Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 16, Pages 9137-9143Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01204
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Funding
- Department of Science and Technology (DST), India
- Science and Engineering Research Board (SERB), New Delhi, India
- University Grants Commission (UGC), India
- Council of Scientific and Industrial Research (CSIR), India
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An efficient and transition-metal-free approach for the synthesis of 4-arylquinolines from readily available anilines and alkynes in the presence of K2S2O8 and DMSO has been developed. A variety of alkynes and anilines having a diverse range of substitution patterns can undergo the one-pot cascade process successfully. Effectively, this method uses DMSO as one carbon source, thus providing a highly atom-economical and environmentally benign approach for the synthesis of 4-arylquinolines.
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