Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2018, Issue 35, Pages 4940-4948Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201800253
Keywords
Earth-abundant metals; Acylation; Amines; Cobalt; Amides
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Funding
- National Natural Science Foundation of China [21402168]
- Scientific Research Foundation of Hunan Provincial Education Department [15B232]
- 1515 Academic Leader Team Program of Hunan Agricultural University
- Hunan 2011 Collaborative Innovation Center of Chemical Engineering & Technology with Environmental Benignity and Effective Resource Utilization
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A practical protocol has been developed for a Co(OAc)(2)center dot 4H(2)O-catalyzed transamidation reaction. The reaction gives high yields and uses N,N-dimethylformamide and other amides as carbonyl sources. The protocol is rapid and simple, and it does not require any acids, bases, ligands, or other additives. It works well for a wide range of primary, secondary, and heterocyclic amines.
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