An emerging post-polymerization modification technique: The promise of thiol-para -fluoro click reaction

Synthesis of Activated Ester Functional Polyesters through Light-Induced [4+4] Cycloaddition Polymerization

(2017) Elif Baysak et al.   MACROMOLECULAR CHEMISTRY AND PHYSICS

Para-Fluoro Postpolymerization Chemistry of Poly(pentafluorobenzyl methacrylate): Modification with Amines, Thiols, and Carbonylthiolates

(2017) Janina-Miriam Noy et al.   MACROMOLECULES

Modification of electron deficient polyester via Huisgen/Passerini sequence

(2017) Serter Luleburgaz et al.   POLYMER

The para-fluoro-thiol reaction as a powerful tool for precision network synthesis

(2017) Federica Cavalli et al.   Polymer Chemistry

The para-fluoro-thiol ligation in water

(2017) Hatice Turgut et al.   Polymer Chemistry

Pentafluorobenzene end-group as a versatile handle for para fluoro “click” functionalization of polythiophenes

(2017) Pierre Boufflet et al.   Chemical Science

In situ click chemistry generation of cyclooxygenase-2 inhibitors

(2017) Atul Bhardwaj et al.   Nature Communications

Pentafluorophenyl Ester-Functionalized Nanoparticles as a Versatile Platform for Selective and Covalent Inter-nanoparticle Coupling

(2016) Jimmy Lawrence et al.   ACS Applied Materials & Interfaces

Post-functionalization of perfluorophenyl ester-functional acyclic diene metathesis polymer

(2016) Ozgun Daglar et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Heterofunctionalized Multiarm Star Polymers via Sequential Thiol-para-Fluoro and Thiol-Ene Double “Click” Reactions

(2016) Nese Cakir et al.   MACROMOLECULAR CHEMISTRY AND PHYSICS

Atomically precise organomimetic cluster nanomolecules assembled via perfluoroaryl-thiol SNAr chemistry

(2016) Elaine A. Qian et al.   Nature Chemistry

Accessing libraries of bifunctional block copolymers using two distinct pentafluorophenyl moieties

(2016) Divya Varadharajan et al.   Polymer Chemistry

1,3-Dipolar and Diels–Alder cycloaddition reactions on polyester backbones possessing internal electron-deficient alkyne moieties

(2016) Muge Cetin et al.   Polymer Chemistry

Externally stimulated click reactions for macromolecular syntheses

(2016) Mehmet Atilla Tasdelen et al.   PROGRESS IN POLYMER SCIENCE

Review on recent advances in polythiophene based photovoltaic devices

(2016) Umer Mehmood et al.   RENEWABLE & SUSTAINABLE ENERGY REVIEWS

Activated Ester Containing Polymers: Opportunities and Challenges for the Design of Functional Macromolecules

(2015) Anindita Das et al.   CHEMICAL REVIEWS

On the Orthogonality of Two Thiol-Based Modular Ligations

(2015) Hatice Turgut et al.   CHEMISTRY-A EUROPEAN JOURNAL

Thiol-reactive Passerini-methacrylates and polymorphic surface functional soft matter nanoparticles via ethanolic RAFT dispersion polymerization and post-synthesis modification

(2015) Yiwen Pei et al.   Polymer Chemistry

The Ugi reaction in polymer chemistry: syntheses, applications and perspectives

(2015) Bin Yang et al.   Polymer Chemistry

Thiol-reactive functional poly(meth)acrylates: multicomponent monomer synthesis, RAFT (co)polymerization and highly efficient thiol–para-fluoro postpolymerization modification

(2015) Janina-Miriam Noy et al.   Polymer Chemistry

Intramolecular folding of triblock copolymers via quadrupole interactions between poly(styrene) and poly(pentafluorostyrene) blocks

(2014) Jie Lu et al.   CHEMICAL COMMUNICATIONS

Polymer grafting onto polyurethane backbone via Diels-Alder reaction

(2014) Soykan Agar et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

“Click”-Inspired Chemistry in Macromolecular Science: Matching Recent Progress and User Expectations

(2014) Pieter Espeel et al.   MACROMOLECULES

Wettability adjustment of PVDF surfaces by combining radiation-induced grafting of (2,3,4,5,6)-pentafluorostyrene and subsequent chemoselective “click-type” reaction

(2014) Ludovic Dumas et al.   POLYMER

(Co)polymers of Chlorotrifluoroethylene: Synthesis, Properties, and Applications

(2013) Frédéric Boschet et al.   CHEMICAL REVIEWS

The Thiol-Michael Addition Click Reaction: A Powerful and Widely Used Tool in Materials Chemistry

(2013) Devatha P. Nair et al.   CHEMISTRY OF MATERIALS

Oxime Ligation: A Chemoselective Click-Type Reaction for Accessing Multifunctional Biomolecular Constructs

(2013) Sébastien Ulrich et al.   CHEMISTRY-A EUROPEAN JOURNAL

Post-Functionalization of Polymers via Orthogonal Ligation Chemistry

(2013) Anja S. Goldmann et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Polyfluorinated mercaptoalcohol as a H-bond modifier of poly(2,3,4,5,6-pentafluorostyrene) (PPFS) enhancing miscibility of hydroxylated-PPFS with various acceptor polymers

(2013) Jing Chen et al.   POLYMER

Protecting-group-free synthesis of chain-end multifunctional polymers by combining ATRP with thiol–epoxy ‘click’ chemistry

(2013) Ikhlas Gadwal et al.   Polymer Chemistry

Sequence-controlled copolymers of 2,3,4,5-pentafluorostyrene: mechanistic insight and application to organocatalysis

(2013) John-Paul O'Shea et al.   Polymer Chemistry

Tuning h-bond capability of hydroxylated-poly(2,3,4,5,6-pentafluorostyrene) grafted copolymers prepared by chemoselective and versatile thiol-para-fluoro “click-type” coupling with mercaptoalcohols

(2012) Jing Chen et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Postfunctionalization of polyoxanorbornene via sequential Michael addition and radical thiol-ene click reactions

(2012) Hakan Durmaz et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Standing on the shoulders of Hermann Staudinger: Post-polymerization modification from past to present

(2012) Kemal Arda Günay et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Triple Click Reaction Strategy for Macromolecular Diversity

(2012) Umit Tunca   MACROMOLECULAR RAPID COMMUNICATIONS

Perfluorophenyl-Terpyridine Ruthenium Complex as Monomer for Fast, Efficient, and Mild Metallopolymerizations

(2012) Andreas Wild et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Synthesis and lectin recognition studies of glycosylated polystyrene microspheres functionalized via thiol–para-fluorine “click” reaction

(2012) M. Álvarez-Paino et al.   Polymer Chemistry

Preparation of jellyfish-shaped amphiphilic block-graft copolymers consisting of a poly(ε-caprolactone)-block-poly(pentafluorostyrene) ring and poly(ethylene glycol) lateral brushes

(2012) Tao Cai et al.   Polymer Chemistry

One-pot synthesis of polyamides with various functional side groups via Passerini reaction

(2012) Yao-Zong Wang et al.   Polymer Chemistry

Orthogonal Multifunctionalization of Random and Alternating Copolymers

(2012) Niels ten Brummelhuis et al.   ACS Macro Letters

Functionalized, Biocompatible Coating for Superparamagnetic Nanoparticles by Controlled Polymerization of a Thioglycosidic Monomer

(2011) Krzysztof Babiuch et al.   BIOMACROMOLECULES

Side-Chain Peptide-Synthetic Polymer Conjugates via Tandem “Ester-Amide/Thiol–Ene” Post-Polymerization Modification of Poly(pentafluorophenyl methacrylate) Obtained Using ATRP

(2011) Nikhil K. Singha et al.   BIOMACROMOLECULES

“Clicking” on/with polymers: a rapidly expanding field for the straightforward preparation of novel macromolecular architectures

(2011) Kristian Kempe et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of Terpolymers by Click Reactions

(2011) Ozcan Altintas et al.   Chemistry-An Asian Journal

The combination of living radical polymerization and click chemistry for the synthesis of advanced macromolecular architectures

(2011) Niels Akeroyd et al.   EUROPEAN POLYMER JOURNAL

Introducing Multicomponent Reactions to Polymer Science: Passerini Reactions of Renewable Monomers

(2011) Oliver Kreye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Adhesion of Preosteoblasts and Fibroblasts onto Poly(pentafluorostyrene)-Based Glycopolymeric Films and their Biocompatibility

(2011) Krzysztof Babiuch et al.   MACROMOLECULAR BIOSCIENCE

Double click reaction strategies for polymer conjugation and post-functionalization of polymers

(2011) Hakan Durmaz et al.   Polymer Chemistry

Synthesis and post-polymerization modification of maleimide-containing polymers by ‘thiol-ene’ click and Diels-Alder chemistries

(2011) Daniel J. Hall et al.   POLYMER INTERNATIONAL

Facile Preparation of Nanogels Using Activated Ester Containing Polymers

(2011) Jiaming Zhuang et al.   ACS Macro Letters

“Clicking” Polymers or Just Efficient Linking: What Is the Difference?

(2010) Christopher Barner-Kowollik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, post-modification and self-assembled thin films of pentafluorostyrene containing block copolymers

(2010) Maria Riedel et al.   EUROPEAN POLYMER JOURNAL

Regiospecific nucleophilic substitution in 2,3,4,5,6-pentafluorobiphenyl as model compound for supramolecular systems. Theoretical study of transition states and energy profiles, evidence for tetrahedral SN2 mechanism

(2010) Jaroslav Kvíčala et al.   JOURNAL OF FLUORINE CHEMISTRY

Thiol-yne click chemistry: A powerful and versatile methodology for materials synthesis

(2010) Andrew B. Lowe et al.   JOURNAL OF MATERIALS CHEMISTRY

Metal-free synthesis of responsive polymers: Cloud point tuning by controlled “click” reaction

(2010) C. Remzi Becer et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

A Simple and Efficient Synthesis of Functionalized Cyclic Carbonate Monomers Using a Versatile Pentafluorophenyl Ester Intermediate

(2010) Daniel P. Sanders et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diels-Alder Cycloaddition-Cycloreversion: A Powerful Combo in Materials Design

(2010) Amitav Sanyal   MACROMOLECULAR CHEMISTRY AND PHYSICS

Clickable initiators, monomers and polymers in controlled radical polymerizations – a prospective combination in polymer science

(2010) Ulrich Mansfeld et al.   Polymer Chemistry

Applications of Orthogonal “Click” Chemistries in the Synthesis of Functional Soft Materials

(2009) Rhiannon K. Iha et al.   CHEMICAL REVIEWS

Postpolymerization modification of poly(pentafluorophenyl methacrylate): Synthesis of a diverse water-soluble polymer library

(2009) Matthew I. Gibson et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Synthesis of dendrimers through divergent iterative thio-bromo “Click” chemistry

(2009) Brad M. Rosen et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Synthesis, micelle formation, and bulk properties of poly(ethylene glycol)-b-poly(pentafluorostyrene)-g-polyhedral oligomeric silsesquioxane amphiphilic hybrid copolymers

(2009) H. Hussain et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

HasClick ChemistryLead to a Paradigm Shift in Polymer Material Design?

(2009) Christopher Barner-Kowollik et al.   MACROMOLECULAR CHEMISTRY AND PHYSICS

Clicking Pentafluorostyrene Copolymers: Synthesis, Nanoprecipitation, and Glycosylation

(2009) C. Remzi Becer et al.   MACROMOLECULES

Macromolecular Engineering through Click Chemistry and Other Efficient Transformations

(2009) Brent S. Sumerlin et al.   MACROMOLECULES

Thiol-ene “click” reactions and recent applications in polymer and materials synthesis

(2009) Andrew B. Lowe   Polymer Chemistry

Synthesis of poly(fluorinated styrene)-block-poly(ethylene oxide) amphiphilic copolymers via atom transfer radical polymerization: potential application as paper coating materials

(2009) Khalid A Ibrahim et al.   POLYMER INTERNATIONAL

Synthesis of Functional Polymers by Post-Polymerization Modification

(2008) Marc A. Gauthier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Post-modification of poly(pentafluorostyrene): a versatile “click” method to create well-defined multifunctional graft copolymers

(2008) Christina Ott et al.   CHEMICAL COMMUNICATIONS

Cu-Catalyzed Azide−Alkyne Cycloaddition

(2008) Morten Meldal et al.   CHEMICAL REVIEWS

Controlled synthesis of fluorinated copolymers with pendant sulfonates

(2008) Ivaylo Dimitrov et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Synthesis of Poly(glycidyl methacrylate)-block-Poly(pentafluorostyrene) by RAFT: Precursor to Novel Amphiphilic Poly(glyceryl methacrylate)-block-Poly(pentafluorostyrene)

(2008) Chakravarthy S. Gudipati et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Synthesis of Reactive Telechelic Polymers Based on Pentafluorophenyl Esters

(2008) Peter J. Roth et al.   MACROMOLECULES