Journal
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Volume 353, Issue -, Pages 602-611Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2017.08.002
Keywords
Copper(I) coordination polymer; Mixed-ligand; Solid solution; Antenna effect
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Funding
- JSPS KAKENHI Grant [JP25107513, JP15H00868, JP15K05448]
- Grants-in-Aid for Scientific Research [17K05806, 15K05448] Funding Source: KAKEN
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Luminescent iodido copper(l) coordination polymers [Cu2I2(PPh3)(2)(mu-bpa)(n) and [Cu2I2(PPh3)(2)(mu-bpe)](n) were synthesized and their luminescent properties were clarified (bpa: bis(4-pyridyl)ethane, bpe: transbis(4-pyridyl)ethylene). By taking advantage of their isomorphous relation, mixed-ligand luminescent coordination polymers [Cu2I2(PPh3)(2)(bPa)((1-x))(bPe)(x)](n) were prepared as solid solutions with various ratio of bpa:bpe. The measurements of their photophysical properties revealed that the mixed-ligand complexes are antenna materials where the bpa and bpe sites serve as the donor and the acceptor sites, respectively. (C) 2017 Elsevier B.V. All rights reserved.
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