Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 15, Pages 8567-8580Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01123
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Funding
- DST-SERB, India [EMR/2014/000978]
- CSIR
- IITM
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A ruthenium(II)-catalyzed cyclization of benzimidates with substituted propargyl alcohols to provide 3,4-disubstituted 1-alkoxy isoquinolines in a highly selective manner via the C-H allenylation is described. The proposed reaction mechanism of the ruthenium(II)-catalyzed cyclization reaction is strongly supported by the isolation of the key ruthenacycle intermediate, deuterium-labeling studies, and detailed DFT calculations including the transition states.
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