Journal
JOURNAL OF POWER SOURCES
Volume 379, Issue -, Pages 261-269Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2018.01.046
Keywords
Si nanowires; Cu nanowires; Pre-lithiation; Bilayer fabric; Lithium-ion capacitor
Funding
- Ministry of Science and Technology, Taiwan [NSC 102-2221-E-007-023-MY3, MOST 103-2221-E-007-089-MY3, MOST 103-2622-E-007-025, MOST 102 - 2633-M-007-002]
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A light and binder-free bilayer fabric electrode composed of silicon nanowires and copper nanowires for lithium ion capacitors (LICs) is reported. A lithium ion capacitor is proposed employing pre-lithiated silicon/copper nanowire fabric and activated carbon as the anode and the cathode, respectively. These LICs show remarkable performance with a specific capacitance of 156 F g(-1) at 0.1 A g(-1), which is approximately twice of that of activated carbon in electric double -layer capacitors (EDLCs), and still exhibit a fine specific capacitance of 68 F g(-1) even at a high current density of 20 A g(-1). At a low power density of 193 W kg(-1), the Si/Cu fabric//AC LIC can achieve high energy density of 210 W h kg(-1). As the power density is increased to 99 kW kg(-1), the energy density still remains at 43 W h kg(-1), showing the prominent rate performance.
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