Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 40, Issue 5, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201800252
Keywords
anticorrosion; graphene oxide; in situ polymerization; silicone matrix; silylation
Categories
Funding
- Natural Science Foundation of Shandong Province, China [ZR2015BM009]
- Shandong Province Science and Technology Development Project, China [2014GGX102030]
- Major Projects of Independent Innovation in Shandong Province, China [2014ZZCX01106]
- Yuandu Industrial Leader Talent Project (Weifang2017)
Ask authors/readers for more resources
Novel graphene-oxide-reinforced silicone composites (GO-SC) are prepared by in situ polymerization of silanes and low concentrations (<0.15 wt%) of silylated GO (S-GO). After modification, the distances of the S-GO nanosheets are successfully increased from 0.72 to 0.87 nm. Compared with GO, the S-GO shows better dispersibility in organic solvents as well as remarkably enhanced decomposition temperature (T-d improved by 100 degrees C). After covalently grafting onto silicone resins via in situ polymerization, the obtained GO-SC exhibits greatly enhanced thermal stability (T-d up to 400 degrees C and T-g improved by 3-5 degrees C), increased storage modulus, loss modulus, and complex viscosity. The morphology, microstructure, interfacial adhesion of the developed GO-SC coatings were carefully investigated. The GO-SC coatings on metal exhibit good transparency (up to 90%), hydrophobicity, and excellent anticorrosion capability. This work provides a new strategy for developing high performance graphene-based silicone composite materials.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available