Journal
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 165, Issue 2, Pages F24-F31Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0521802jes
Keywords
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Funding
- National Natural Science Foundation of China [21776167, 21276148, 21076119]
- State Key Laboratory of Chemical Engineering (Tianjin University) [SKL-ChE-14B01]
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Cobalt phthalocyanine (CoPc) is supported on homemade three-dimensional graphene (3D-G) to prepare CoPc/3D-G catalysts used for oxygen reduction reaction (ORR). 3D-G is made from coal tar pitch with nano MgO as template and KOH as activation agent. Raman spectra indicate that 3D-G is multi-layered. Transmission electron microscopy images show that CoPc/3D-G retains the mesoporous foam structure of 3D-G and CoPc is dispersed homogeneously on the surface of 3D-G. CoPc/3D-G shows a half-wave potential of 0.85 V vs. RHE in oxygen-saturated solution of 0.1 M KOH, which is 50 mV higher than that of 6 wt% Pt/C. The electron transfer number of CoPc/3D-G is 3.99 at 0.65 V vs. RHE, indicating that oxygen reduction is catalyzed mainly via a four-electron process. CoPc/3D-G exhibits a current density loss of 10% after 40,000 s in chronoamperometry tests, while CoPc/C lost 17.5% after the same period. (C) 2018 The Electrochemical Society.
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