4.6 Article

Poly(methyl methacrylate)-epoxy vitrimer composites

Journal

JOURNAL OF APPLIED POLYMER SCIENCE
Volume 135, Issue 22, Pages -

Publisher

WILEY
DOI: 10.1002/app.46307

Keywords

applications; mechanical properties; thermal properties

Ask authors/readers for more resources

In this study, we synthesized poly(methyl methacrylate) (PMMA) epoxy vitrimer composites by doping methyl methacrylate (MMA) and benzoyl peroxide into a curing system of epoxy resin and citric acid. The vitrimer composites were characterized with dynamic mechanical thermal analysis, scanning electron microscopy, and stress-relaxation and lap-shear testing. The test results show that with increasing amount of MMA, the existence of PMMA in the epoxy vitrimer matrix in the form of intermiscible, slightly soluble, and phase separation became more evident. When the doping amount of PMMA reached 10-25 wt %, the bonding strength of the PMMA-epoxy vitrimer composites was about two times that of the epoxy vitrimer (from 2.3 to 4.3 MPa). This showed that the self-healing strength of the vitrimer composites was better than that of the pure vitrimer. When the PMMA in the epoxy matrix was in a slightly soluble form, the linear PMMA improved the mechanical properties of the epoxy vitrimer by physical winding. At the same time, the doping of PMMA promoted the transesterification rate of the epoxy vitrimer and enhanced the bonding strength of the composites without lowering the epoxy vitrimer glass-transition temperature. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46307.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available