Article
Environmental Sciences
Junfeng Chen, Kunqi Zhao, Yiqun Wu, Jinyu Liu, Renjun Wang, Yuewei Yang, Yanyan Liu
Summary: The property of cathode in microbial fuel cell (MFC) is a key factor limiting its output performance. MnO2 nanorods were prepared by hydrothermal method and used as cathode catalysts for MFCs. The unique crystal planes and abundant hydroxyl groups on the surface of MnO2 nanorods provided active adsorption sites, leading to a significantly higher power density and stability compared to other cathode materials.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Engineering, Environmental
Xinyi Li, Yangtian Huang, Yubiao Lu, Tianbo Jia, Jianxin Wang, Peng Li
Summary: Nitrogen-doped graphene oxide (N-doped GO) catalyst improves the oxygen reduction reaction (ORR) performance of air-cathode microbial fuel cell (AMFC), enhancing the output voltage and power density. The NGO10 catalyst shows the highest output voltage (391.8 mV) and power density (1800 mWm-3) in AMFC, outperforming H-NGO and Pt/C electrodes. High-throughput sequencing reveals diverse bacterial communities in anode and cathode biofilms, with enriched denitrifying bacteria including Marinobacter, Methylophaga, and Arcobacter on NGO10 cathode. Real-time PCR confirms higher expression of denitrification-related genes in the NGO10 cathode biofilm.
JOURNAL OF WATER PROCESS ENGINEERING
(2023)
Article
Environmental Sciences
Yong-Por Ong, Li-Ngee Ho, Soon-An Ong, Johar Banjuraizah, Abdul Haqi Ibrahim, Shen-Hui Thor, Kea-Lee Yap
Summary: A unidirectional flow solar photocatalytic fuel cell (PFC) was successfully developed using different MnO2 crystal phases as cathodic catalysts, demonstrating the significant influence of crystallographic structures on catalytic activity. Micropore surface area was found to impact PFC performance, with nanowire alpha-M3(24 h)/C material showing the best performance.
Article
Engineering, Environmental
Bi-Lin Lai, Hai-Xia Liao, Shu-Qi Zhou, Hui-Xu Wei, Ai-Yi Li, Nan Li, Zhao-Qing Liu
Summary: This study successfully prepared a series of chalcogen-modified copper and nitrogen co-doped catalysts, which showed improved oxygen reduction reaction (ORR) performance through proper chalcogen doping while maintaining antibacterial properties. Among these catalysts, the optimized Cu2S@Cu-SNC-2 catalyst exhibited excellent durability and ORR activity, outperforming the commercial Pt/C catalyst. The MFC based on Cu2S@Cu-SNC-2 also achieved significantly higher power density and had fewer cathode biofilms.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Physical
Jingzhen Wang, Kaijie Mu, Xuedong Zhao, Dianliang Luo, Xiaodi Yu, Wenpeng Li, Jie Chu, Jing Yang, Qinzheng Yang
Summary: In this study, Pd was uniformly dispersed on the graphene framework supported by carbon black to form nanocomposite catalysts, leading to improved catalytic performance. The optimized metal loading reduced resistance and improved accessibility of Pd particles for the ORR, resulting in a 4.2-fold increase in the maximum current output of the MFC compared to the carbon paper cathode. Overall, this research provides a novel protocol for preparing high-efficiency ORR catalysts for MFCs.
Article
Agricultural Engineering
Junfeng Chen, Yuhan Liu, Jiaqi Yang, Haidi Wang, Huan Liu, Shining Cao, Xiaochi Zhang, Renjun Wang, Yanyan Liu, Yuewei Yang
Summary: A cathode catalyst of MnO2@Co3O4 nanohybrids was prepared by a simple two-step hydrothermal method, which not only contained rich metallic elements and electrochemically active sites, but also improved the performance of microbial fuel cells, such as maximum output power and stabilization time.
BIORESOURCE TECHNOLOGY
(2022)
Article
Chemistry, Physical
Yuan Fang, Tingting Zhang, Yuhang Zhang, Jianfeng Zhu
Summary: This study synthesized CeO2-QDs@MnO2 and MnO2@CeO2-QDs composites to investigate the role of CeO2 in ORR. CeO2-QDs@MnO2 showed superior ORR activity and stability, with a mechanism of temporary storage and timely replenishment of oxygen in CeO2 catalyzing greater efficiency.
APPLIED CATALYSIS A-GENERAL
(2021)
Article
Electrochemistry
Bolong Liang, Ming Su, Zhe Zhao, Hongbin He, Shumin Lin, Shu-xuan Liang
Summary: To investigate the effect of iron ligands on catalyst properties, catalysts with different structures using four kinds of ligands were prepared and compared for their oxygen reduction reaction (ORR) activity and maximum power density in microbial fuel cells (MFCs). The results showed that the Fe single atoms, metal-organic framework compound, Prussia blue crystal, and ethylenediamine coordination compound exhibited different maximum power densities and electrochemical performances. It was found that the structures and surface properties of the catalysts played a significant role in ORR activity, with the single-atom and ethylenediamine coordination structures showing promise for ORR in MFCs.
ELECTROCHIMICA ACTA
(2023)
Article
Chemistry, Physical
Yuan Fang, Yuhang Zhang, Xin Wu, Lixiang Jian, Jianfeng Zhu
Summary: This study aimed to develop new fabrication techniques for improving the performance of cathodes in liquid fuel cells. An integrated electrode with a sandwich-structured MnCo2O4/NC/MnO2 catalyst was prepared by in-situ growth on nickel foam. The resulting electrode showed promising results as the cathode in direct methanol fuel cells (DMFC) and direct borohydride fuel cells (DBFC), with peak power densities of 12.22 mW cm-2 and 33.65 mW cm-2, respectively. The in-situ growth of the MnCo2O4/NC/MnO2 catalyst layer exhibited superior catalytic activity compared to other catalysts. Stability tests showed excellent performance of the integrated cathode-based DBFC for approximately 350 hours. This work provides a new strategy for the preparation and optimization of fuel cell electrodes.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Junfeng Chen, Yiwen Zhang, Yiqun Wu, Jingyu Wang, Yongyue Zhao, Mingkun Wang, Jiaqi Yang, Jinyu Liu, Renjun Wang, Yuewei Yang, Yanyan Liu
Summary: NiCoAl-layered double hydroxide (LDH)/MXene was successfully prepared through hydrothermal method and showed superior catalytic oxygen reduction reaction (ORR). As the cathode in microbial fuel cell (MFC), NiCoAl-LDH/MXene exhibited higher power density and output voltage compared to MXene-MFC and NiCoAl-LDH-MFC. These results suggest that NiCoAl-LDH/MXene is a potential cathode catalyst for MFC with promising future applications.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Nanoscience & Nanotechnology
Simran Kaur Dhillon, Patit Paban Kundu
Summary: The performance of microbial fuel cells (MFCs) can be enhanced by synthesizing a composite material of magnesium cobaltite embedded in nitrogen-doped carbon. The composite serves as an air cathode and demonstrates superior power output compared to traditional catalysts.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Thermodynamics
Wenwen Chen, Zhongliang Liu, Yanxia Li, Qiang Liao, Xun Zhu
Summary: This study proposes an energy-efficient method for preparing a three-dimensional binder-free air cathode for MFCs by synthesizing non-noble composite catalysts on stainless steel fiber felt (SSFF). This method aims to reduce the cost of air cathode preparation while maintaining high electricity output of MFCs.
Review
Environmental Sciences
Yasser Bashir, Rishabh Raj, Sovik Das, M. M. Ghangrekar
Summary: Microbial fuel cells (MFCs) are important for bioelectricity production and wastewater treatment. However, the low power output of MFCs due to slow oxygen reduction reaction (ORR) is a major challenge. The application of bimetallic catalysts in MFCs has shown potential in improving power generation. This review evaluates different metal composites used in lab-scale and field-scale MFCs, focusing on power generation and ORR activity. It also discusses the synthesis, morphology, and electrochemical behavior of bimetallic catalysts.
WATER AIR AND SOIL POLLUTION
(2023)
Article
Engineering, Environmental
Simran Kaur Dhillon, Patit Paban Kundu
Summary: Efficient and inexpensive electrocatalysts for microbial fuel cells were developed. PANI@Fe/NC showed superior performance with a higher power output compared to conventional catalysts. This novel cathode catalyst has potential for long-term fuel cell applications.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Electrochemistry
Indrajit Chakraborty, Debanjali Ghosh, S. M. Sathe, B. K. Dubey, D. Pradhan, M. M. Ghangrekar
Summary: The study focused on synthesizing CeO2 nanosheets as a cathode catalyst for microbial fuel cells to accelerate the reduction of O-2 to H2O2. CeO2 catalyst with a unique structure showed increased H2O2 production and enhanced electrical performance compared to bare carbon catalyst.
ELECTROCHIMICA ACTA
(2021)
Article
Environmental Sciences
Ali Reza Rahmani, Nahid Navidjouy, Mostafa Rahimnejad, Saber Alizadeh, Mohammad Reza Samarghandi, Davood Nematollahi
Summary: The potential application of double-chamber microbial fuel cell (DC-MFC) for the removal of chemical oxygen demand (COD) and power generation from wastewater in different conditions is investigated. The results show that COD removal efficiency increases with higher concentrations of organic matter, but decreases with further increase. The important system outputs are reported for the highest COD concentration.
ENVIRONMENTAL TECHNOLOGY
(2022)
Article
Energy & Fuels
Mehrdad Mashkour, Mostafa Rahimnejad, Mahdi Mashkour, Francesca Soavi
Summary: A novel membrane electrode assembly (MEA) was fabricated and evaluated as an air-cathode in a single-chamber microbial fuel cell (MFC), showing higher performance in electricity generation and wastewater treatment at a lower cost compared to a PTFE-based gas diffusion electrode (GDE).
Article
Chemistry, Physical
Mahsa Masoudi, Mostafa Rahimnejad, Mehrdad Mashkour
Summary: Air-cathode microbial fuel cells (MFCs) with sinusoidal geometry anodes showed improved electrode surface area, leading to enhanced power production and COD removal efficiency. Increasing the surface area of air-cathodes and anodes had a significant impact on power density and overall performance of SCMFCs.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Electrochemistry
Mehri Shabani, Maxime Pontie, Habibollah Younesi, Mouna Nacef, Ahmad Rahimpour, Mostafa Rahimnejad, Racha Medjda Bouchenak Khelladi
Summary: The study demonstrated that mixed bacterial-fungal biofilm culture had a higher biodegradation rate, effectively removing APAP and PAP in a shorter period of time, while also exhibiting significantly greater power density in the FMFC system compared to pure fungal biofilm culture.
JOURNAL OF APPLIED ELECTROCHEMISTRY
(2021)
Article
Chemistry, Physical
Pouria Khalaj, Hannaneh Naghibi, Mohsen Ghorbani
Summary: The present study aimed to synthesize polypyrrole coated tin oxide (PPy/SnO2) nanocomposite for the removal of Acid Blue 62 anionic dye and disinfection of bacteria. The nanoadsorbent showed high adsorption capacity for Acid Blue 62 and exceptional disinfection ability for both Escherichia coli and Staphylococcus aureus.
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY
(2022)
Review
Materials Science, Characterization & Testing
Yasamin Pesaran Afsharian, Mostafa Rahimnejad
Summary: Skin tissue engineering utilizes biomedical scaffold design to resorb skin layers and regenerate skin appendages, with electrospinning technology playing a crucial role in creating nanoscale structures. Bioactive electrospun dressings have shown effectiveness in treating acute and chronic wounds while also promoting cellular functions and tissue repair. Excellent scaffold design is crucial for successful application of electrospun dressings in tissue engineering.
Article
Chemistry, Applied
Fatemeh Karimi, Mohsen Ghorbani, Mohammad Soleimani Lashkenari, Masoomeh Jajroodi, Elahe Fallah Talooki, Yasser Vaseghian, Onur Karaman, Ceren Karaman
Summary: This study successfully developed PANI-MnFe2O4/Pt/Ru nanocomposite as an effective catalyst for ethanol oxidation process with improved efficiency, stability, and carbon monoxide tolerance, which are essential for practical applications in alkaline direct ethanol fuel cells.
TOPICS IN CATALYSIS
(2022)
Review
Chemistry, Physical
Yasamin Pesaran Afsharian, Mostafa Rahimnejad
Summary: Recent advancements in biotechnology have made it easier to engineer microbial communities as biocatalysts for bioelectrochemical systems. Efforts are focused on precision electroactive biofilm, with emphasis on controlling electron transfer efficiency at the microbe/anode interface. The research highlights techniques for controlling biofilm composition on the anode using real multispecies substrates.
CURRENT OPINION IN ELECTROCHEMISTRY
(2022)
Article
Environmental Sciences
Rosan Zokhtareh, Mostafa Rahimnejad, Ghasem Najafpour-Darzi, Hassan Karimi-Maleh
Summary: The development of efficient antibiotic monitoring systems to reduce the environmental risks of antibiotic resistant genes is crucial. In this study, an electrochemical sensor was fabricated using green synthesis of Fe3O4 nanoparticles with the help of Sambucus ebulus L. leaves alcoholic plant extract. The sensor showed excellent catalytic activity and was successfully used for the electrochemical detection of metronidazole in real aqueous samples.
ENVIRONMENTAL RESEARCH
(2023)
Article
Chemistry, Multidisciplinary
Neda Rahmati, Mostafa Rahimnejad, S. Masoomeh Pourali, Shatha K. Muallah
Summary: A safe and green procedure is introduced for synthesizing bismuth oxychloride nanoparticles as an alternative to the time-consuming and hazardous chemical methods. The synthesized nanoparticles show excellent patterns and high purity, and are used as electrode modifiers for a high-performance electrochemical nickel ion sensor. The sensor demonstrates promising capability for nickel ion detection in real samples.
Article
Environmental Sciences
Elahe Fallah Talooki, Mohsen Ghorbani, Mostafa Rahimnejad, Mohammad Soleimani Lashkenari
Summary: Photo-assisted microbial fuel cells (PMFCs) are a novel bioelectrochemical system that utilizes light to generate bioelectricity and reduce contaminants efficiently. This study evaluates the influence of different operational conditions on electricity generation in a photoelectrochemical double chamber MFC using a highly functional photocathode, and compares their trends with photoreduction efficiency trends. Results show that despite the harmful effect of initial contaminant concentration, it has a superior ability to improve power generation efficiency. Additionally, power density increases significantly under higher light irradiation intensity, due to an increase in photon production and their chance of reaching the electrode surface. Moreover, power generation decreases with increasing pH, following the same trend as photoreduction efficiency.
ENVIRONMENTAL TECHNOLOGY
(2023)
Article
Engineering, Multidisciplinary
Rosan Zokhtareh, Mostafa Rahimnejad, Ghasem Najafpour-Darzi, hassan karimi-Maleh
Summary: Excessive use of antibiotics has led to an increase in drug-resistant genes. A valid feasible sensor was developed for ciprofloxacin determination using graphene nanosheets and Fe3O4 nanoparticles in the matrix of carbon paste electrode. The sensor exhibited enhanced electrocatalytic activity and provided detection and quantification limits of 1.8 nM and 6 nM, respectively. These findings promise a reliable device for food and environmental applications.
Article
Environmental Sciences
Maedeh Nouri, Mostafa Rahimnejad, Ghasem Najafpour, Ali Akbar Moghadamnia
Summary: A novel electrochemical biosensor based on DNA was developed for measuring the antimigraine drug rizatriptan benzoate in biological samples. The biosensor was modified with magnetic nanoparticles and gold nanoparticles and showed excellent performance in terms of sensitivity, selectivity, and usability.
ENVIRONMENTAL RESEARCH
(2023)
Article
Chemistry, Analytical
Razieh Seyfi Zouleh, Mostafa Rahimnejad, Ghasem Najafpour-Darzi, Davood Sabour, Joseany M. S. Almeida, Christopher M. A. Brett
Summary: A new electrochemical enzyme biosensor has been developed for monitoring hydrogen peroxide. The sensor utilizes a multiwalled carbon nanotube modified glassy carbon electrode with a polymer film. The characteristics and morphology of the sensor were studied using electrochemical methods and microscopy. Catalase enzyme was immobilized on the electrode, and the biosensor exhibited a low detection limit for hydrogen peroxide and good recovery in commercial samples.
MICROCHEMICAL JOURNAL
(2023)
Article
Engineering, Electrical & Electronic
Mohsen Ghorbani, Babak Mozafari, Mehdi Firouzi, Farzad Golshan
Summary: This paper proposes a RC-type solid state fault current limiter (SSFCL) to enhance the low-voltage ride-through (LVRT) requirement of wind power plants (WPPs). Simulation results show that the RC-type SSFCL can effectively improve the LVRT performance of WPPs under both symmetrical and asymmetrical fault conditions, and outperforms the RL-type SSFCL.
ELECTRIC POWER COMPONENTS AND SYSTEMS
(2022)