Journal
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
Volume 13, Issue 6, Pages 6048-6058Publisher
ESG
DOI: 10.20964/2018.06.26
Keywords
Hierarchical structure; Cr2O3/N-doped carbon composite; Bio-template method; Li-ion battery
Categories
Funding
- International Science & Technology Cooperation Program of China [2016YFE0115100]
- National Natural Science Foundation of China [21771060, 61271126, 21305033]
- Program for Science and Technology Project of Heilongjiang province [B201414]
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A green and facile bio-template method was developed to synthesize porous hierarchical Cr2O3/Ndoped carbon (denoted as Cr2O3/NC) composite using egg-shell membrane as template and carbon source. The as-prepared Cr2O3/NC composite is assembled from interwoven and coalesced porous microfibers. The microfibers are constructed by Cr2O3 nanoparticles uniformly encapsulated 1D porous N-doped carbon matrix. Importantly, the as-prepared Cr2O3/NC electrode shows a superior Li-ion battery anodic performance. Under a current density of 100 mA g(-1), the Cr2O3/NC sample has a specific discharge capacity of 640 mA h g(-1) after 100 cycles. Moreover, after 50 cycles at a high current density of 1000 mA g(-1), the sample exhibits a discharge capacity of 368 mA h g(-1). The outstanding Li-storage performance of the composite should be attributed to the stable porous hierarchical structure, large specific surface area and highly conductive N-doped carbon matrix.
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