Journal
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES
Volume 24, Issue 3, Pages 195-201Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/1536383X.2015.1113524
Keywords
Graphene; Fullerene ozopolymers; Graphite oxide; Electron spin resonance; EPR
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It is shown that graphite oxide (GO) and both heavily ozonized C-60 and C-70 fullerenes, known as fullerene ozopolymers, are paramagnetic materials with a very strong electron spin resonance (ESR) signal at room temperature. When thermally annealed, the paramagnetic centers are gradually lost in large part. This occurs at 350 degrees C in the case of GO, while for fullerene ozopolymers, a higher temperature is required, reaching the same results in the end. The half-width of ESR signal is linked to the distribution of paramagnetic centers. Once again, striking analogies were found in the half-width of the ESR signal measured on GO and fullerene ozopolymers, at least in the temperature range of 25-450 degrees C. Similarly, the same g-factor values, which are diagnostic for understanding the chemical nature of paramagnetic centers, were found on both GO and fullerene ozopolymers in all ranges of temperature considered.
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