4.3 Article

Nitrogen-doped three-dimensional graphene-supported platinum catalysts for polymer electrolyte membrane fuel cells application

Journal

FUNCTIONAL MATERIALS LETTERS
Volume 11, Issue 1, Pages -

Publisher

WORLD SCIENTIFIC PUBL CO PTE LTD
DOI: 10.1142/S1793604718500157

Keywords

Catalyst; carbon materials; fuel cell; graphene; nanoparticles

Funding

  1. National Natural Science Foundation of China [21476031, 51602031]
  2. Jiangsu Natural Science Foundation [BK20151187]
  3. Priority Academic Program Development of Jiangsu Higher Education Institutions [17KJA430002]
  4. Applied Basic Research Programs of Changzhou [CJ20179020]
  5. Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP)
  6. Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)

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Catalysts are a key component of polymer electrolyte membrane fuel cells (PEMFCs). In this work, nitrogen-doped three-dimensional graphene-supported platinum (Pt-3DNG) catalysts are successfully prepared and characterized. SEM and TEM images show the Pt nanoparticles are uniformly dispersed in the sheets of nitrogen-doped 3DNG. Compared with that of the commercial Pt/C catalysts, Pt-3DNG show much better oxygen reduction reaction (ORR) activity and cycling stability, and the reduction in limit current density after 1000 cycles is only about 1.6% for the Pt-3DNG catalysts, whereas 7.2% for the commercial Pt/C catalysts. The single cell using Pt-3DNG catalysts in both the anode and the cathode show a higher peak power density (21.47mW cm(-2)) than that using commercial Pt/C catalysts (20.17mW cm(-2)) under the same conditions. These properties make this type of catalyst suitable for the application in PEMFCs.

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