Journal
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER
Volume 206, Issue -, Pages 367-377Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jqsrt.2017.12.008
Keywords
Precision molecular spectroscopy; Line lists; Carbon dioxide; Cavity ring-down spectroscopy; Infrared spectroscopy; Dipole moment surfaces
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Funding
- National Institute of Standards and Technology (NIST) Greenhouse Gas Measurements Program
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Reported here are highly accurate, experimentally measured ro-vibrational transition intensities for the R-branch of the (20012)-(00001) (CO2)-C-12-O-16 band near lambda =2 mu m. Measurements were performed by a frequency-stabilized cavity ring-down spectroscopy (FS-CRDS) instrument designed to achieve precision molecular spectroscopy in this important region of the infrared. Through careful control and traceable characterization of CO2 sample conditions, and through high-fidelity measurements spanning several months in time, we achieve relative standard uncertainties for the reported transition intensities between 0.15% and 0.46%. Such high accuracy spectroscopy is shown to provide a stringent test of calculated potential energy and ab initio dipole moment surfaces, and therefore transition intensities calculated from first principles. Published by Elsevier Ltd.
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