4.4 Article

Glutathione Functionalized Gold Nanoparticles as Efficient Surface Enhanced Raman Scattering Substrate for Poly Chlorinated Biphenyl Detection

Journal

JOURNAL OF CLUSTER SCIENCE
Volume 29, Issue 2, Pages 281-287

Publisher

SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10876-017-1323-9

Keywords

PCBs; Rangeland soil extract; GSH-Au NPs; Surface plasmon; SERS

Funding

  1. Department of Science and Technology-WOS-A, New Delhi, India [SR/WOS-A/PS-40/2013]
  2. DST-SERB, New Delhi, India [EMR/2015/000320]

Ask authors/readers for more resources

Polychlorinated biphenyls (PCBs) are harmful even at trace level in the environment, and they are difficult to detect. This work presents a simple method for preparation of glutathione (GSH) functionalized gold nanoparticles (Au NPs) (GSH-Au NPs) for the detection of PCBs and its isomers based on surface enhanced Raman scattering (SERS). The prepared Au NPs show the surface plasmon band around 533 nm. The crystallinity and formation of GSH-Au NPs were confirmed by using X-ray diffraction and vibrational studies. Transmission electron microscopic analysis showed the average particle size of GSH-Au NPs is around 16 nm. The morphology of the GSH-Au NPs indicates dumbbell-shaped structures with hot spots present. These hot spots increase the SERS activity significantly. Gas chromatography-mass spectrum showed that the soil extract contained PCBs, which, has also been detected using SERS. SERS based detection is simple and powerful for identifying the PCBs, as established here for PCBs in the real soil sample.Hence, from this investigation, a rapid, sensitive, cost-effective sensing method for detecting toxic PCBs in the environment was demonstrated.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.4
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Physical

Application of G-SERS for the efficient detection of toxic dye contaminants in textile effluents using gold/graphene oxide substrates

V. Poornima Parvathi, R. Parimaladevi, Vasant Sathe, M. Umadevi

JOURNAL OF MOLECULAR LIQUIDS (2019)

Article Chemistry, Physical

Environmental photochemistry by plasmonic semiconductor decorated GO nanocomposites: SERS detection and visible light driven degradation of aromatic dyes

V. Poornima Parvathi, R. Parimaladevi, Vasant Sathe, M. Umadevi

APPLIED SURFACE SCIENCE (2019)

Article Chemistry, Physical

Antibacterial and electrochemical activities of silver, gold, and palladium nanoparticles dispersed amorphous carbon composites

P. M. Anjana, M. R. Bindhu, M. Umadevi, R. B. Rakhi

APPLIED SURFACE SCIENCE (2019)

Article Engineering, Chemical

Enhanced photocatalytic degradation of textile dyeing wastewater under UV and visible light using ZnO/MgO nanocomposites as a novel photocatalyst

Bhaviya R. Raj, M. Umadevi, R. Parimaladevi

PARTICULATE SCIENCE AND TECHNOLOGY (2020)

Article Chemistry, Multidisciplinary

Built-in Electric Field Assisted Photocatalytic Dye Degradation and Photoelectrochemical Water Splitting of Ferroelectric Ce Doped BaTiO3 Nanoassemblies

P. Senthilkumar, D. Arockiya Jency, T. Kavinkumar, D. Dhayanithi, S. Dhanuskodi, M. Umadevi, S. Manivannan, N. V. Giridharan, V. Thiagarajan, M. Sriramkumar, K. Jothivenkatachalam

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Materials Science, Biomaterials

Plasmonic silver nanospheres embedded ε-caprolactone/reduced graphite oxide nanolayers as active SERS substrates

Poornima Parvathi Veerabaghu, Parimaladevi Ramasamy, Vasanth Sathe, Anbarasan Ramasamy, Umadevi Mahalingam

MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS (2019)

Article Biochemistry & Molecular Biology

Antimicrobial and catalytic activities of biosynthesized gold, silver and palladium nanoparticles from Solarium nigurum leaves

C. Vijilvani, M. R. Bindhu, F. C. Frincy, Mohamad S. AlSalhi, S. Sabitha, K. Saravanakumar, Sandhanasamy Devanesan, M. Umadevi, Mamduh J. Aljaafreh, Muhammad Atif

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY (2020)

Article Materials Science, Multidisciplinary

Enhanced bioactivity of Fe3O4-Au nanocomposites - A comparative antibacterial study

Arockia D. Jency, K. Sathyavathi, Umadevi Mahalingam, Parimaladevi Ramasamy

MATERIALS LETTERS (2020)

Article Materials Science, Multidisciplinary

Novel silver nanoparticles/activated carbon co-doped titania nanoparticles for enhanced antibacterial activity

V. Poornima Parvathi, M. Umadevi, R. Sasikala, R. Parimaladevi, V. Ragavendran, J. Mayandi, G. V. Sathe

MATERIALS LETTERS (2020)

Article Polymer Science

Effect of ZnO/Ag Nanocomposites Against Anionic and Cationic Dyes as Photocatalysts and Antibacterial Agents

Ramaraj Bhaviya Raj, Mahalingam Umadevi, Ramasamy Parimaladevi

Summary: Efficient, strong and cost-effective nanoparticles with inhibitory activities are in high demand. Synthesis of ZnO/Ag NCs through doping strategies resulted in materials with small particle size, high surface area, and excellent photocatalytic and antibacterial properties, making them promising for practical applications.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2021)

Article Chemistry, Physical

Hollow Gold Nanosphere Templated Synthesis of PEGylated Hollow Gold Nanostars and Use for SERS Detection of Amyloid Beta in Solution

A'Lester C. Allen, Mekedlawit Efrem, Umadevi Mahalingam, Melissa Guarino-Hotz, Alejandro R. Foley, Jevgenij A. Raskatov, Chengyu Song, Sarah A. Lindley, Jing Li, Bin Chen, Jin Z. Zhang

Summary: Hollow gold nanospheres were used as templates for the growth of multibranched hollow gold nanostars, with control of the localized surface plasmon resonance achieved through manipulation of core size and spike length. Conjugation of A beta to HNS enabled detection through vibrational modes, demonstrating the potential for rapid disease detection.

JOURNAL OF PHYSICAL CHEMISTRY B (2021)

Article Environmental Sciences

Environmental photochemistry with thiol- and silica-modified plasmonic nanocomposites: SERS sensing of municipal solid waste and tannery waste leachate from groundwater

Aarthi Avadaiappan, Smonia Joe Princy Soosai Antony, Bindhu Franci, Umadevi Mahalingam, Parimaladevi Ramasamy, Hentry Conchalish, Vasant Sath

Summary: Mismanagement of obsolete solid waste can have a damaging impact on the environment, particularly in terms of open trash disposal contaminating water bodies. The waste management act aims to prevent harmful effects on living organisms by implementing waste prevention, processing, and disposal principles. Surface-enhanced Raman scattering (SERS) technology enhances the detection of environmental pollutants, such as hazardous chemicals.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2022)

Article Materials Science, Multidisciplinary

Environmental Remediation of Real Textile Dyeing Wastewater Under Visible Light and Inactivation of Pathogenic Bacteria Using ZnO/CuO Nano-Needles

Bhaviya Raj Ramaraj, Umadevi Mahalingam, Parimaladevi Ramasamy, Joshua M. Pearce, Jeyanthinath Mayandi, Anuratha Mahalingam

Summary: Textile industries play an important role in a country's economy, but they consume large amounts of water and produce volumes of wastewater. This study evaluates the use of eco-friendly and low-cost zinc oxide/copper oxide nanocomposites for degrading organic pollutants and antibacterial activity. The presence of CuO in the nanocomposites enhances their catalytic properties, and they also exhibit high antibacterial activity. The experimental characteristics of the nanocomposites can be explained by the combination of electronic band structure due to size effect and tuning metal oxide proportions.

PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE (2023)

Article Polymer Science

A Negatively Charged Hydrophobic Hemi-micelle of Fe3O4/Ag MNP Role Towards SERS, Photocatalysis and Bactericidal

A. Aarthi, M. Umadevi, R. Parimaladevi, G. V. Sathe, S. Arumugam, P. Sivaprakash

Summary: The study reports the surface enhanced Raman scattering (SERS), photocatalytic, and antibacterial activities of Fe3O4/Ag magnetic nano particles. The synthesized Fe3O4/Ag MNP is characterized by various techniques and shows promising properties for potential applications in environmental pollution, human medicine, and contaminated drinking water. The presence of Fe3O4 NPs improves the catalytic degradation efficiency of Ag NPs.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2021)

Article Chemistry, Multidisciplinary

Fluorinated TiO2-doped, glycine-functionalized MWCNTs for high-performance antibacterial agents

Umadevi Mahalingam, Poornima P. Veerabaghu, Sangari Mayavan, Parimaladevi Ramasamy

CARBON LETTERS (2019)

No Data Available