Journal
JOURNAL OF MOLECULAR LIQUIDS
Volume 250, Issue -, Pages 229-235Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molliq.2017.11.175
Keywords
Gemini surfactants; Aggregation; Solubilization; Hydrolysis; Micellar catalysis
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Herein, supramolecular systems with improved aggregation, solubilization and catalytic activity have been constructed by self-assembly of gemini surfactants with two cationic centers separated by the spacer chain of 10 atoms long and hydroxyl functionality in their head group or in the spacer. It was found that hydroxylic dicationic surfactants capable of forming hydrogen bonds exhibit the ability to micelle formation at a concentration substantially lower than that of their monocationic and non-functionalized dicationic counterparts. They are capable of initiating additional solubilization mechanisms, which are responsible for the enhanced solubilization capacity of the surfactants. The use of the dicationic hydroxylic surfactants in hydrolytic decomposition of esters gives rise to the high catalytic effect and substrate selectivity: the highest, 430-fold, acceleration was observed for pnitrophenyl caprate. (C) 2017 Elsevier B.V. All rights reserved.
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