4.6 Article

Comments on the Artificiality of Actual Amount Adsorbed

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 57, Issue 19, Pages 6766-6773

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.8b00852

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The artificiality of the actual amount adsorbed (AAA) estimated from the experimentally measured Gibbsian surface excess (GSE) of a gas is discussed. The use of AAA for calculation of isosteric heat of adsorption or mixed gas adsorption isotherms using ideal adsorbed solution theory can be misleading and incorrect. The GSE, on the other hand, can be unambiguously used to describe all practical aspects of adsorption science and technology.

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