Article
Energy & Fuels
Mehran Mirzavandi, Jagar A. Ali, Abbas Khaksar Manshad, Barham Majeed, Barham Sabir Mahmood, Amir H. Mohammadi, Stefan Iglauer, Alireza Keshavarz
Summary: Nanomaterials, specifically silica-graphene quantum dots (Si-GQDs), have been synthesized and dispersed in water to form nanofluids. These nanofluids exhibit significant reduction in interfacial tension and wettability alteration, leading to enhanced oil recovery from carbonate reservoirs. The experimental results show that the nanofluids formulated with 1000 ppm Si-GQDs in distilled water enable an additional 14.4% oil recovery due to the reduction in interfacial tension and contact angle.
Article
Chemistry, Multidisciplinary
Jincan Zhang, Kaicheng Jia, Yongfeng Huang, Xiaoting Liu, Qiuhao Xu, Wendong Wang, Rui Zhang, Bingyao Liu, Liming Zheng, Heng Chen, Peng Gao, Sheng Meng, Li Lin, Hailin Peng, Zhongfan Liu
Summary: The study found that pristine graphene exhibits high hydrophilicity with an average water contact angle of approximately 30 degrees, due to charge transfer between graphene and water molecules. This work provides insight into water-graphene interaction and introduces a new approach for measuring surface properties of 2D materials.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Physical
Izabela M. Barszczewska-Rybarek, Marta W. Chroszcz, Grzegorz Chladek
Summary: The addition of 1 wt.% QA-PEI-NPs is suitable for applications in dental materials, as it ensures sufficient physicochemical and mechanical properties. Changes in most properties were not statistically significant, except for solubility, flexural strength, and impact resistance, which were affected by the concentration of QA-PEI-NPs. The water contact angle values increased slightly, but remained within the range corresponding to hydrophilic surfaces.
Article
Mechanics
Hsin-Yu Chang, Heng-Kwong Tsao, Yu-Jane Sheng
Summary: The wicking dynamics of total wetting liquid in graphene nanocapillaries were explored, and two regimes were identified: inertia-dominated initial spreading and viscous spreading with an exponent greater than Tanner's law. The advancing motions of both the precursor film and main flow were observed, and their lengths were proportional to the square root of time. However, the proportional constant of the precursor film was greater than that of the main flow, and it decreased with increasing channel widths. The thickness of the precursor film and the diameter of curvature of the menisci increased with increasing channel widths, and rapid imbibition behavior was observed in very narrow nanoslits.
Article
Chemistry, Multidisciplinary
Shanshan Yang, Xiao Zhao, Yi-Hsien Lu, Edward S. Barnard, Peidong Yang, Artem Baskin, John W. Lawson, David Prendergast, Miquel Salmeron
Summary: The structure of interfacial water near suspended graphene electrodes in contact with Na2SO4, NH4Cl, and (NH)(2)SO4 solutions has been investigated using confocal Raman spectroscopy, sum frequency vibrational spectroscopy, and Kelvin probe force microscopy. The results showed that SO42- anions preferentially accumulate near the interface at an open circuit potential, creating an electrical field that orients water molecules below the interface. Positive voltages further increased the degree of water molecule orientation and the strength of the electrical double layer, while negative voltages only affected the intensity and frequency of certain water peaks.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Engineering, Environmental
Shaolin Yang, Jinze Li, Cheng Zhen, Fangfang Li, Simiao Sha, Chunping Hou, Hui Lu, Jiandong Wu, Zhilin Sheng, Jinfu Ma
Summary: Oil/water separation can be achieved regardless of the oil/water density relationship by coating melamine sponges with graphene oxide or reduced graphene oxide. The graphene oxide coated sponge selectively absorbs water, while the reduced graphene oxide coated sponge selectively absorbs oil. These coated sponges maintain their original performance in various environments.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Engineering, Chemical
Shaolin Yang, Simiao Sha, Hui Lu, Jiandong Wu, Jinfu Ma, Dewei Wang, Chunping Hou, Zhilin Sheng
Summary: The study presents a low-cost, mild and environmentally friendly method to prepare underwater superoleophobic graphene oxide (GO) and superhydrophobic reduced graphene oxide (rGO) coated fabrics for efficient separation of various oil/water mixtures, showcasing high efficiency and recyclability in harsh environments.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Thermodynamics
Geng Di Sia, Ming Kwang Tan, Gooi Mee Chen, Yew Mun Hung
Summary: By modifying surface wettability with graphene nanoplatelets, coatings can greatly enhance flow boiling heat transfer, with superhydrophilic coatings showing the best performance. The superhydrophilic coatings facilitate fast water permeation and effective filmwise boiling heat transfer, while hydrophobic and superhydrophobic coatings hinder water intercalation and reduce heat transfer rates.
CASE STUDIES IN THERMAL ENGINEERING
(2021)
Article
Forestry
Rami Benkreif, Fatima Zohra Brahmia, Csilla Csiha
Summary: The surface tension of solid wood surfaces affects the wettability and adhesion of various adhesives and wood coatings. This study explores the impact of wood moisture content on contact angle values, finding that increasing moisture content leads to an increase in contact angle (and a decrease in surface tension).
EUROPEAN JOURNAL OF WOOD AND WOOD PRODUCTS
(2021)
Article
Chemistry, Multidisciplinary
Zhiying Li, Tian Shen, Jianxia Gu, Sadaqat Ali Chattha
Summary: This study introduces a simple and cost-effective method for the detection of malachite green (MG) using a fluorescent sensor based on PVP-Au/CuNCs. The sensor exhibited good selectivity and a wide linear detection range for MG in aquatic products. The detection limit of the sensor was found to be 16 nM (S/N = 3), making it a promising alternative to existing MG detection methods.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Electrochemistry
Mohanraj Jagannathan, Durgalakshmi Dhinasekaran, Ajay Rakkesh Rajendran
Summary: Heteroatom-doped graphene structure is an effective platform for electrochemical sensing of DNA. In this study, heteroatoms such as nitrogen, phosphorus, and sulphur were doped into graphene sheets obtained from biomass. The resulting graphene electrodes on paper substrate showed excellent electrochemical sensing response towards calf thymus DNA. The N-doped graphene electrode exhibited high sensitivity for guanine and adenine sensing, with a calculated limit of detection of 227 ng ml(-1) and 322 ng ml(-1), respectively.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2023)
Article
Chemistry, Physical
Jiao Chen, Hanhan Wang, Xing Liu, Xia Han, Honglai Liu
Summary: Regulating the hydrophilic-hydrophobic balance of polymers has a significant impact on their aggregation behavior in aqueous solution, adhesion properties on substrate surfaces, and applications of modified surfaces. By adjusting pH or temperature, the aggregation behavior in aqueous solutions and surface adhesion behavior of copolymers can be regulated. Increasing the hydrophobicity of copolymers enhances surface adsorption and improves oil-water separation performance. Changing the ratio of hydrophilic components in copolymers can tune the properties of coatings, providing a reference for designing coatings in different application environments.
Article
Agricultural Engineering
Bhuvan Vemuri, Vaibhav Handa, Kalimuthu Jawaharraj, Rajesh Sani, Venkataramana Gadhamshetty
Summary: The use of graphene oxide nanoparticles in a consortium based on Thermoanaerobacterium thermosaccharolyticum significantly enhances bio-H-2 production, increasing H-2 yield and conversion efficiency without altering microbial composition.
BIORESOURCE TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Hongxu Gao, Fujian Zhang, Zhen Liu, Yunyun Song, Zhongqiang Zhang, Jianning Ding
Summary: This study introduces a novel multibranch gradient groove structure and successfully achieves long-distance continuous self-transport of mercury droplets through molecular dynamics simulation. The study finds that droplet merging allows for reacceleration of the droplets in the gradient groove, enabling self-transport.
Article
Biochemical Research Methods
Ji Yeon Park, Han Been Lee, Seong Eun Son, Pramod K. Gupta, Yosep Park, Won Hur, Gi Hun Seong
Summary: In this study, we demonstrated the ability of nanozymes to replace natural enzymes in enzyme-based assays for the measurement of biomarkers such as LPC. The synthesized PVP/PtRu nanozymes showed great peroxidase-like activity and high stability, allowing accurate analysis of LPC concentration through absorbance and fluorescence signals.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2023)