4.6 Article

Capillary breakup extensional rheometry of associative and hydrolyzed polyacrylamide polymers for oil recovery applications

Journal

JOURNAL OF APPLIED POLYMER SCIENCE
Volume 135, Issue 22, Pages -

Publisher

WILEY
DOI: 10.1002/app.46253

Keywords

oil and gas; rheology; viscosity and viscoelasticity

Funding

  1. Natural Sciences and Engineering Research Council of Canada (NSERC)
  2. University of Alberta
  3. Canada Foundation for Innovation (CFI) [32727]
  4. AB Innovation and Advanced Education Research Capacity Program Small Equipment Grants

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High molecular weight polymers used for heavy oil recovery exhibit viscoelasticity that can influence the oil recovery during chemical enhanced oil recovery. Different polymers having similar molecular weight and shear rheology may have different elongation flow behavior depending on their extensional properties. Displacing slugs are more likely to stretch than shear in tortuous porous media. Therefore, it is critical to seek an analytical tool that can characterize extensional parameters to improve polymer selection criteria. This article focuses on the extensional characterization of two polymers (hydrolyzed polyacrylamide and associative polymer) having identical shear behavior using capillary breakup extensional rheometer to explain their different porous media behavior. Maximum extensional viscosity at the critical Deborah number and Deborah number in porous media classified the associative polymer as the one having high elastic-limit. Extensional characterization results were complemented by significantly higher pressure drop, marginally increased oil recovery of associative polymer in porous media. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46253.

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