Facile synthesis of (E)-β-nitroolefinic alkoxyamines via silver-catalyzed decarboxylative nitroaminoxylation of phenylpropiolic acids

Chemoselective Synthesis of Unsymmetrical Internal Alkynes or Vinyl SulfonesviaPalladium-Catalyzed Cross-Coupling Reaction of Sodium Sulfinates with Alkynes

(2014) Yanli Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition from π Radicals to σ Radicals: Substituent-Tuned Cyclization of Hydrazonyl Radicals

(2014) Xiao-Yong Duan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Functionalization of Amides via Copper-Catalyzed Oxyalkylation of Vinylarenes and Decarboxylative Alkenylation of sp3 C–H

(2014) Hong Yan et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Regio- and Stereoselective Intermolecular Three-Component Oxyarylation of Allenes

(2014) Taisuke Itoh et al.   ORGANIC LETTERS

Stereoselective Intermolecular Nitroaminoxylation of Terminal Aromatic Alkynes: Trapping Alkenyl Radicals by TEMPO

(2014) Hong Yan et al.   ORGANIC LETTERS

Copper-Catalyzed TEMPO Addition to Propargyl Alcohols for the Synthesis of Vinylic Alkoxyamines

(2014) Ye-Won Kang et al.   ORGANIC LETTERS

Aerobic Oxynitration of Alkynes with tBuONO and TEMPO

(2014) Uttam Dutta et al.   ORGANIC LETTERS

Thiosemicarbazone salicylaldiminato palladium(II)-catalyzed alkynylation couplings between arylboronic acids and alkynes or alkynyl carboxylic acids

(2014) Linhua Lu et al.   TETRAHEDRON

Iron-catalyzed decarboxylative methylation of α,β-unsaturated acids under ligand-free conditions

(2014) Guangwei Rong et al.   TETRAHEDRON

Catalytic and direct methyl sulfonylation of alkenes and alkynes using a methyl sulfonyl radical generated from a DMSO, dioxygen and copper system

(2014) Yaojia Jiang et al.   Chemical Science

Decarboxylative Cross-Coupling of Mesylates Catalyzed by Copper/Palladium Systems with Customized Imidazolyl Phosphine Ligands

(2013) Bingrui Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aerobic Oxysulfonylation of Alkenes Leading to Secondary and Tertiary β-Hydroxysulfones

(2013) Qingquan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cu(ii)-catalyzed decarboxylative acylation of acyl C–H of formamides with α-oxocarboxylic acids leading to α-ketoamides

(2013) Dengke Li et al.   CHEMICAL COMMUNICATIONS

Multifunctionalization of alkenes via aerobic oxynitration and sp3 C–H oxidation

(2013) Tsuyoshi Taniguchi et al.   CHEMICAL COMMUNICATIONS

Synthesis of (E)-nitroolefins via decarboxylative nitration using t-butylnitrite (t-BuONO) and TEMPO

(2013) Srimanta Manna et al.   CHEMICAL COMMUNICATIONS

Metal-free nitro-carbocyclization of activated alkenes: a direct approach to synthesize oxindoles by cascade C–N and C–C bond formation

(2013) Tao Shen et al.   CHEMICAL COMMUNICATIONS

Iron-catalyzed direct alkenylation of sp3(C–H) bonds via decarboxylation of cinnamic acids under ligand-free conditions

(2013) Hailong Yang et al.   GREEN CHEMISTRY

A Predictably Selective Nitration of Olefin with Fe(NO3)3 and TEMPO

(2013) Togati Naveen et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient and Stereoselective Nitration of Mono- and Disubstituted Olefins with AgNO2 and TEMPO

(2013) Soham Maity et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dioxygen-Triggered Oxidative Radical Reaction: Direct Aerobic Difunctionalization of Terminal Alkynes toward β-Keto Sulfones

(2013) Qingquan Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Radical Azidooxygenation of Alkenes

(2013) Bo Zhang et al.   ORGANIC LETTERS

Stereoselective Nitration of Olefins with tBuONO and TEMPO: Direct Access to Nitroolefins under Metal-free Conditions

(2013) Soham Maity et al.   ORGANIC LETTERS

Ligand-accelerating low-loading copper-catalyzed effective synthesis of (E)-1,3-enynes by coupling between vinyl halides and alkynes performed in water

(2013) Peng Sun et al.   TETRAHEDRON

An enantioselective tandem reduction/nitro-Mannich reaction of nitroalkenes using a simple thiourea organocatalyst

(2013) James C. Anderson et al.   Chemical Science

Copper-mediated trifluoromethylation of propiolic acids: facile synthesis of α-trifluoromethyl ketones

(2013) Zhengbiao He et al.   Chemical Science

Effects of internal and external carboxylic acids on the reaction pathway of organocatalytic 1,4-addition reactions between aldehydes and nitroolefins

(2013) Jörg Duschmalé et al.   Chemical Science

Oxime Radical Promoted Dioxygenation, Oxyamination, and Diamination of Alkenes: Synthesis of Isoxazolines and Cyclic Nitrones

(2012) Bing Han et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Trifluoromethylaminoxylation of Alkenes

(2012) Yi Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed decarboxylative C(sp2)–C(sp3) coupling reactions via radical mechanism

(2012) Hailong Yang et al.   CHEMICAL COMMUNICATIONS

Radical Cascades Initiated by Intermolecular Radical Addition to Alkynes and Related Triple Bond Systems

(2012) Uta Wille   CHEMICAL REVIEWS

Transition-Metal-Free Oxyarylation of Alkenes with Aryl Diazonium Salts and TEMPONa

(2012) Marcel Hartmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed decarboxylative coupling of aryl halides with alkynyl carboxylic acids performed in water

(2012) Tingyi Li et al.   TETRAHEDRON

Copper-catalyzed decarboxylative C–N coupling for N-arylation

(2012) Yun Zhang et al.   Chemical Science

Catalytic asymmetric synthesis of highly substituted pyrrolizidines

(2012) Andrew D. Lim et al.   Chemical Science

Synthesis of Diarylalkynes by Iron/Copper Co-Catalyzed Decarboxylative spsp2 Coupling of Alkynyl Carboxylic Acids and Aryl Halides

(2011) Tingyi Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Oxidative Nitration of Alkenes with tert-Butyl Nitrite and Oxygen

(2011) Tsuyoshi Taniguchi et al.   ADVANCED SYNTHESIS & CATALYSIS

Pd-Catalyzed Decarboxylative Coupling of Propiolic Acids: One-Pot Synthesis of 1,4-Disubstituted 1,3-Diynes via Sonogashira−Homocoupling Sequence

(2011) Jihye Park et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly effective copper-catalyzed decarboxylative coupling of aryl halides with alkynyl carboxylic acids

(2011) Xiaoming Qu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Orthogonal Enantioselectivity Approaches Using Homogeneous and Heterogeneous Catalyst Systems: Friedel-Crafts Alkylation of Indole

(2010) Hun Young Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An expeditious, highly efficient, catalyst-free and solvent-free synthesis of nitroamines and nitrosulfides by Michael addition

(2010) Garima Choudhary et al.   GREEN CHEMISTRY

Palladium-Catalyzed Intermolecular Decarboxylative Coupling of 2-Phenylbenzoic Acids with Alkynes via C−H and C−C Bond Activation

(2010) Congyang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Vinyl Sulfides by Copper-Catalyzed Decarboxylative C−S Cross-Coupling

(2010) Sadananda Ranjit et al.   ORGANIC LETTERS

Enamine Catalysis with Low Catalyst Loadings - High Efficiency via Kinetic Studies

(2009) Markus Wiesner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Selective and Practical Synthesis of Nitroolefins

(2008) Irina Jovel et al.   ADVANCED SYNTHESIS & CATALYSIS

Carboxylic Acids as Substrates in Homogeneous Catalysis

(2008) Lukas J. Gooßen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly enantioselective conjugate addition of aldehydes to nitroolefins catalyzed by chiral bifunctional sulfamides

(2008) Xue-jing Zhang et al.   CHEMICAL COMMUNICATIONS