Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 6, Pages 683-693Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201701027
Keywords
Surface chemistry; Anatase TiO2; Photocatalysis; Crystal engineering; Doping
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Funding
- National Basic Research Program of China [2015CB932003]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB14020201]
- National Natural Science Foundation of China [41373123, 41425016, 21321004]
- Graduate Innovation Project in Chongqing [CYB17151]
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The atomic arrangement of titanium and oxygen on crystalline anatase TiO2 formulates various facets, dominating the TiO2 surface chemistry. Due to its unique surface atomic structure, TiO2 with high-index facets has received great interest from a wide spectrum of science. Insights gained from the intricate link between the morphological modulation of anatase TiO2 with distinct high-index facets and the properties of these modifications can expedite the rational fabrication of functional crystals. This review succinctly presents the recent impressive progress on the manipulation of high-index facets of anatase TiO2, focusing on the comparison of surface energies. In addition, the rational synthesis and the fascinating performance of both high-index terminated pristine anatase TiO2 and its modified surfaces are collectively discussed. Finally, the perspective of ongoing research on high-index bounded anatase TiO2 is addressed.
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