Journal
MACROMOLECULES
Volume 51, Issue 3, Pages 846-852Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.7b02463
Keywords
-
Categories
Funding
- University of Rostock
Ask authors/readers for more resources
Herein we report the synthesis of isotactically enriched poly(cyclohexene carbonate) (PCHC) by the bulk alternating copolymerization of meso-cyclohexene oxide and carbon dioxide using dialkylmagnesium compounds as catalyst. These simple achiral catalysts showed good activity for the isoselective copolymerization, with high yield and high carbonate-linkage contents, in a controlled manner under mild conditions and atmospheric CO2 pressure. The triad sequences in the C-13 NMR spectra of these polymers were assigned using Bernoullian statistical methods in order to determine the tacticity of the copolymer. Differential scanning calorimetry analysis confirmed the formation of highly isotactic polycarbonate. Furthermore, kinetic studies and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry investigations allowed us to shed light on the reaction mechanism of the polymerization process.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available