Synthesis of 6-Trifluoromethylphenanthridines through Radical Trifluoromethylation of Isocyanides with Sodium Triflinate under Visible Light

Catalyst-Free and Redox-Neutral Innate Trifluoromethylation and Alkylation of Aromatics Enabled by Light

(2017) Peng Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Halogen-Bond-Promoted Photoactivation of Perfluoroalkyl Iodides: A Photochemical Protocol for Perfluoroalkylation Reactions

(2017) Yaxin Wang et al.   ORGANIC LETTERS

Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible-Light Photoredox Catalysis

(2016) Jian Rong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Operationally simple hydrotrifluoromethylation of alkenes with sodium triflinate enabled by Ir photoredox catalysis

(2016) Lei Zhu et al.   CHEMICAL COMMUNICATIONS

Simple and Clean Photoinduced Aromatic Trifluoromethylation Reaction

(2016) Lu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient generation of perfluoroalkyl radicals from sodium perfluoroalkanesulfinates and a hypervalent iodine(iii) reagent: mild, metal-free synthesis of perfluoroalkylated organic molecules

(2016) Ryu Sakamoto et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Recent advances in photoinduced trifluoromethylation and difluoroalkylation

(2016) Xiaolin Pan et al.   Organic Chemistry Frontiers

Visible-Light Photoredox-Catalyzed Semipinacol-Type Rearrangement: Trifluoromethylation/Ring Expansion by a Radical-Polar Mechanism

(2015) Basudev Sahoo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trifluoromethylchlorosulfonylation of Alkenes: Evidence for an Inner-Sphere Mechanism by a Copper Phenanthroline Photoredox Catalyst

(2015) Dattatraya B. Bagal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free radical oxidative decarboxylation/cyclization of acyl peroxides and 2-isocyanobiphenyls

(2015) Changduo Pan et al.   CHEMICAL COMMUNICATIONS

Transition Metal-Free Oxidative Radical Decarboxylation/Cyclization for the Construction of 6-Alkyl/Aryl Phenanthridines

(2015) Shichao Lu et al.   JOURNAL OF ORGANIC CHEMISTRY

Anti-Diastereoselective Synthesis of CF3-Containing Spirooxazolines and Spirooxazines via Regiospecific Trifluoromethylative Spirocyclization by Photoredox Catalysis

(2015) Naoki Noto et al.   ORGANIC LETTERS

Photoinduced additive-free trifluoromethylation of aromatic aldehydes with TMSCF3

(2015) Jing Sun et al.   TETRAHEDRON LETTERS

Light triggered addition/annulation of 2-isocyanobiphenyls toward 6-trifluoromethyl-phenanthridines under photocatalyst-free conditions

(2015) Xiangyang Tang et al.   RSC Advances

Trifluoromethylation of Alkenes with Concomitant Introduction of Additional Functional Groups

(2014) Hiromichi Egami et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

tert-Butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane: efficient synthesis of 6-alkyl phenanthridines via C(sp3)–H/C(sp2)–H bond functionalization

(2014) Jia-Jia Cao et al.   CHEMICAL COMMUNICATIONS

The benzoyl peroxide-promoted functionalization of simple alkanes with 2-aryl phenyl isonitrile

(2014) Wanxing Sha et al.   CHEMICAL COMMUNICATIONS

Transition-metal-free, visible-light induced cyclization of arylsulfonyl chlorides with 2-isocyanobiphenyls to produce phenanthridines

(2014) Lijun Gu et al.   CHEMICAL COMMUNICATIONS

Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

(2014) Xiu-Hua Xu et al.   CHEMICAL REVIEWS

Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents

(2014) Julie Charpentier et al.   CHEMICAL REVIEWS

Synthesis of 6-substituted phenanthridines by metal-free, visible-light induced aerobic oxidative cyclization of 2-isocyanobiphenyls with hydrazines

(2014) Tiebo Xiao et al.   GREEN CHEMISTRY

FeCl3-Promoted Carboxamidation and Cyclization of Aryl Isonitriles with Formamides toward Phenanthridine-6-carboxamides

(2014) Hai-Yong Tu et al.   JOURNAL OF ORGANIC CHEMISTRY

6-Perfluoroalkylated Phenanthridines via Radical Perfluoroalkylation of Isonitriles

(2014) Bo Zhang et al.   ORGANIC LETTERS

Somophilic Isocyanide Insertion: Synthesis of 6-Arylated and 6-Trifluoro­methylated Phenanthridines

(2014) Yan Zhang et al.   SYNTHESIS-STUTTGART

Trifluoromethylation by Visible-Light-Driven Photoredox Catalysis

(2014) Takashi Koike et al.   TOPICS IN CATALYSIS

Metal-Free Photocatalytic Radical Trifluoromethylation Utilizing Methylene Blue and Visible Light Irradiation

(2014) Spencer P. Pitre et al.   ACS Catalysis

6-Trifluoromethyl-Phenanthridines through Radical Trifluoromethylation of Isonitriles

(2013) Bo Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Induced Trifluoromethylation ofN-Aryl Acrylamides: A Convenient and Effective Method To Synthesize CF3-Containing Oxindoles Bearing a Quaternary Carbon Center

(2013) Pan Xu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silver-Mediated Trifluoromethylation of Aryldiazonium Salts: Conversion of Amino Group into Trifluoromethyl Group

(2013) Xi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

PhI(OAc)2-Mediated Synthesis of 6-(Trifluoromethyl)phenanthridines by Oxidative Cyclization of 2-Isocyanobiphenyls with CF3SiMe3 under Metal-Free Conditions

(2013) Qile Wang et al.   ORGANIC LETTERS

Isocyanide Insertion: De Novo Synthesis of Trifluoromethylated Phenanthridine Derivatives

(2013) Yuanzheng Cheng et al.   ORGANIC LETTERS

6-Aroylated Phenanthridines via Base Promoted Homolytic Aromatic Substitution (BHAS)

(2013) Dirk Leifert et al.   ORGANIC LETTERS

Modular Synthesis of Phenanthridine Derivatives by Oxidative Cyclization of 2-Isocyanobiphenyls with Organoboron Reagents

(2012) Mamoru Tobisu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A “Renaissance” in Radical Trifluoromethylation

(2012) Armido Studer   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Mediated Trifluoromethylation of α-Diazo Esters with TMSCF3: The Important Role of Water as a Promoter

(2012) Mingyou Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoredox Catalysis: A Mild, Operationally Simple Approach to the Synthesis of α-Trifluoromethyl Carbonyl Compounds

(2011) Phong V. Pham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic Trifluoromethylation with Metal Complexes

(2011) Olesya A. Tomashenko et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature

(2011) Xin Mu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis

(2011) David A. Nagib et al.   NATURE

Asymmetric Construction of Stereogenic Carbon Centers Featuring a Trifluoromethyl Group from Prochiral Trifluoromethylated Substrates

(2010) Jing Nie et al.   CHEMICAL REVIEWS

Copper-Mediated Aerobic Oxidative Trifluoromethylation of Terminal Alkynes with Me3SiCF3

(2010) Lingling Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis

(2009) David A. Nagib et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS

Phenanthridine synthesis via [2+2+2] cyclotrimerization reactions

(2007) Lakshminath Sripada et al.   ORGANIC & BIOMOLECULAR CHEMISTRY