4.7 Article

Role of microstructure on electrochemical hydrogen permeation properties in advanced high strength steels

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 43, Issue 24, Pages 10905-10914

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2018.04.241

Keywords

Retained austenite; Phase interfaces; Hydrogen diffusion; Trapping sites density; Steels

Funding

  1. National Key R&D Program of China [2017YFB0703003]
  2. National Natura Science Foundation of China [U1564203, 51571141, 51201105]
  3. Interdisciplinary Program of Shanghai Jiao Tong University [YG2014MS23]
  4. Program of Shanghai Academic Research Leader
  5. Shanghai Key Laboratory of Materials Laser Processing and Modification, Shanghai Jiao Tong University
  6. Tescan China company
  7. Baosteel company

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The hydrogen permeation process in steels is closely associated with the microstructure of steels that greatly affect hydrogen trapping and hydrogen diffusion behaviors. In this study, the electrochemical hydrogen permeation experiment using a modified Devanathan-Stachurski (D-S) cells was employed to evaluate the hydrogen permeation properties in advanced high strength steels with four types of microstructures (from single phase, dual phase to complex phase). Results showed that both phase interfaces and retained austenite (RA) could act as the trapping sites for hydrogen and consequently reduced the hydrogen diffusion coefficient in steels. Furthermore, it was suggested that the role of RA on hydrogen trapping behaviors depended on its morphology. Finally, the lattice diffusion coefficient (DL) in each steel was determined and the correlations between the microstructure in steels and hydrogen evolution reaction (HER) kinetics were also investigated. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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