Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2018, Issue 12, Pages 1507-1512Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201701641
Keywords
Carboranes; Aggregation-induced emission; Solid-state structures; Luminescence
Categories
Funding
- The Institute for Synthetic Organic Chemistry
- JSPS [JP24102013]
- Grants-in-Aid for Scientific Research [15H03856] Funding Source: KAKEN
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Bis-carborane-substituted benzo[1,2-b:4,5-b]dithiophenes (DCB-R, where R = H, tBu) were synthesized and characterized. Their three-dimensional conformations were tuned by introducing the tert-butyl substituent at the para-positions of the phenyl rings. Both molecules showed emission enhancement behavior, especially in the solid state. The emission quantum efficiencies were over 0.90 in the crystalline state. Moreover, it was shown that the efficiency of DCB-tBu was over 0.70 in the amorphous state. From structural analyses and mechanistic investigations, it was proposed that the tert-butyl substituents play a critical role in the formation of the trans-conformation followed by suppression of aggregation-caused quenching because of the o-carborane units located at each plane of the benzodithiophene ring.
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