

Journal

MARINE POLLUTION BULLETIN
Volume 129, Issue 2, Pages 884-892

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.marpolbul.2017.10.043

Keywords

Lagoon; Metals; Sediment; Chemical speciation

Ask authors/readers for more resources

In order to study the role of sediment re-suspension and deposition versus the role of organic complexation, we investigated the speciation of cadmium (Cd), copper (Cu) and lead (Pb) in samples collected in the Venice Lagoon during several campaigns from 1992 to 2006. The increment in Cd and Pb concentration in the dissolved phases, observed in the central and northern basins, can be linked to important alterations inside the lagoon caused by industrial and urban factors. The study focuses on metal partition between dissolved and particulate phases. The analyses carried out in different sites illustrate the complex role of organic matter in the sedimentation process. While Cd concentration in sediments can be correlated with organic matter, no such correlation can be established in the case of Pb, whose particulate concentration is related only to the dissolved concentration. In the case of Cu, the role of organic complexation remains unclear.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Environmental Sciences

Screening environmental risk evaluation of As and trace metals in soils and sediments from a developing area (Bc Giang Province, Northern Vietnam)

Stefania Romano, Clara Turetta, Fabiana Corami, Silvia Giuliani, Luca Giorgio Bellucci

Summary: In the areas close to the rivers Cu and Ngu Huy in Bac Giang Province, Northern Vietnam, investigations revealed the presence of contaminants in soils and sediments that may exceed international and national standards, with local sources potentially prevailing over geogenic origins. Higher concentrations of elements such as arsenic may pose risks to public health, especially when found in family wells.

ENVIRONMENTAL MONITORING AND ASSESSMENT (2021)

Article Geography, Physical

A multi-decadal geochemical record from Rano Aroi (Easter Island/Rapa Nui): Implications for the environment, climate and humans during the last two millennia

Marco Roman, David B. McWethy, Natalie M. Kehrwald, Evans Osayuki Erhenhi, Amy E. Myrbo, Jose M. Ramirez-Aliaga, Anibal Pauchard, Clara Turetta, Carlo Barbante, Matthew Prebble, Elena Argiriadis, Dario Battistel

Summary: This study reconstructs past changes in lithogenic inputs, weathering processes, redox conditions, productivity and water levels in the Rano Aroi wetland over the last 2000 years. The research provides insight into the complex history of human colonization and environmental interactions on Easter Island.

QUATERNARY SCIENCE REVIEWS (2021)

Article Environmental Sciences

A Year-Round Measurement of Water-Soluble Trace and Rare Earth Elements in Arctic Aerosol: Possible Inorganic Tracers of Specific Events

Clara Turetta, Matteo Feltracco, Elena Barbaro, Andrea Spolaor, Carlo Barbante, Andrea Gambaro

Summary: This study investigates the year-round variability of water-soluble trace elements and rare earth elements in size segregated airborne particulate matter samples collected in Ny-angstrom, Svalbard. The findings suggest that the content of wsTE and wsREE, especially in the finest fractions in remote areas, is primarily influenced by long-range transport. Factor analysis and back-trajectories were used to assess the potential of using certain inorganic tracers as indicators of specific transport events or circulation regimes.

ATMOSPHERE (2021)

Article Environmental Sciences

Characterization of atmospheric total gaseous mercury at a remote high-elevation site (Col Margherita Observatory, 2543 m a.s.l.) in the Italian Alps

Massimiliano Varde, Carlo Barbante, Elena Barbaro, Francesca Becherini, Paolo Bonasoni, Maurizio Busetto, Francescopiero Calzolari, Giulio Cozzi, Paolo Cristofanelli, Federico Dallo, Fabrizio De Blasi, Matteo Feltracco, Jacopo Gabrieli, Andrea Gambaro, Niccolo Maffezzoli, Elisa Morabito, Davide Putero, Andrea Spolaor, Warren R. L. Cairns

Summary: The Col Margherita (MRG) Observatory is a high-altitude station located in the Eastern Italian Alps. This study investigated the seasonal and diurnal variability of total gaseous mercury (TGM) measurements from March 2018 to May 2019. The results showed that TGM concentrations were influenced by local meteorology, as well as regional and long-range transport of air masses. The lowest TGM concentrations were observed in winter, while the highest concentrations were found in spring and summer.

ATMOSPHERIC ENVIRONMENT (2022)

Article Environmental Sciences

Assessing glyphosate in water, marine particulate matter, and sediments in the Lagoon of Venice

Matteo Feltracco, Elena Barbaro, Elisa Morabito, Roberta Zangrando, Rossano Piazza, Carlo Barbante, Andrea Gambaro

Summary: The study collected samples from the Lagoon of Venice to investigate the presence of the herbicide glyphosate, and found that its content mainly depends on external forcing from river inlets and agricultural lagoon activities, showing spatial and temporal fluctuations in concentration levels.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2022)

Article Environmental Sciences

Occurrence of rare earth elements in fledgelings of Thalasseus sandvicensis

Marco Picone, Gabriele Giuseppe Distefano, Fabiana Corami, Piero Franzoi, Simone Redolfi Bristol, Marco Basso, Lucio Panzarin, Annamaria Volpi Ghirardini

Summary: The study investigated the concentrations of rare earth elements in the feathers of Sandwich terns in Venice's Lagoon, finding that they were higher than in other bird feathers, with lanthanum being the most abundant. The research suggested that diet is the main exposure route for young terns, and emphasized the need for more data on REEs in aquatic ecosystems.

ENVIRONMENTAL RESEARCH (2022)

Article Food Science & Technology

Characterization of Botanical Origin of Italian Honey by Carbohydrate Composition and Volatile Organic Compounds (VOCs)

Raffaello Tedesco, Elisa Scalabrin, Valeria Malagnini, Lidija Strojnik, Nives Ogrinc, Gabriele Capodaglio

Summary: This study describes the chemical characterization of honeys of different botanical origin in the Trentino Alto-Adige region in Italy. The relationship between pollen composition and the chemical profile of honey was investigated, and it was found that the classification of honey botanical origin based on effective pollen composition is important for defining the properties and value of honeys.

FOODS (2022)

Article Environmental Sciences

Occurrence and Characterization of Small Microplastics (<100 μm), Additives, and Plasticizers in Larvae of Simuliidae

Fabiana Corami, Beatrice Rosso, Valentina Iannilli, Simone Ciadamidaro, Barbara Bravo, Carlo Barbante

Summary: This study is the first to investigate the ingestion of microplastics, plasticizers, additives, and particles of micro-litter by larvae of blackflies in rivers. The study found significant differences in the abundances of microplastics and plasticizers ingested by the two species under examination. Additives and plasticizers can be used as proxies for the presence of plastic polymers in the environment.

TOXICS (2022)

Article Environmental Sciences

Seabirds as Biomonitors of Mercury Bioavailability in the Venice Lagoon

Marco Picone, Gabriele Giuseppe Distefano, Godbless Adu Benhene, Fabiana Corami, Marco Basso, Lucio Panzarin, Caterina Carabelli, Annamaria Volpi Ghirardini

Summary: A study in Venice's Lagoon found that fledgling seabirds can be used as sentinels for mercury bioavailability. Different seabird species had significant differences in mercury residues in their feathers, possibly due to different diets, with one species accumulating more mercury than the others. While average residues were below the threshold for adverse effects on birds, a majority of individuals in one species exceeded the adverse effect level, emphasizing the need for stronger mercury monitoring. Seabirds provide valuable insight into mercury transfer in food webs and the potential risks to humans when consuming exploited species.

BULLETIN OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY (2023)

Article Environmental Sciences

Quantification and identification of airborne small microplastics (<100 μm) and other microlitter components in atmospheric aerosol via a novel elutriation and oleo-extraction method

Beatrice Rosso, Fabiana Corami, Carlo Barbante, Andrea Gambaro

Summary: The atmosphere plays a crucial role in the transportation of plastic particles and micro-litter particles from their sources to other environmental compartments. There is a lack of standardized methods for quantification and identification of airborne microplastics and micro-litter components. This study developed and optimized a pre-treatment method to simultaneously extract small microplastics and airborne micro-litter particles from urban aerosol samples. The results will contribute significantly to the establishment of standardized methods for quantification and identification of airborne microplastics and micro-litter particles.

ENVIRONMENTAL POLLUTION (2023)

Article Environmental Sciences

Quantification and characterization of additives, plasticizers, and small microplastics (5-100?m) in highway stormwater runoff

Beatrice Rosso, Fabiana Corami, Luca Vezzaro, Stefano Biondi, Barbara Bravo, Carlo Barbante, Andrea Gambaro

Summary: Highway stormwater runoff serves as a significant pathway for microplastics and other micro-litter to enter the surrounding environment. The concentrations and distribution of small microplastics (SMPs) and other components of micro-litter in highway stormwater runoff vary due to rainfall events. Assessing SMPs and other micro-litter in highway stormwater runoff is important for evaluating their potential impact on water bodies and air compartments.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2022)

Article Environmental Sciences

Identification and quantification of tire wear particles by employing different cross-validation techniques: FTIR-ATR Micro-FTIR, Pyr-GC/MS, and SEM

Beatrice Rosso, Elena Gregoris, Lucio Litti, Federico Zorzi, Maurizio Fiorini, Barbara Bravo, Carlo Barbante, Andrea Gambaro, Fabiana Corami

Summary: This study conducted chemical identification of tire wear particles (TWPs) in highway stormwater runoff through cross-validation techniques for the first time. A pre-treatment method was provided to extract TWPs without degradation and denaturation, ensuring accurate identification and quantification. Specific markers and various analytical techniques were used for TWPs identification, and the complex composition of these particles was confirmed through elemental analysis. This study contributes significantly to the understanding of TWPs in the environment and highlights the importance of cross-validation techniques for their identification and quantification.

ENVIRONMENTAL POLLUTION (2023)

Article Chemistry, Analytical

Microplastics analysis: can we carry out a polymeric characterisation of atmospheric aerosol using direct inlet Py-GC/MS?

Elena Gregoris, Gaia Gallo, Beatrice Rosso, Rossano Piazza, Fabiana Corami, Andrea Gambaro

Summary: This study tested the use of Py-GC/MS to detect polymers in atmospheric aerosol, and found the presence of polyethylene, polypropylene, and polystyrene in the samples. The direct analysis of sampling filters was suggested as an exploratory technique, but further research is needed for a comprehensive characterization of polymers in atmospheric aerosol.

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS (2023)

Article Environmental Sciences

Microplastics, Additives, and Plasticizers in Freshwater Bivalves: Preliminary Research of Biomonitoring

Giulia Cesarini, Fabiana Corami, Beatrice Rosso, Massimiliano Scalici

Summary: Microplastics, plasticizers, and additives were found to accumulate in freshwater bivalves Anodonta cygnea, highlighting the plastic pollution caused by small microplastics. The gills and gastrointestinal tract of the bivalves contained a high concentration of polyamide, indicating the presence of microplastics in rivers. Additionally, the presence of natural and synthetic fibers in rivers suggests the need for further investigation of the sources of microplastics.

WATER (2023)

Article Geosciences, Multidisciplinary

Five thousand years of fire history in the high North Atlantic region: natural variability and ancient human forcing

Delia Segato, Maria Del Carmen Villoslada Hidalgo, Ross Edwards, Elena Barbaro, Paul Vallelonga, Helle Astrid Kjaer, Marius Simonsen, Bo Vinther, Niccolo Maffezzoli, Roberta Zangrando, Clara Turetta, Dario Battistel, Orri Vesteinsson, Carlo Barbante, Andrea Spolaor

Summary: The study suggests that the fire regime reconstructed from RECAP fluxes is mainly related to climatic changes, but over the last millennium, human activities might have substantially influenced wildfire frequency/occurrence.

CLIMATE OF THE PAST (2021)

Article Environmental Sciences

Analysis of microplastics in ships ballast water and its ecological risk assessment studies from the Persian Gulf

Atefeh Zendehboudi, Azam Mohammadi, Sina Dobaradaran, Gabriel E. De-la-Torre, Bahman Ramavandi, Seyed Enayat Hashemi, Reza Saeedi, Emran Moradpour Tayebi, Ahmad Vafaee, Amirhossein Darabi

Summary: This study investigated the characteristics and ecological risks of microplastics (MPs) in ballast water for the first time, and found high levels of MP pollution. These findings contribute to our understanding of the sources and risks of microplastics in marine ecosystems.

MARINE POLLUTION BULLETIN (2024)

Article Environmental Sciences

Catchment scale assessment of macroplastic pollution in the Odaw river, Ghana

Rose Boahemaa Pinto, Linda Bogerd, Martine van der Ploeg, Kwame Duah, Remko Uijlenhoet, Tim H. M. van Emmerik

Summary: Catchment-scale plastic pollution assessments provide insights into the sources, sinks, and pathways of plastic pollution. We propose an approach to quantify macroplastic transport and density in the Odaw catchment, Ghana, and find that the urban riverine zone has the highest transport, while the urban tidal zone has the highest riverbank and land macroplastic density.

MARINE POLLUTION BULLETIN (2024)

Article Environmental Sciences

Evaluating the capacity of heavy metal pollution enrichment in green vegetation in the industrial zone, Northwest China

Aliya Baidourela, Qian Sun, Gongxin Yang, Umut Halik, Zhongkai Dong, Kaixu Cai, Guili Sun, Wenya Zhang, Sisi Cheng

Summary: The study focused on heavy metal pollution in the green vegetation of a suburban industrial area in Tuokexun County, Xinjiang, China. The results showed that the overall level of heavy metal pollution in the soil was minor, with mercury (Hg) being the most severe contamination, likely caused by human activities. The composition of heavy metal elements in trees was more stable compared to grass and shrubs, with varying concentrations across different vegetation. Shrubbery was found to be the most effective in heavy metal restoration, and there were disparities in heavy metal enrichment among different vegetation types.

MARINE POLLUTION BULLETIN (2024)

Article Environmental Sciences

Leaching and transformation of chemical additives from weathered plastic deployed in the marine environment

James H. Bridson, Hayden Masterton, Beatrix Theobald, Regis Risani, Fraser Doake, Jessica A. Wallbank, Stefan D. M. Maday, Gavin Lear, Robert Abbel, Dawn A. Smith, Joanne M. Kingsbury, Olga Pantos, Grant L. Northcott, Sally Gaw

Summary: Plastic pollution has significant environmental impacts, largely due to chemical additives. However, the behavior of plastic additives in marine environments is not well understood. A marine deployment experiment was conducted to investigate the effects of weathering on the extractables profile of four types of plastics in New Zealand over a period of nine months. The concentration of additives in polyethylene and oxo-degradable polyethylene was strongly influenced by artificial weathering, while polyamide 6 and polyethylene terephthalate showed minimal change. These findings emphasize the importance of considering leaching and weathering effects on plastic composition when assessing the potential impact and risk of plastic pollution in receiving environments.

MARINE POLLUTION BULLETIN (2024)

Article Environmental Sciences

Do distributions of diamondoid hydrocarbons accumulated in oil-contaminated fish tissues help to identify the sources of oil?

Alan G. Scarlett, Francis D. Spilsbury, Steven J. Rowland, Marthe Monique Gagnon, Kliti Grice

Summary: This study used diamondoid hydrocarbon distributions to identify the sources of environmental oil contamination. A suite of 20 diamondoids was found to accumulate in fish adipose tissue. The scatter plots of indices between fish and exposure oils showed a close to ideal 1:1 relationship, which can be used to determine the origin of the oil.

MARINE POLLUTION BULLETIN (2024)

Article Environmental Sciences

Spatiotemporal distribution, source analysis and ecological risk assessment of polychlorinated biphenyls (PCBs) in the Bohai Bay, China

Shan Jiang, Mengmeng Wan, Kun Lin, Yanshan Chen, Rui Wang, Liju Tan, Jiangtao Wang

Summary: In this study, the concentration, composition, distribution, and sources of PCBs in surface seawater of the Bohai Bay were analyzed. The results showed that PCBs in the Bohai Bay had high concentrations and were primarily derived from land-based sources such as port activities and river inputs. The PCBs in the Bohai Bay may come from commercial PCBs and their incineration products, municipal landfills, wood and coal combustion, and industrial activities, etc.

MARINE POLLUTION BULLETIN (2024)

Article Environmental Sciences

Human health risk assessment of mercury in highly consumed fish in Salvador, Brazil

Icaro S. A. Porto, Saulo V. A. Dantas, Caio S. A. Felix, Francisco A. S. Cunha, Jailson B. de Andrade, Sergio L. C. Ferreira

Summary: This study evaluated the risks of mercury levels in sardines consumed by low-income population in Salvador, Brazil. The results showed that the mercury content in the sampled sardines posed no risks to human health. This study is significant as most sardines in Salvador come from Todos os Santos Bay, which has a history of mercury contamination.

MARINE POLLUTION BULLETIN (2024)

Article Environmental Sciences

Mangrove species and site elevation are critical drivers of greenhouse gas fluxes from restored mangrove soils

Jiahui Chen, Chengyu Yuan, Guanqun Zhai, Guangcheng Chen, Heng Zhu, Jun Liu, Yong Ye

Summary: This study investigated the combined influences of species selection and site elevation on greenhouse gas fluxes from restored mangrove soils. The results suggest that Avicennia marina should be selected for mangrove restoration to minimize carbon release and reduce the influence of greenhouse gas fluxes on the global greenhouse effect.

MARINE POLLUTION BULLETIN (2024)

Article Environmental Sciences

Building collaboration and synergy among regional blocs to reduce marine plastic waste pollution: A case for the Gulf of Guinea region

Emmanuel Onyeabor, Uju Obuka

Summary: The Gulf of Guinea region in Africa is a significant area for coastal countries, playing a vital role in their economic and environmental development. This study aims to reduce marine plastic pollution in the region by utilizing legal instruments.

MARINE POLLUTION BULLETIN (2024)

Article Environmental Sciences

Detecting small microplastics down to 1.3 μm using large area ATR-FTIR

Yuanli Liu, Stephan Luttjohann, Alvise Vianello, Claudia Lorenz, Fan Liu, Jes Vollertsen

Summary: Large area attenuated total reflectance-Fourier transform infrared spectroscopy (LAATR-FTIR) is a novel technique for detecting small microplastics, with limited accuracy for large microplastics. However, it shows promise in homogeneous matrices. The spectra quality is comparable between transmission mode and LAATR mode.

MARINE POLLUTION BULLETIN (2024)

Article Environmental Sciences

Relationship between floating marine debris accumulation and coastal fronts in the Northeast coast of the USA

Phuc T. D. Le, Andrew M. Fischer, Britta D. Hardesty, Heidi J. Auman, Chris Wilcox

Summary: This study explores the relationship between ocean currents and the accumulation of floating marine debris (FMD) and finds that higher concentrations of FMD are associated with frontal frequencies (FF). FMD is primarily trapped in accumulation zones between fronts and the coastline, which have high biodiversity value.

MARINE POLLUTION BULLETIN (2024)

Article Environmental Sciences

Microplastic inputs to the Mediterranean Sea during wet and dry seasons: The case of two Lebanese coastal outlets

Rosa Sawan, Perine Doyen, Florence Viudes, Rachid Amara, Celine Mahfouz

Summary: Few studies have examined the impact of urbanization and meteorological events on microplastics discharged into the sea through rivers. Surface water samples were collected from two Lebanese rivers, with differing degrees of urbanization, during dry and wet periods. The results showed that the most industrialized river had a significantly higher abundance of microplastics compared to the less-industrialized river. There was also a correlation between particle contamination and the season at each site, with microplastic concentrations highest on the first day of the wet season. These findings highlight the importance of considering meteorological events in accurately assessing plastic pollution influx into coastal waters.

MARINE POLLUTION BULLETIN (2024)

Article Environmental Sciences

Microplastics absent from reef fish in the Marshall Islands: Multistage screening methods reduced false positives

Katherine R. Shaw, Jonathan L. Whitney, Eileen M. Nalley, Madeline C. Schmidbauer, Megan J. Donahue, Jesse Black, Raquel N. Corniuk, Kellie Teague, Rachel Sandquist, Catherine Pirkle, Rachel Dacks, Max Sudnovsky, Jennifer M. Lynch

Summary: This study examines the ingestion of plastic in reef fish in the Republic of the Marshall Islands. Plastic particles were found in the gastrointestinal tracts of multiple fish species. However, further analysis revealed that these particles were actually natural materials and posed no threat to human consumers.

MARINE POLLUTION BULLETIN (2024)

Article Environmental Sciences

Trait-based classification and environmental drivers of phytoplankton functional structure from anthropogenically altered tropical creek, Thane Creek India

Revati Hardikar, C. K. Haridevi, Shantaj Deshbhratar

Summary: This study investigated the variability in phytoplankton functional structure using a trait-based approach and explored the relationship between species traits and environmental factors, as well as their impact on ecosystem functioning. The results revealed that morphological traits, temperature, and ammonia played a decisive role in the seasonal succession of phytoplankton species. It was found that certain traits favored higher biomass production but might hinder energy transfer efficiency. The strong correlation between environmental variables and phytoplankton functional structure supports the practical implementation of a trait-based approach in studying phytoplankton community dynamics under different environmental conditions.

MARINE POLLUTION BULLETIN (2024)

Article Environmental Sciences

Dispersion of surface floating plastic marine debris from Indonesian waters using hydrodynamic and trajectory models

Engki A. Kisnarti, Nining Sari Ningsih, Mutiara R. Putri, Nani Hendiarti, Bernhard Mayer

Summary: This study examines the movement patterns of plastic marine debris in Indonesian waters, revealing that Indonesia contributes significantly to transboundary marine debris in the Pacific Ocean, Indian Ocean, and the South China Sea. Most of the debris remains in Indonesian waters and moves back and forth due to the influence of monsoon currents.

MARINE POLLUTION BULLETIN (2024)