Article
Energy & Fuels
Jia-Hao Li, Xian-Yong Wei, Zheng Yang, Dao-Guang Teng, Li Li, Zhuang Li, Zi-Chun Fan, Qian-Qian Kong, Ji Zhao, Kun-Lang Lu, Fan Yin, Zhi-Min Zong
Summary: In this study, a dynamic combined strategy of extraction, column chromatography, and catalytic hydroconversion was used to prepare cyclohexanol from crude phenols derived from low temperature coal tar, as well as to enrich condensed arenes. The results showed that phenol can be completely converted to cyclohexanol under specific conditions, with a high selectivity of 99.9%. The nickel-supported nitrogen-doped carbon material played a crucial role in the hydrogenation of aromatic rings through its strong adsorption ability and effective activation of hydrogen.
Article
Chemistry, Multidisciplinary
Zhitao Sun, Wei Fan, Yi Han, Wei Yuan, Yong Ni, Jinyi Wang, Haipeng Wei, Yanli Zhao, Zhe Sun, Jishan Wu
Summary: This study presents a one-pot synthesis of twisted polyarenes using nickel-catalyzed cyclo-oligomerization reactions. The highly twisted helical structures consist of equal parts left- and right-handed enantiomers. Chiral resolution yielded two stable enantiomers with absorption dissymmetry factors of around 0.008-0.009.
Article
Engineering, Chemical
Wei Jiang, Jing-Pei Cao, Zi-Meng He, Chen Zhu, Xiao-Bo Feng, Xiao-Yan Zhao, Yun-Peng Zhao, Hong-Cun Bai
Summary: This study investigates a series of catalysts supported on a-Al2O3 and prepared with different metals for the hydrogenation of lignin derivatives at room temperature. Rh-1/a-Al2O3 catalyst exhibits the highest reaction rate and TOF value for diphenyl ether and toluene conversion. Characterization results suggest that dispersed Rh nanoparticles on a-Al2O3 support are responsible for hydrogen activation/dissociation and subsequent arenes hydrogenation. DFT calculation shows the stronger adsorption capacity of toluene and guaiacol on Rh (200) compared to Rh (111) and Rh (220). Stable Rh-1/a-Al2O3 catalyst contributes to the improvement of lignin derivatives hydrogenation at room temperature, promoting the production of high-value-added platform chemicals.
CHEMICAL ENGINEERING SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Yizhou Yang, Yuliang Xu, Huadong Wang
Summary: Non-metal-catalyzed hydrogenation of arenes is a sustainable and environment-friendly approach for the synthesis of cyclohexane derivatives. In this study, a borenium-ion catalyst system was developed to effectively hydrogenate monocyclic arenes. Moreover, the metal-free catalytic system allows for selective partial or full hydrogenation of naphthalene and anthracene by modifying the reaction conditions. Mechanism studies suggest that the H2 splitting mediated by borenium-arene occurs before the rate-limiting step, and hydride transfer between the resulting neutral borane and protonated arene is likely the rate-limiting step in the catalytic process.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Gabriele Hierlmeier, Paolo Tosatti, Kurt Puentener, Paul J. J. Chirik
Summary: This study reports a new molybdenum ligand for catalyzing the hydrogenation of benzene, which is formed by the coordination of phosphino(imino)pyridine and cyclooctadiene. The experimental results indicate that the ligand can selectively generate cyclohexane catalyst in the presence of benzene, and the formation of the insertion product is a key step.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Feng Yu, Renqing Tao, Lan Gan, Hao Ni, Qi-Kai Kang, Guixia Liu, Zheng Huang
Summary: Here we report a one-pot relay bicatalysis system for constructing C-aryl-C-alkyl bonds using (pincer)Ir-catalyzed alkane transfer dehydrogenation and Fe(OTf)(3)-catalyzed olefin hydroarylation. This system exhibits broad scope and high selectivity for the alkylation of arenes with arylalkanes, making it potentially useful for late-stage alkylation of complex molecules. Experimental mechanistic data provide insights into the factors controlling the regioselectivity.
CHINESE JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Zeming Xia, Sai Ho Pun, Han Chen, Qian Miao
Summary: New strategies for designing and synthesizing unprecedented zigzag carbon nanobelts have been reported, demonstrating their structure and binding properties with C60 in solution. The formation of multiple carbon-carbon bonds through Scholl reactions, as well as the increase in strain during the ladderization process of these nanobelts through Scholl reactions, were successfully validated in this study.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Rafal Kusy, Karol Grela
Summary: In this review, recent advances in the application of metal nanoparticles in the selective hydrogenation of C-C double bonds are presented. The reduction methods of alkenes, arenes, and aromatic heterocycles are focused on and classified according to the transition metals used as catalysts. Most of the described systems involve direct hydrogenation, which is important for industrial processes. Additionally, convenient transfer hydrogenation protocols have been developed for laboratory purposes. Some methods exhibit excellent chemoselectivity, making them ideal for synthesizing compounds with reducible functional groups. The use of earth-abundant metals as catalysts has also been explored.
CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY
(2022)
Article
Multidisciplinary Sciences
Wei Zhang, Sungmin Kim, Lennart Wahl, Rachit Khare, Lillian Hale, Jianzhi Hu, Donald M. Camaioni, Oliver Y. Gutierrez, Yue Liu, Johannes A. Lercher
Summary: We propose a unique approach to selectively upcycle polyolefin waste by utilizing a highly ionic reaction environment, which increases polymer reactivity and reduces energy required for breaking carbon-carbon bonds. By catalyzing endothermic cleavage and exothermic alkylation reactions, we are able to convert polyethylene and polypropylene to liquid isoalkanes at temperatures below 100 degrees C. This process offers a high yield conversion of unprocessed postconsumer items into high-quality liquid alkanes.
Article
Chemistry, Organic
Xian-Tao Wu, En-Kai Xiao, Feng Ma, Jin Yin, Jie Wang, Peng Chen, Yi-Jun Jiang
Summary: A general, efficient, and substrate-controlled regiodivergent trifluoroacetylation of carbazoles has been developed through Friedel-Crafts acylation. This method is applicable to a wide range of readily available substituted carbazoles, achieving yields of up to 99%, and illustrates the impact of different substituents on the products. Additionally, this approach enables the synthesis of chlorodifluoroacetylated and pentafluoropropionylated carbazoles for the first time.
JOURNAL OF ORGANIC CHEMISTRY
(2021)
Article
Chemistry, Organic
Yukihiro Motoyama, Kenta Ohnishi, Hayato Shibuya, Prerna Joshi, Masamichi Yoshimura
Summary: The combination of Karstedt's catalyst or Pt(dba)(2) with activated carbon is an efficient catalyst system for the arene hydrogenation of functionalized aromatic compounds. The reaction proceeds at ambient temperature under atmospheric hydrogen pressure, resulting in high yields of carbo- and heterocyclic compounds without metallic contamination. The addition of activated carbon or vinyl siloxane derivatives is crucial for sustaining the catalytic activity and effective trapping of platinum species after the reaction.
ASIAN JOURNAL OF ORGANIC CHEMISTRY
(2023)
Review
Chemistry, Inorganic & Nuclear
Koji Yamamoto, Tsuyoshi Sugawa, Tetsuro Murahashi
Summary: This review summarizes the coordination behavior of fused benzene ring hydrocarbons (FBHs) in di- or multinuclear metal complexes, particularly focusing on their coordination modes to multinuclear metal moieties.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Chemistry, Organic
Tobias Krueger, Torsten Linker
Summary: A convenient method for the synthesis of gamma-spirolactams in only three steps is described, with good efficiency. The synthesis can be carried out from inexpensive and commercially available aromatic carboxylic acids, yielding products with good stereoselectivities.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
(2021)
Article
Chemistry, Organic
Tobias Krueger, Andrea Bramborg, Alexandra Kelling, Eric Sperlich, Torsten Linker
Summary: A convenient method for the synthesis of gamma-spirolactones in only 2-3 steps has been described, resulting in more than 30 new compounds. The process involves Birch reduction of aromatic carboxylic acids followed by direct lactonization, and subsequent hydrogenation with Pd/C catalyst. The method allows for the construction of up to 3 new stereogenic centers from achiral benzoic acids.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
(2021)
Article
Environmental Sciences
Chukwujindu M. A. Iwegbue, Ernest Bebenimibo, Grace Obi, Godswill O. Tesi, Chijioke Olisah, Francis E. Egobueze, Bice S. Martincigh
Summary: This study provides data on the characteristic levels, spatial patterns, sources, and risk of n-alkanes and polycyclic aromatic hydrocarbons in surficial sediments from the Escravos River Basin in Nigeria. The concentrations of these compounds in sediments exceeded guideline values, indicating potential ecological and health risks. The study suggests that these compounds mainly originate from petroleum sources and combustion emissions.
ARCHIVES OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Qiu-ju Huang, Guo-chao Liao, Xue-rong Zhuang, Meng-lan Yang, Jing-jing Yao, Jian-hua Deng, Yan-min Zhang, Ying Wang, Xiao-xiao Qi, Dong-feng Pan, Yang Guan, Zhi-ying Huang, Feng-xue Zhang, Zhong-qiu Liu, Lin-lin Lu
Summary: The study demonstrates the significant improvement in the properties of FTS by conjugating it with IR783, enhancing its anti-cancer potential and tumor-targeting ability. The conjugate shows superior therapeutic effects in breast cancer cells, increasing drug bioavailability and targeting through various pathways.
ACTA PHARMACOLOGICA SINICA
(2022)
Article
Engineering, Environmental
Meijia Sun, Baokuan Li, Zhongqiu Liu, Lixin Tang
Summary: The study investigates the transient multiscale bubble behaviors in the electrolysis process of CuSO4 aqueous solution under the anode, demonstrating bubble nucleation, growth, collision, and detachment. The experimental and numerical methods reveal the characteristics of bubbles and their interactions. Results show that controlling current and anode inclination angle can affect bubble velocity and diameter.
CHEMICAL ENGINEERING JOURNAL
(2022)
Review
Pharmacology & Pharmacy
Dan Liu, Qi Yu, Qing Ning, Zhongqiu Liu, Jie Song
Summary: UGT1A1 is the only enzyme capable of metabolizing detoxified bilirubin, and its inactivation can lead to diseases like GS and CN. UGT1A1 polymorphisms may be associated with neurological diseases, hepatobiliary diseases, cardiovascular diseases, etc., with ongoing research in this area.
DRUG METABOLISM REVIEWS
(2022)
Article
Chemistry, Applied
Peng Hong, Limin Wang, Linsheng Bai, Zhongqiu Liu, Yujing Liu, Jianguo Yang, Anguo Ying
Summary: In this study, SPA and 1-vinyl-3-ethylimidazole were grafted onto Polyacrylonitrile fiber using RAFT, forming an intelligent photo-responsive catalyst for efficient water oxidation of benzyl alcohol. The reversible light-responsive property of SPA allows for recycling of the catalyst without the need for volatile organic solvents, demonstrating potential for scalable production.
Review
Energy & Fuels
Dan Zhang, Huan He, Yi Ren, Rizwan Haider, Michael Urynowicz, Paul H. Fallgren, Song Jin, Muhammad Ishtiaq Ali, Asif Jamal, Muhammad Adnan Sabar, Hongguang Guo, Fang-Jing Liu, Zaixing Huang
Summary: Coalbed methane (CBM) has significant environmental and economic value in addition to energy content. Chemical pretreatment of coal can enhance bioconversion rate and promote further development of CBM resources.
Article
Energy & Fuels
Zaixing Huang, Fangjing Liu, Mingchen Tang, Yangyan Gao, David M. Bagley, Xin He, Alexander Goroncy, Maohong Fan
Summary: Coal has potential applications in water treatment, effectively removing cations, anions, organic carbon, and suspended solids simultaneously.
INTERNATIONAL JOURNAL OF COAL SCIENCE & TECHNOLOGY
(2022)
Article
Biotechnology & Applied Microbiology
Jia Huang, Yaru She, Jingyang Yue, Yidu Chen, Yu Li, Jing Li, Yonger Hu, Deying Yang, Jiabo Chen, Lu Yang, Zhongqiu Liu, Ruibo Wu, Pengfei Jin, Lixin Duan
Summary: Anemarrhena asphodeloides, a popular medicinal herb in China, contains mangiferin which has various pharmacological activities. A promiscuous C-glycosyltransferase (AaCGT) was identified from Anemarrhena asphodeloides, which was capable of catalyzing mono-C-glycosylation and di-C-glycosylation reactions. AaCGT showed potential as a biocatalyst for synthesizing high-value C-glycosides.
SYNTHETIC AND SYSTEMS BIOTECHNOLOGY
(2022)
Article
Energy & Fuels
Juan -Juan Zheng, Fang-Jing Liu, Bing-Kang Sun, Yan-Hong Li, Bo Meng, Yan-Ming Yu, Yun-Peng Zhao, Jing-Pei Cao, Xian-Yong Wei, Yao Lu, Hai-Yun Lu
Summary: Conversion of lignite into chemicals and high-performance carbon materials through supercritical ethanolysis and ultrasonic extraction shows potential for clean and efficient utilization. The soluble organic matters (SOMs) containing oxygen-containing compounds can be used as feedstock for producing value-added chemicals. The insoluble extraction residue (ER) serves as a carbon precursor to produce three-dimensional porous carbon materials (PCMs) with high stability and large specific surface area, showing a high specific capacitance and capacitance retention.
Article
Energy & Fuels
Li Li, Xian-Yong Wei, Chang-Wang Shao, Zhuang Li, Jia-Hao Li, Zi-Chun Fan, Kun-Lang Lu, Fang-Jing Liu, Qian-Qian Kong, Ji Zhao, Zhong-Qiu Liu, Zhi-Min Zong
Summary: In this study, organic waste oil was extracted using ultrasonic waves and a mixed solvent, and then the extracted portion was converted into cyclanes using catalytic hydroconversion technology. The Ni/SiO2 catalyst played a significant role in hydrogenating aromatic rings and removing heteroatoms, exhibiting favorable reactivity under mild conditions.
Article
Energy & Fuels
Li Li, Xian-Yong Wei, Chang-Wang Shao, Fan Yin, Bing-Kang Sun, Fang-Jing Liu, Jia-Hao Li, Zhong-Qiu Liu, Zhi-Min Zong
Summary: Hierarchical porous carbons (HPCs) with various porous structures were successfully prepared using soluble portions (SPs) from catalytic ethanolysis of Xinjiang low-rank coals. Among them, the HPC prepared from a soluble portion of light Runbei lignite (SPLRL) exhibited favorable electrochemical performance with high specific surface area, hierarchical pore volume, and nitrogen/oxygen doping. It showed promising capacitance and cycle stability as a supercapacitor electrode.
Review
Energy & Fuels
Zhi-Hao Ma, Sheng Li, Xue-Qian Dong, Min Li, Guang-Hui Liu, Zhong-Qiu Liu, Fang-Jing Liu, Zhi-Min Zong, Xing-Shun Cong, Xian-Yong Wei
Summary: This paper mainly elaborated on the sources and compound types of coal tars, as well as the molecular characterization and properties of coal tars. It also discussed the performance evaluation of coal tar pitch-based carbon materials. The review aims to promote the enthusiasm for investigating the value-added utilization of coal tars.
Article
Environmental Sciences
Yue Cao, Huan He, Di Zhan, Hua-Zhou Huang, Yong Zhang, Bo Fu, Zhi-Min Xu, Muhammad Ishtiaq Ali, Fang-Jing Liu, Xiu-Xiang Tao, Huang Zaixing
Summary: Research has shown that enhancing coalbed methane (CBM) production can be achieved by adding microbes or stimulating indigenous microbes within coalbeds. However, the application of single purified microbes has not received much attention. In this study, an acetogenic bacterium, Clostridium sp., was used to treat Tiefa anthracite from Liaoning Province, China. The results showed that this bacterium could change the physical properties of the coal by increasing its permeability and porosity, offering a potential alternative method for in situ coalbed methane development in the future.
GEOMICROBIOLOGY JOURNAL
(2023)
Article
Energy & Fuels
Han-Bing Gao, Le-Le Qiu, Fa-Peng Wu, Jian Xiao, Yun-Peng Zhao, Jing Liang, Yong-Hui Bai, Fang-Jing Liu, Jing-Pei Cao
Summary: C-O bonds in lignin can be efficiently cleaved by a hydrotalcite-derived Ni-based catalyst, leading to the production of high value-added bio-fuels and chemicals. The optimized Ni/Al2O3-500 catalyst exhibits excellent catalytic activity and stability, with complete conversion of diphenyl ether to monomeric products under optimized conditions. This catalyst shows promising potential in the hydrogenolysis of lignin derivatives.
Correction
Microbiology
Weiting Zhang, Qianyun Mo, Zaixing Huang, Muhammad Adnan Sabar, Gordana Medunic, Tatjana Ivosevic, Huan He, Michael Urynowicz, Fang-Jing Liu, Hongguang Guo, Rizwan Haider, Muhammad Ishtiaq Ali, Asif Jamal
FRONTIERS IN MICROBIOLOGY
(2023)
Article
Microbiology
Weiting Zhang, Qianyun Mo, Zaixing Huang, Muhammad Adnan Sabar, Gordana Medunic, Tatjana Ivosevic, Huan He, Michael Urynowicz, Fang-Jing Liu, Hongguang Guo, Rizwan Haider, Muhammad Ishtiaq Ali, Asif Jamal
Summary: This study investigated the release of hazardous trace elements and toxic organic pollutants into the local environment by Croatian superhigh-organic-sulfur Rasa coal mining activities. The results showed the persistent presence of polycyclic aromatic hydrocarbons and hazardous trace elements, which negatively impacted the diversity and abundance of microbial communities. The findings of this study are significant for the monitoring and restoration of ecosystems affected by coal mining activities, especially considering the expected closure of a large number of coal plants globally due to growing concerns about global climate change.
FRONTIERS IN MICROBIOLOGY
(2023)
Article
Energy & Fuels
Yingna Du, Chen Huang, Wei Jiang, Qiangwei Yan, Yongfei Li, Gang Chen
Summary: In this study, anionic surfactants modified hydrotalcite was used as a flow improver for crude oil under low-temperature conditions. The modified hydrotalcite showed a significant viscosity reduction effect on crude oil. The mechanism of the modified hydrotalcite on viscosity and pour point of crude oil was explored through characterization and analysis of the modified hydrotalcite and oil samples.
Article
Energy & Fuels
Mohammad Saeid Rostami, Mohammad Mehdi Khodaei
Summary: In this study, a hybrid structure, MIL-53(Al)@MWCNT, was synthesized by combining MIL-53(Al) particles and -COOH functionalized multi-walled carbon nanotube (MWCNT). The hybrid structure was then embedded in a polyethersulfone (PES) polymer matrix to prepare a mixed matrix membrane (MMM) for CO2/CH4 and CO2/N2 separation. The addition of MWCNTs prevented MIL-53(Al) aggregation, improved membrane mechanical properties, and enhanced gas separation efficiency.
Article
Energy & Fuels
Yunlong Li, Desheng Huang, Xiaomeng Dong, Daoyong Yang
Summary: This study develops theoretical and experimental techniques to determine the phase behavior and physical properties of DME/flue gas/water/heavy oil systems. Eight constant composition expansion (CCE) tests are conducted to obtain new experimental data. A thermodynamic model is used to accurately predict saturation pressure and swelling factors, as well as the phase boundaries of N2/heavy oil systems and DME/CO2/heavy oil systems, with high accuracy.
Article
Energy & Fuels
Morteza Afkhamipour, Ebad Seifi, Arash Esmaeili, Mohammad Shamsi, Tohid N. Borhani
Summary: Non-conventional amines are being researched worldwide to overcome the limitations of traditional amines like MEA and MDEA. Adequate process and thermodynamic models are crucial for understanding the applicability and performance of these amines in CO2 absorption, but studies on process modeling for these amines are limited. This study used rate-based modeling and Deshmukh-Mather method to model CO2 absorption by DETA solution in a packed column, validated the model with experimental data, and conducted a sensitivity analysis of mass transfer correlations. The study also compared the CO2 absorption efficiency of DETA solution with an ionic solvent [bmim]-[PF6] and highlighted the importance of finding optimum operational parameters for maximum absorption efficiency.
Article
Energy & Fuels
Arastoo Abdi, Mohamad Awarke, M. Reza Malayeri, Masoud Riazi
Summary: The utilization of smart water in EOR operations has gained attention, but more research is needed to understand the complex mechanisms involved. This study investigated the interfacial tension between smart water and crude oil, considering factors such as salt, pH, asphaltene type, and aged smart water. The results revealed that the hydration of ions in smart water plays a key role in its efficacy, with acidic and basic asphaltene acting as intrinsic surfactants. The pH also influenced the interfacial tension, and the aged smart water's interaction with crude oil depended on asphaltene type, salt, and salinity.
Article
Energy & Fuels
Dongao Zhu, Kun Zhu, Lixian Xu, Haiyan Huang, Jing He, Wenshuai Zhu, Huaming Li, Wei Jiang
Summary: In this study, cobalt-based metal-organic frameworks (Co-based MOFs) were used as supports and co-catalysts to confine the NHPI catalyst, solving the leaching issue. The NHPI@Co-MOF with carboxyl groups exhibited stronger acidity and facilitated the generation of active oxygen radicals O2•, resulting in enhanced catalytic activity. This research provides valuable insights into the selection of suitable organic linkers and broadens the research horizon of MOF hybrids in efficient oxidative desulfurization (ODS) applications.
Article
Energy & Fuels
Edwin G. Hoyos, Gloria Amo-Duodu, U. Gulsum Kiral, Laura Vargas-Estrada, Raquel Lebrero, Rail Munoz
Summary: This study investigated the impact of carbon-coated zero-valent nanoparticle concentration on photosynthetic biogas upgrading. The addition of nanoparticles significantly increased microalgae productivity and enhanced nitrogen and phosphorus assimilation. The presence of nanoparticles also improved the quality of biomethane produced.
Article
Energy & Fuels
Yao Xiao, Asma Leghari, Linfeng Liu, Fangchao Yu, Ming Gao, Lu Ding, Yu Yang, Xueli Chen, Xiaoyu Yan, Fuchen Wang
Summary: Iron is added as a flocculant in wastewater treatment and the hydrothermal carbonization (HTC) of sludge produces wastewater containing Fe. This study investigates the effect of aqueous phase (AP) recycling on hydrochar properties, iron evolution and environmental assessment during HTC of sludge. The results show that AP recycling process improves the dewatering performance of hydrochar and facilitates the recovery of Fe from the liquid phase.
Article
Energy & Fuels
He Liang, Tao Wang, Zhenmin Luo, Jianliang Yu, Weizhai Yi, Fangming Cheng, Jingyu Zhao, Xingqing Yan, Jun Deng, Jihao Shi
Summary: This study investigated the influence of inhibitors (carbon dioxide, nitrogen, and heptafluoropropane) on the lower flammability limit of hydrogen and determined the critical inhibitory concentration needed for complete suppression. The impact of inhibitors on explosive characteristics was evaluated, and the inhibitory mechanism was analyzed with chemical kinetics. The results showed that with the increase of inhibitor quantity, the lower flammability limit of hydrogen also increased. The research findings can contribute to the safe utilization of hydrogen energy.
Article
Energy & Fuels
Zonghui Liu, Zhongze Zhang, Yali Zhou, Ziling Wang, Mingyang Du, Zhe Wen, Bing Yan, Qingxiang Ma, Na Liu, Bing Xue
Summary: In this study, high-performance solid catalysts based on phosphotungstic acid (HPW) supported on Zr-SBA-15 were synthesized and evaluated for the one-pot conversion of furfural (FUR) to γ-valerolactone (GVL). The catalysts were characterized using various techniques, and the ratio of HPW and Zr was found to significantly affect the selectivity of GVL. The HPW/Zr-SBA-15 (2-4-15) catalyst exhibited the highest GVL yield (83%) under optimized reaction conditions, and it was determined that a balance between Bronsted acid sites (BAS) and Lewis acid sites (LAS) was crucial for achieving higher catalytic performance. The reaction parameters and catalyst stability were also investigated.
Article
Energy & Fuels
Michael Stoehr, Stephan Ruoff, Bastian Rauch, Wolfgang Meier, Patrick Le Clercq
Summary: As part of the global energy transition, an experimental study was conducted to understand the effects of different fuel properties on droplet vaporization for various conventional and alternative fuels. The study utilized a flow channel to measure the evolution of droplet diameters over time and distance. The results revealed the temperature-dependent effects of physical properties, such as boiling point, liquid density, and enthalpy of vaporization, and showed the complex interactions of preferential vaporization and temperature-dependent influences of physical properties for multi-component fuels.
Article
Energy & Fuels
Yuan Zhuang, Ruikang Wu, Xinyan Wang, Rui Zhai, Changyong Gao
Summary: Through experimental validation and optimization of the chemical kinetic model, it was found that methanol can accelerate the oxidation reaction of ammonia, and methanol can be rapidly oxidized at high concentration. HO2 was found to generate a significant amount of OH radicals, facilitating the oxidation of methanol and ammonia. Rating: 7.5/10.
Article
Energy & Fuels
Radwan M. EL-Zohairy, Ahmed S. Attia, A. S. Huzayyin, Ahmed I. EL-Seesy
Summary: This paper presents a lab-scale experimental study on the impact of diethyl ether (DEE) as an additive to waste cooking oil biodiesel with Jet A-1 on combustion and emission features of a swirl-stabilized premixed flame. The addition of DEE to biodiesel significantly affects the flame temperature distribution and emissions. The W20D20 blend of DEE, biodiesel, and Jet A-1 shows similar flame temperature distribution to Jet A-1 and significantly reduces UHC, CO, and NOx emissions compared to Jet A-1.
Article
Energy & Fuels
Jiang Bian, Ziyuan Zhao, Yang Liu, Ran Cheng, Xuerui Zang, Xuewen Cao
Summary: This study presents a novel method for ammonia separation using supersonic flow and develops a mathematical model to investigate the condensation phenomenon. The results demonstrate that the L-P nucleation model accurately characterizes the nucleation process of ammonia at low temperatures. Numerical simulations also show that increasing pressure and concentration can enhance ammonia condensation efficiency.
Article
Energy & Fuels
Shiyuan Pan, Xiaodan Shi, Beibei Dong, Jan Skvaril, Haoran Zhang, Yongtu Liang, Hailong Li
Summary: Integrating CO2 capture with biomass-fired combined heat and power (bio-CHP) plants is a promising method for achieving negative emissions. This study develops a reliable data-driven model based on the Transformer architecture to predict the flowrate and CO2 concentration of flue gas in real time. The model validation shows high prediction accuracy, and the potential impact of meteorological parameters on model accuracy is assessed. The results demonstrate that the Transformer model outperforms other models and using near-infrared spectral data as input features improves the prediction accuracy.