Synthesis, microstructures, magnetic properties and thermal stabilities of isotropic alnico ribbons

Reducing the spatial dimension of ferromagnetic (alpha(1)) phase is the most promising route for coercivity enhancement of alnico alloys. It is an experimental fact that the spatial dimension of alpha(1) phase cannot be reduced below a certain limit ( similar to 25 nm) using conventional processing methods. To obtain finer alpha(1) phase we have fabricated alnico ribbons with nominal composition of 32.2Fe-36Co-13.5Ni-7.6Al-6.2Ti-3.8Cu-0.5Zr-0.2B by melt spinning and subsequent heat treatments. Very fine Fe-Co rich (alpha(1)) rods of the order of 5 nm diameter and 100 nm length embedded in Al-Ni rich matrix are obtained. After simplified heat treatment the properties of the isotropic ribbons are H-cj = 770 Oe, B-r = 6.5 kGs and (BH)(max) = 1.86 MGOe. It is shown that alnico ribbons have unprecedented thermal stability described in terms of temperature coefficient of remanence (alpha) and temperature coefficient of coercivity (beta) by measuring magnetic properties at high temperatures ( similar to 800 K). The microstructures of the alloys have been analyzed by Optical Microscope, Scanning Electron Microscope and Transmission Electron Microscope. The phase transition temperatures have been observed by DTA and magnetic properties are measured by PPMS.