Journal
INORGANIC CHEMISTRY
Volume 57, Issue 3, Pages 899-902Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.7b01992
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Funding
- National Key R&D Program of China [2017YFC1103800]
- NSFC [U1663225, U1662134, 51472190, 51611530672, 51503166]
- ISTCP [2015DFE52870]
- PCSIRT [IRT_15R52]
- HPNSF [2016CFA033, 2017CFB487]
- BMBF [OptiMat 03SF0492C]
- DAAD through PPP Project [57053987]
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The metal-organic framework (MOF) MIL-101Cr was readily encapsulated by a very thin shell (around 30 nm) of hydrophobic mesoporous silica, which replicates the irregular shape of the MOF nanocrystals. Such a silica shell facilitates the diffusion of hydrophobic reactants with enhancement of the catalytic activity of the MOF and significantly improved catalytic stability of the MOF in the oxidation of indene.
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