Article
Materials Science, Multidisciplinary
Walther-Dario Bejarano-Pena, Brenda Alcantar-Vazquez, Rosa-Maria Ramirez-Zamora
Summary: Lithium silicate-based CO2 sorbents were synthesized using steel metallurgical slags, with K2CO3 addition improving CO2 capture efficiency by facilitating CO2 diffusion. The best capture capacity value of 104 mg(CO2)/g(material) was achieved with 20 wt% K2CO3 at 600 degrees C. Thermal stability was excellent, with only a 10% reduction in CO2 capture capacity after 20 adsorption-desorption cycles using 20 vol% CO2.
MATERIALS RESEARCH BULLETIN
(2021)
Article
Thermodynamics
Wladyslaw Janusz, Ewa Skwarek, Dariusz Sternik, Stanislaw Pikus
Summary: Yttrium citrate was synthesized in aqueous environment through hydrothermal treatment. The product is crystalline yttrium citrate dihydrate, which undergoes thermal decomposition in synthetic air, releasing water and carbon dioxide.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2021)
Article
Polymer Science
Ponnusamy Packialakshmi, Perumal Gobinath, Daoud Ali, Saud Alarifi, Norah Salem Alsaiari, Akbar Idhayadhulla, Radhakrishnan Surendrakumar
Summary: Chitosan was investigated for its interaction with SARS-CoV-2, with beta-chitosan derivatives synthesized and evaluated for cytotoxic activity against cancer cell lines. In addition, docking analysis showed that compound 1c exhibited notable inhibition ability against the SARS coronavirus, suggesting it as a potential alternative antiviral agent for SARS-CoV-2.
Article
Chemistry, Physical
Francesco Trequattrini, Sergio Brutti, Oriele Palumbo, Madhura Hulyalkar, Leslie T. Mushongera, Wenye Ye, M. Rashed Khan, Michael Dolan, Dhanesh Chandra, Annalisa Paolone
Summary: The crystallization and hydrogen absorption properties of a Ni32Nb28Zr30Fe10 melt spun ribbon were investigated, showing exceptionally low activation energy during the crystallization process and slow kinetics of hydrogen absorption due to weak interaction with clusters after hydrogenation.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Medicinal
Mercy A. A. Okezue, Stephen R. R. Byrn
Summary: This study provides detailed information about the synthesis, characterization, and stability of four new salts of bedaquiline, namely, benzoate, hydrochloride (HCl), nicotinate, and malonate. The benzoate salt showed the lowest tendency to lose its chemical potency, while the others retained long-term stability.
Article
Chemistry, Physical
Karolina Kutynia, Anna Przybyl, Piotr Gebara
Summary: The present study investigates the influence of partial substitution of Mn by Pd on structure, thermomagnetic properties, and phase transitions in the MnCoGe alloys. The research reveals the existence of orthorhombic TiNiSi-type and hexagonal Ni2Ti-type phases. The increase in Pd content leads to changes in lattice parameters and phase quantity, as well as an increase in Curie temperature.
Article
Materials Science, Multidisciplinary
C. F. Ramirez-Gutierrez, I. A. Lujan-Cabrera, L. D. Valencia-Molina, J. H. Castillo-Chamorro, S. M. Londono-Restrepo
Summary: This paper investigates the electrical properties and physicochemical transformations of porcine bone through in-situ impedance spectroscopy and complementary techniques. The conduction behavior in biogenic hydroxyapatite is influenced by intergranular contact and crystal size. A thermal phase transition at around 973 K is detected, which involves changes in crystal size and out-diffusion of Mg to the surface. The correlation between structural and electrical properties is evident.
MATERIALS TODAY COMMUNICATIONS
(2022)
Article
Polymer Science
Mengmeng Li, Ruihu Wang, Haijie Wang, Xinhua Cao, Yu Cheng, Erqi Guan, Ke Bian
Summary: The industrial application of plywood made from soybean meal-based adhesive (SMA) was enhanced by improving the wet shear strength and water resistance through microwave-chemical treatment. The wet shear strength of SMA was improved to 0.93 MPa by optimizing microwave conditions and using PEG-PEI treatment, which was 32.86% higher than the China National Standard. The modified mechanism was characterized using various techniques, showing that the formation of crosslinking improved the bonding performance and water resistance of SMA, providing favorable conditions for further application.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Biochemistry & Molecular Biology
Elisa Aranda, Jose A. Teruel, Antonio Ortiz, Maria Dolores Perez-Carceles, Jose N. Rodriguez-Lopez, Francisco J. Aranda
Summary: Catechins, including the modified structural analog TMBC, affect the structure and dynamics of phosphatidylglycerol bilayers, leading to changes in membrane thickness and hydrogen bonding patterns. This study helps to understand the mechanisms of action behind the diverse effects exhibited by catechins.
Article
Chemistry, Multidisciplinary
Shuo Feng, Rajesh Kumar Singh, Yucheng Fu, Zhuo Li, Yulong Wang, Jie Bao, Zhijie Xu, Guosheng Li, Cassidy Anderson, Lili Shi, Yuehe Lin, Peter G. Khalifah, Wei Wang, Jun Liu, Jie Xiao, Dongping Lu
Summary: In this study, a simple strategy was demonstrated for constructing low-tortuosity through-pores in both vertical and planar directions of electrodes by casting large particles into single-particle-layer electrodes. Through multi-scale characterizations and simulations, correlations between material/electrode structures, electrolyte permeability, polysulfide migration, and sulfur reactions were elucidated. The high-loading and dense sulfur cathode fabricated by this method delivers a high specific capacity at a very low electrolyte/sulfur ratio.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Thermodynamics
Sandra Ramos-Inza, Eneko Almagro, Maria Font, Ignacio Encio, Daniel Plano, Carmen Sanmartin, Rafael Sirera, Elena Lizarraga
Summary: In this study, the stability, thermal characterization, and polymorphic forms of thirty new nonsteroidal anti-inflammatory drug derivatives containing selenium were analyzed. The compounds exhibited thermal stability and no significant differences were found among polymorphic forms, indicating their suitability for further drug development.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2023)
Article
Biochemistry & Molecular Biology
Anna Lech, Patrycja Garbacz, Artur Sikorski, Maria Gazda, Marek Wesolowski
Summary: The research aimed to prepare an organic salt of chlordiazepoxide with saccharin by obtaining a crystalline salt through grinding and crystallization methods. Various analytical techniques confirmed the structure and properties of the salt formed between chlordiazepoxide and saccharin.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Food Science & Technology
Ana Gabriela da Silva Anthero, Talita Aline Comunian, Eveling Oliveira Bezerra, Miriam Dupas Hubinger
Summary: The study aimed to obtain novel materials for oil/water emulsions from malt modification using stearic acid and different energy densities from ultrasound probe. Increasing energy densities affected malt properties by increasing degree of substitution, amylose content, and dextrose equivalent values. The sonication process with stearic acid enhanced malt solubility, gelatinization temperature, and stabilizing properties for emulsions.
FOOD AND BIOPROCESS TECHNOLOGY
(2021)
Article
Biophysics
David Chapron, Jean-Philippe Michel, Philippe Fontaine, Jeremy Godard, Frederique Bregier, Vincent Sol, Veronique Rosilio
Summary: This study investigates the suitability of photosensitizer PN grafted with lipid chains to form nano assemblies or mixed lipid vesicles for photodynamic therapy. The results show that PN-C-18 conjugates can control the thermodynamic and structural properties of mixtures, leading to the disintegration of vesicles due to pi-pi interactions between PN molecules.
COLLOIDS AND SURFACES B-BIOINTERFACES
(2023)
Article
Materials Science, Ceramics
M. Gancheva, T. Rojac, R. Iordanova, I. Piroeva, P. Ivanov
Summary: MgMoO4 with hexagonal particles was prepared by combining high energy ball milling with heat treatment technique. The mechanochemical activation/heat-treatment influenced the phase, structural and morphology transformation, and the optical properties of the final product were studied. The calculated energy band gap value of prepared MgMoO4 is 2.03 eV with photoluminescence emission above 600 nm.
CERAMICS INTERNATIONAL
(2022)
Article
Polymer Science
Robert Mundil, Alexander Zhigunov, Mariusz Uchman
Summary: In this study, we synthesized and self-assembled mPEG-block-PDL-block-PMMA triblock terpolymers using a metal-free catalytic system, which showed better polymerization control compared to sequential copolymerization. The blocks were found to be incompatible, leading to their self-assembly into multicompartment micelles in water.
EUROPEAN POLYMER JOURNAL
(2022)
Review
Biochemistry & Molecular Biology
Agnieszka Adamczyk-Wozniak, Andrzej Sporzynski
Summary: Fluorinated boron species are important organoboron compounds used in bioanalysis and antifungal drugs. The presence of fluorine substituents increases the acidity of boronic compounds, which is crucial for their interactions with bioanalytes and pathogen enzymes. This review discusses the electron acceptor properties, NMR spectroscopy data, and solution equilibria of fluorinated boronic species, as well as the latest research on their biological activity.
Article
Chemistry, Multidisciplinary
Mateusz Urban, Paulina H. Marek-Urban, Krzysztof Durka, Sergiusz Lulinski, Piotr Pander, Andrew P. Monkman
Summary: The high triplet boracycle SO2B was successfully applied in TADF emitters PXZ-Dipp-SO2B and CZ-Dipp-SO2B, achieving near-complete separation of highest occupied and lowest unoccupied molecular orbitals and leading to low oscillator strength of the S-1 -> S-0 CT transition. OLEDs using CZ-Dipp-SO2B as the luminescent dopant displayed high external quantum efficiency and maximum luminance with low efficiency roll off. The rISC in CZ-Dipp-SO2B is mediated through vibronic coupling of two CT states, allowing stable OLED performance to be achieved in different host environments.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Pharmacology & Pharmacy
Eva Hlavatovicova, Roberto Fernandez-Alvarez, Katarzyna Bys, Sami Kereiche, Tarun K. Mandal, Leonard Ionut Atanase, Miroslav Stepanek, Mariusz Uchman
Summary: Stimuli-responsive copolymers were synthesized by post-polymerization quaternization of a poly(4-vinyl pyridine) (P4VP) block of a triblock terpolymer. Stable micelles were prepared using a self-assembly protocol, and their characterization was performed using light scattering and cryogenic transmission electron microscopy. The encapsulation and release of a model drug were studied using UV-Vis spectroscopy, showing selective response to specific geminal diols. This study presents a reproducible method for preparing stimuli-responsive systems with potential for targeted drug delivery, especially for cancer treatment.
Article
Chemistry, Multidisciplinary
Paulina H. Marek-Urban, Karolina A. Urbanowicz, Karolina Wrochna, Piotr Pander, Agata Blacha-Grzechnik, Simone T. Hauer, Henning R. V. Berens, Krzysztof Wozniak, Thomas J. J. Mueller, Krzysztof Durka
Summary: A synthetic approach to two regioisomeric pi-electron extended [1,4]thiaborins annulated with two benzothiophene units has been developed. The obtained boracycles exhibit different electronic properties reflected in their aromatic characters, boron Lewis acidity, and UV-vis spectroscopic behavior. The spiro thiaborin-BODIPY complexes show excellent photocatalytic performance as singlet oxygen photosensitizers with high singlet oxygen quantum yields and full conversion of organic substrates.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Physical
Sayan Das, Somdeb Jana, Martin Orsagh, Katarzyna Bys, Jaisankar Mishra, Mariusz Uchman, Venimadhav Adyam
Summary: Flexible and intrinsically safe single-ion gel polymer electrolytes with high transference number (0.75) were developed by blending poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) copolymer and biocompatible poly((sulfamate-carboxylate) iso-prene) (PISC) in carbonate solvents. A steady conductivity of 1.81 x 10-5 S/cm was observed for 15 days under normal air exposure conditions (RH = 45%-61%, T = 25-31 degrees C). The sodium metal battery with an NVP cathode showed 82% capacity retention after 45 cycles at 80 degrees C with a C/5 rate, and 67.92% capacity retention after 200 cycles at room temperature with a C/10 rate using the gel formed with a conventional liquid electrolyte even after air exposure.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Edyta Pindelska, Mateusz A. Mogilnicki, Jolanta Jaskowska, Izabela D. Madura
Summary: Three crystal structures of ligands for a serotonin receptor were studied, analyzing the differences in experimental affinities and discrepancies in the molecular structure in crystal and theoretical docking studies. Experimental methods were supplemented with quantum chemical calculations and modern cheminformatics methods.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Chemistry, Physical
Joanna Bojarska, Martin Breza, Milan Remko, Ye Yuan, Zyta M. Ziora, Tsun-Thai Chai, Izabela D. Madura, Krzysztof Kaczmarek, Mark A. T. Blaskovich, Wojciech M. Wolf
Summary: A supramolecular behavior of a newly synthesized compound and a library of tetrazole-based H-bonding synthons were studied by X-ray crystallography and computational techniques. The supramolecular assembly was controlled by various interactions, including O...H, N...H, C...H, and pi-stacking interactions. The 3D topologies of the supramolecular architectures were visualized and dispersion forces played a crucial role. Quantum-chemical treatment revealed the chemical activity and stability of the compound. These findings provide valuable information for the design of therapeutic agents containing tetrazole motifs.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Nanoscience & Nanotechnology
Martin Orsagh, Beata Strachota, Ewa Pavlova, Jiri Panek, Agnieszka Adamczyk-Wozniak, Andrzej Sporzynski, Pawel Leszczynski, Miroslav Stepanek, Mariusz Uchman
Summary: Hydrogelators form nanoscale networks when dissolved in water, resulting in hydrogels with unique properties that have applications in tissue engineering and drug delivery. The solubility of different derivatives of phenylboronic acid was measured, and m-isobutoxyphenylboronic acid (PBA) was identified as a low-molecular-weight hydrogelator based solely on phenylboronic acid. PBA hydrogels exhibited a combination of amorphous and crystalline phases and had their elastic modulus and viscoelastic properties tuned by adjusting the PBA concentration and adding urea. Additionally, PBA hydrogels demonstrated responsiveness to various triggers and selective absorption of dyes for liquid mixture separation, highlighting their potential in bioapplications as biodegradable, multistimuli-responsive hydrogelators.
ACS APPLIED NANO MATERIALS
(2023)
Article
Chemistry, Inorganic & Nuclear
Krzysztof Fink, Jakub Cebula, Zdenek Tosner, Mateusz Psurski, Mariusz Uchman, Tomasz M. Goszczynski
Summary: Cobalt bis(dicarbollide) (COSAN) is a versatile metallacarborane used in drug development. This study comprehensively characterized the interactions between COSAN and DNA, finding that COSAN has no significant effect on DNA structure and can induce cytotoxicity even without DNA presence. These findings confirm the safety and biocompatibility of metallacarboranes and provide new opportunities for drug development.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Multidisciplinary
Joanna Bojarska, Martin Breza, Milan Remko, Pawel Borowiecki, Andrzej Fruzinski, Izabela D. Madura, Krzysztof Kaczmarek, Zbigniew Lesnikowski, Agata Kraj, Piotr Zielenkiewicz, Wojciech M. M. Wolf
Summary: In this study, a series of cyclopropyl-containing peptide-derived compounds were synthesized and their crystal structures were determined. The self-assembly mechanism and potential biological activity of these compounds were investigated. This research provides a basis and guidance for further applications of cyclopropyl-containing peptide-derived compounds.
Article
Chemistry, Multidisciplinary
Anna M. Dabrowska, Agnieszka Adamczyk-Wozniak, Izabela D. Madura
Summary: In this study, new tavaborole derivatives were synthesized and their crystal structures were compared to investigate the effects of substitutions on the structure. The presence of a fluorine atom was found to reduce the molecular dipole moment and the hydrogen bond acceptor abilities of a ring oxygen atom, thereby affecting the structure of the main hydrogen-bonded motif.