Big Groundwater Data Sets Reveal Possible Rare Contamination Amid Otherwise Improved Water Quality for Some Analytes in a Region of Marcellus Shale Development

Eleven thousand groundwater samples collected in the 2010s in an area of Marcellus shale-gas development are analyzed to assess spatial and temporal patterns of water quality. Using a new data mining technique, we confirm previous observations that methane concentrations in groundwater tend to be naturally elevated in valleys and near faults, but we also show that methane is also more concentrated near an anticline. Data mining also highlights waters with elevated methane that are not otherwise explained by geologic features These slightly elevated concentrations occur near 7 out of the 1,385 shale-gas wells and near some conventional gas wells in the study area. For ten analytes for which uncensored data are abundant in this 3,000 km(2) rural region, concentrations are unchanged or unproved as compared to samples analyzed prior to 1990. Specifically, TDS, Fe, Mn, sulfate, and pH show small but statistically significant improvement, and As, Pb, Ba, Cl, and Na show no change. Evidence from this rural area could document improved groundwater quality caused by decreased acid ram (pH, sulfate) since the imposition of the Clean Air Act or decreased steel production (Fe, Mn). Such improvements have not been reported in groundwater in more developed areas of the U.S.