Journal
JOURNAL OF RARE EARTHS
Volume 36, Issue 6, Pages 662-668Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jre.2017.12.007
Keywords
Al-Si alloy; Yb; Eutectic Si; Microstructure; Twins; Rare earths
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Funding
- National Natural Science Foundation of China [51405216]
- Training Programme Foundation for Young Scientists of Jiangxi Province [20153BCB23023]
- Natural Science Foundation of Jiangxi Province [20171BAB206005]
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The solidification behavior, microstructure and silicon twinning of Al-10Si alloys with Yb addition were investigated by thermal analysis, optical microscopy, X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. The results indicate that the nucleation temperature, minimum temperature, and growth temperature of Al-10Si alloys decrease with increasing Yb content. The cooling curves of the Yb-modified alloys exhibit marked recalescence. The recalescence of the modified alloy peaks at 2.3 degrees C when the Yb content is 0.7 wt%. The 3D morphologies of eutectic Si in Yb-modified alloys change from a coarse plate-like structure to a honeycomb structure with many fine fibrous structures. The Al-Si-Yb intermetallic compound is observed in the 1.0 wt% Yb-modified alloy. Meanwhile, XRD analysis and TEM results indicate that the average twin spacing in the Yb-modified alloys is 18-46.2 nm. The average twin spacing of eutectic Si decreases with increasing Yb content. When the Yb content in the modified alloy is increased to 0.7 wt%, the average twin spacing value of eutectic Si reaches to 18 nm, which promotes the formation of twins and refinement of eutectic Si. (C) 2018 Published by Elsevier B.V.
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