4.4 Article

Synthesis of Porous Fiber-like CoMn2O4 Derived from Cotton Template as Lithium Ion Battery Anodes

Journal

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
Volume 13, Issue 2, Pages 1505-1514

Publisher

ESG
DOI: 10.20964/2018.02.57

Keywords

Cotton template; porous fiber-like CoMn2O4; lithium ion battery; anode materials

Funding

  1. Scientific Start Foundation of Longyan University [LB2014001]
  2. Provincial Science and Technology Department for Provincial Colleges and Universities Program [JK2015047]

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Porous fiber-like CoMn2O4 has been prepared by a cotton template route. The fiber-like CoMn2O4 with hausmannite-type structure is composed of numerous nanoparticles with an average size of similar to 100 nm. A Brunauer-Emmett-Teller (BET) surface area of 12.28 m(2) g(-1) and mesoporous structure can be calculated from N-2 adsorption-desorption isotherms for porous fiber-like CoMn2O4. As anode of lithium ion battery, the CoMn2O4 obtained from 600 degrees C shows a reversible discharge capacity of 867.0 mAh g(-1) and a capacity retention ratio of 86.8% after 60 cycles at a current rate of 200 mA g(-1). Even at a high rate of 1 A g(-1), the sample still delivers a stable discharge capacity of 546.0 mAh g(-1). These promising electrochemical performances could be attributed to the unique porous fiber structure of CoMn2O4.

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