Journal
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 509, Issue -, Pages 334-345Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2017.09.031
Keywords
Precursors; Homogeneously dispersed; CuO-CoOx/gamma-Al2O3; Synergistic effect; NO reduction by CO
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Funding
- National Natural Science Foundation of China [21677069]
- Guangdong Natural Science Foundation [2015A030310195]
- Distinguished Young Talents Foundation in Higher Education of Guangdong [2013LYM_0054]
- Doctoral Special Foundation of Lingnan Normal University [ZL1201]
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Catalytic reduction of NO by CO was studied over a series of CuO-CoOx/gamma-Al2O3 catalysts prepared by co-impregnation with different copper and cobalt precursors (acetate and nitrate) to evaluate the structure-activity relationship. The obtained samples were characterized in detail by means of XRD, LRS, XPS, H-2-TPR and in situ FT-IR technologies. Results indicate that copper oxide is agglomerated while cobalt oxide is dispersed on gamma-Al2O3 for the catalyst prepared from copper acetate and cobalt acetate precursors (CuACoA); CuxCo(3-x)O(4) spinel is formed and agglomerated on the catalyst prepared from copper nitrate and cobalt nitrate precursors (CuNCoN); while both copper oxide and cobalt oxide could be homogeneously dispersed for the catalyst prepared from copper nitrate and cobalt acetate precursors (CuNCoA), which exhibits the best activity for NO reduction by CO. Probably the synergistic effect between dispersed copper oxide and cobalt oxide is propitious to the oxygen transfer, which could be the reason for its high activities. Finally, a possible reaction mechanism was tentatively proposed to explore the different catalytic performances in NO reduction by CO model reaction. (C) 2017 Elsevier Inc. All rights reserved.
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