Journal
INORGANIC CHEMISTRY
Volume 57, Issue 5, Pages 2925-2932Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b00038
Keywords
-
Categories
Funding
- Sichuan Provincial Education Department [16ZB0133]
- Longshan academic talent research supporting program of SWUST [17LZX324]
- Sichuan Provincial Science and Technology Department [2016TD0014]
- NSFC [21602182]
Ask authors/readers for more resources
A selective mono-/tetraacetoxylation of o-carboranes with acetic acid via cross dehydrogenative coupling of cage B-H/O-H bonds has been developed, and a series of mono- and tetraacetoxylated o-carboranes have been synthesized with moderate to good yields as well as good selectivity. Mechanistic studies indicate that the acetoxyl originates from acetic acid directly, and a nucleophilic addition of Pd-IV-oxo species and dehydration process is proposed.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
