4.7 Article

Combined effects of antimony and sodium diethyldithiocarbamate on soil microbial activity and speciation change of heavy metals. Implications for contaminated lands hazardous material pollution in nonferrous metal mining areas

Journal

JOURNAL OF HAZARDOUS MATERIALS
Volume 349, Issue -, Pages 160-167

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2018.01.044

Keywords

Flotation reagent; Combined pollution; Heavy metal speciation; Simulation

Funding

  1. National Science Foundation of China [41430106]
  2. International Key Project from National Science Foundation of China [41720104007]
  3. National Natural Science Foundation of China [41573080, U1402234, 41711530030, 41711530150, 41711530224]
  4. Public Welfare Project of Chinese Ministry of Environmental Protection [201509049]
  5. International Key Project of Ministry of Science and Technology of China [S2016G2135]

Ask authors/readers for more resources

The combined effects of antimony (Sb) and sodium diethyldithiocarbamate (DDTC), a common organic flotation reagent, on soil microbial activity and speciation changes of heavy metals were investigated for the first time. The results showed that the exchangeable fraction of Sb was transformed to a stable residual fraction during the incubation period, and the addition of DDTC promoted the transformation compared with single Sb pollution, probably because DDTC can react with heavy metals to form a complex. In addition, the presence of DDTC and Sb inhibited the soil microbial activity to varying degrees. The growth rate constant k of different interaction systems was in the following order on the 28th day: control group >= single DDTC pollution > combined pollution > single Sb pollution. A correlation analysis showed that the concentration of exchangeable Sb was the primary factor that affected the toxic reaction under combined pollution conditions, and it significantly affected the characteristics of the soil microorganisms. All the observations provide useful information for a better understanding of the toxic effects and potential risks of combined Sb and DDTC pollution in antimony mining areas.

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