Article
Engineering, Environmental
Sunkyu Kim, Leelavathi Annamalai, Raul F. Lobo
Summary: The combination of methane dehydroaromatization (MDA) and chemical looping (CL) combustion of hydrogen can overcome the thermodynamic constraints limiting conversion. The development of selective hydrogen-oxidation oxygen carriers in the CL is crucial for improving MDA performance. A novel oxygen carrier, silica-encapsulated Fe2O3, demonstrated high overall methane conversion and aromatics yield in a recirculating system. The silica layer prevented aromatics diffusion and promoted hydrogen transport and oxidation, while close physical contact between iron oxide particles and silica facilitated hydrogen conversion without full depletion of iron oxides.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Energy & Fuels
Shouxi Jiang, Laihong Shen, Jingchun Yan, Xin Niu, Bin Hu
Summary: The study investigated Cu-Fe bimetallic oxygen carriers (OCs) supported by SiO2, Al2O3, or hematite in a fluidized-bed reactor. It was found that CuFe-He and CuFe-Al OCs performed better than CuFe-Si OC, with the latter leading to deactivation due to irreversible interaction. Hematite was identified as an excellent support candidate for manufacturing Cu-Fe OCs. Additionally, maintaining a high O/C ratio and increasing reaction temperature above 850 degrees C promoted coal conversion efficiency in chemical looping combustion.
Article
Engineering, Chemical
Peng Gao, Yue Shen, Min Zheng, Guirong Bao, Hua Wang, Haitao Xie, Lulu Wang
Summary: Chemical looping is a novel technology for fuel conversion and material separation, which can be used to obtain sulphur and produce high concentrations of H2SO4. This study analyzed the thermodynamics and reactor design of the chemical looping combustion of sulphur for H2SO4 production.
CANADIAN JOURNAL OF CHEMICAL ENGINEERING
(2023)
Article
Engineering, Environmental
Chunqiang Lu, Rongrong Deng, Ruidong Xu, Yannan Zhao, Xing Zhu, Yonggang Wei, Kongzhai Li
Summary: The CeO2/MnCo2O4 oxygen carrier significantly improves the redox stability for methane combustion in Chemical Looping Combustion (CLC). Among different compositions, the 10% CeO2/MnCo2O4 sample shows the highest stability during successive CLC testing, with a methane combustion capacity of 2.22 mmol/g and average methane conversion rate of over 90%.
CHEMICAL ENGINEERING JOURNAL
(2021)
Review
Energy & Fuels
Guicai Liu, Grzegorz Lisak
Summary: This review summarizes the basic properties and opportunities of Cu-based OCs in various chemical looping processes. It covers the applications of Cu-based OCs in chemical looping combustion (CLC), chemical looping oxygen uncoupling (CLOU), chemical looping air separation (CLAS), chemical looping for syngas/H2 production, integrated CaO/CuO looping process, and thermochemical energy storage (TCES). The review also discusses the technical challenges and current strategies related to agglomeration, attrition, and ash accumulation. It provides insights and guidance for the design and development of Cu-based OCs and their applications in chemical looping processes.
Article
Energy & Fuels
Li Yang, Wenbin Chen, Chen Song, Caifu Li, Jinlong Chen, Xi Zhang, Fang Liu
Summary: Chemical looping combustion (CLC) is a technique that utilizes oxygen carriers (OCs) to transfer oxygen and heat between fuel reactor and air reactor. The attrition of OCs is a major impediment to the large-scale application of CLC technology. In this study, the effects of different biomass ashes on the reactivity and attrition resistance of red mud OCs were investigated. The results showed that the rape straw ash promoted the reactivity of OCs, while the bagasse ash improved the attrition resistance. The corn straw ash was found to be an effective material for strengthening the skeleton structure of OCs, enhancing both reactivity and attrition resistance.
Article
Engineering, Environmental
Amr Abdalla, Mansour Mohammedramadan Tijani, Mohanned Mohamedali, Nader Mahinpey
Summary: This study investigated the effects of introducing WO3 into NiO/ZrO2 oxygen carriers for methane CLC, and found that the dual metal oxide oxygen carriers exhibited enhanced oxygen capacity and lower carbon formation compared to their monometallic counterparts. The introduction of WO3 into the NiO/ZrO2 lattice structure led to the formation of an intermediate phase (NiWO4) which improved oxygen carriers' reducibility and metal dispersion. Impregnation synthesis method showed superior performance in terms of cyclic stability and coking resistance.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Applied
Yunchang Dong, Yanan Wang, Jinchen Ma, Hengfeng Bu, Chuanbao Zheng, Haibo Zhao
Summary: In this study, composite oxygen carriers were prepared using extrusion-spheronization method with fine iron and copper ores as raw materials and inert aluminosilicates as binders. After optimization, the oxygen carriers showed good performance in terms of reactivity and stability, indicating the suitability of the method for large-scale preparation of oxygen carrier particles.
FUEL PROCESSING TECHNOLOGY
(2021)
Article
Energy & Fuels
Yu Li, Jing Liu, Feng Liu, Yingju Yang
Summary: Chemical-looping combustion (CLC) is a promising combustion technology for fossil fuel utilization and CO2 capture due to its low cost and minimal energy penalty. This study investigates the rational design of oxygen carriers based on spinel CuFe2O4 by balancing the formation energy and transportation barrier of oxygen vacancies. Doping Cr and Co in CuFe2O4 reduces the formation energy and transportation barrier of oxygen vacancies, enabling easier oxygen migration. Cr and Co dopants also improve the reactivity and catalytic performance of CuFe2O4.
Article
Energy & Fuels
Richard A. Newby, Dale L. Keairns, Robert W. Stevens
Summary: The objective of this study was to estimate the cost of commercial production of oxygen carriers (OCs) for large-scale application in the chemical looping combustion (CLC) power generation industry. Two production facility scenarios were considered, and two OC production techniques were addressed. The estimated OC product costs can be used to guide development and determine the maximum OC makeup rate for achieving a designated cost-of-electricity (COE) reduction goal.
Article
Energy & Fuels
Wu Qin, Laixing Luo, Anwen Feng, Xianbin Xiao, Changqing Dong
Summary: Chemical looping combustion between Fe2O3 and NH3 can lead to the generation of H2O, H-2, NO, and N-2, with the control of oxidation state optimizing the process for H-2 production.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Energy & Fuels
B. Fleiss, J. Fuchs, S. Penthor, S. Arlt, R. Pachler, S. Muller, H. Hofbauer
Summary: Chemical-looping combustion (CLC) is an efficient CO2 separation technology that uses a metal oxide as an oxygen carrier. It has the potential to be used with solid fuels, particularly biomass. This study presents the design and results of a laboratory reactor for fundamental investigation of oxygen carriers. The reactor allows for cheap and rapid pre-testing of materials and has shown promising results for recommending operation in larger plants.
BIOMASS CONVERSION AND BIOREFINERY
(2023)
Review
Energy & Fuels
Sanaz Daneshmand-Jahromi, Mohammad Hashem Sedghkerdar, Nader Mahinpey
Summary: This review provides a detailed understanding of the selection and fabrication methods of oxygen carrier (OC) materials for Chemical Looping Combustion (CLC) up to 2022. The CLC process is a well-known technology for capturing CO2 emissions and generating energy. Scaling up the CLC process requires the development of suitable OCs with high oxygen transport capacity, reactivity, and stability. The review covers the fundamentals of the CLC process, kinetics of reduction and oxidation reactions, and various fabrication methods for OC materials. Synthetic OCs are extensively discussed, including mechanical mixing, sol-gel, co-precipitation, impregnation, freeze granulation, and spray-drying. The review also summarizes the different lab and pilot-scale operating facilities.
Article
Thermodynamics
Yang Wang, Zhenshan Li
Summary: The redox kinetics of oxygen carrier in chemical looping plays a crucial role in material preparation, reactor design, and process demonstration. This study presents a DFT-based microkinetic rate equation theory to predict the heterogeneous kinetics of Fe2O3 reduction by CO in chemical looping. By combining density functional theory (DFT) calculations with transition state theory (TST) and bulk diffusion consideration, a rate equation is developed to bridge the gap between elementary surface reactions and grain conversion. Experimental data validation shows the accuracy and effectiveness of the developed theory in predicting the redox kinetics of oxygen carriers.
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2023)
Article
Energy & Fuels
Pietro Bartocci, Alberto Abad, Arturo Cabello Flores, Margarita de las Obras Loscertales
Summary: To address the scale-up challenges of Chemical Looping Processes, the development of efficient and affordable oxygen carriers is crucial. Ilmenite, an ore-derived oxygen carrier, has been identified as an abundant and low-cost option. This paper provides insights into its preparation, reactivity, and performance compared to other carriers, along with its thermodynamic properties and kinetics. The paper also explores its compatibility with various fuels (solid, liquid, gaseous, including biofuels) and discusses important considerations such as cost, environmental sustainability, oxygen transport capacity, as well as issues related to fluidized bed reactors, such as agglomeration and attrition behavior. Furthermore, the paper investigates the interaction between ilmenite and fuels, including the impact of impurities and coke deposition on the gasification rate of solid fuels.
Article
Chemistry, Physical
Alaa H. Alminshid, Mohammed N. Abbas, Hayder A. Alalwan, Abbas J. Sultan, Mohammed A. Kadhom
Summary: Adsorption of acetone on MgO nanoparticles surface leads to activation of aldol condensation reaction forming di-acetonealcohol (DAA), while the OH group on MgO surface acts as an inhibitor for the further dehydration to mesityl oxide. Basic sites concentration on MgO surface plays a crucial role in the catalytic reaction, with high-strength basic sites representing only 17.5% of total concentration and low-strength basic sites representing 22.5%. Multiple components are produced from acetone interaction on MgO surfaces, providing essential insights into catalytic reactions.
MOLECULAR CATALYSIS
(2021)
Review
Environmental Sciences
Hayder A. Alalwan, Alaa H. Alminshid
Summary: This report discusses recent advancements in CO2 capturing methods, with a focus on chemical looping combustion (CLC) as a promising technology. CLC is highlighted for its ability to reduce the cost of CO2 separation and concentrate the captured CO2, making it a feasible option for carbon capture.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Biotechnology & Applied Microbiology
Sajjad Khudhur Abbas Al-Amshawee, Mohd Yusri Bin Mohd Yunus, Hayder A. Alalwan, Woo Hyoung Lee, Fei Dai
Summary: This study investigated the performance of 9 synthetic and 8 natural biofilm carriers in treating palm oil mill effluent for 7 days at 35 degrees C. The green ammonia absorption stone had the highest COD removal rate on the 7th day, while K1 micro had the best performance among synthetic carriers.
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
(2022)
Article
Spectroscopy
Alaa H. Alminshid, Hayder A. Alalwan, Hadeel A. Abdulghani, Malik M. Mohammed
Summary: A simple, rapid, accurate, and sensitive UV-Visible spectrophotometric method has been developed for estimating ephedrine hydrochloride (Eph) in pharmaceutical drugs. The method involves the formation of a chelate complex between Eph and cobalt ion (Co (II)). The method offers advantages of low cost, high sensitivity, and ease of operation.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2022)
Article
Chemistry, Physical
Malik M. Mohammed, Hayder A. Alalwan, Alaa Alminshid, Saif Ali Mohammed Hussein, Mohammed Fakhir Mohammed
Summary: The study evaluated the removal efficiency of sulfur compounds from heavy naphtha using oxidation and adsorption processes. IPAC showed superior performance in both oxidation and adsorption due to its physicochemical properties. The maximum desulfurization efficiency achieved was 97% for IPAC and 93% for CPZ13X, with adsorption capacities of 21.83 mg/g and 20.93 mg/g, respectively.
CATALYSIS COMMUNICATIONS
(2022)
Article
Engineering, Chemical
Hayder A. Alalwan, Alaa H. Alminshid, Malik M. Mohammed, Mohammed Fakhir Mohammed
Summary: In this study, the CH4 reaction on metal oxide surfaces was investigated using in situ spectroscopy. It was found that CH4 adsorbs on the surfaces as methoxy and formate, reacts with lattice oxygen to form bicarbonate, and decomposes to CO2 and water vapor.
PARTICULATE SCIENCE AND TECHNOLOGY
(2023)
Article
Engineering, Chemical
Hayder A. Alalwan, Alaa Alminshid, Malik M. Mohammed, Mohammed Fakhir Mohammed
Summary: In this study, CO2 adsorption on the surfaces of CoO, CuO, and α-Fe2O3 nanoparticles was investigated using DRIFTS. The results showed that carbonate species were predominantly observed on CoO and CuO surfaces, while bicarbonate species were more prevalent on α-Fe2O3 surfaces.
CHEMICAL ENGINEERING & TECHNOLOGY
(2023)
Article
Engineering, Civil
Mohanad Hatem Shadhar, Malik M. M. Mohammed, Mazin Hussien Abdullah, A. H. A. Shather, Hayder A. Alalwan
Summary: The influence of adding Megaterium and Subtilis bacteria with different concentrations and nutrient amounts to concrete mixture on the self-healing ability of concrete was investigated. The impact of exposure to a sulfate environment on the compressive strength of concrete was also studied. The results showed that the best performance was observed in the Megaterium bacteria specimen with a proportion of 15% and a nutrient content of 1.2%, with a reduction in water penetration depth of 56-59% compared to the control mix.
INNOVATIVE INFRASTRUCTURE SOLUTIONS
(2023)
Article
Green & Sustainable Science & Technology
Lizan Mahmood Khorsheed Zangana, Abdulelah Hameed Yaseen, Qais Hussein Hassan, Malik M. Mohammed, Mohammed Fakhir Mohammed, Hayder A. Alalwan
Summary: This study aims to investigate the impact of blending diesel fuel with kerosene on engine performance and fuel consumption. The results show that blending ratios up to 14% do not significantly affect the engine performance and fuel consumption. Blending diesel with kerosene can help reduce pollutant emissions and engine noise intensity.
CLEANER ENGINEERING AND TECHNOLOGY
(2023)
Article
Green & Sustainable Science & Technology
Hayder A. Alalwan, Nisreen Sabti Mohammed Ali, Malik M. Mohammed, Mohammed F. Mohammed, Alaa H. Alminshid
Summary: This study compares the efficiency of peroxi-coagulation (PC) and peroxi-electrocoagulation (PEC) methods for removing methyl green (MG) stains from aqueous solutions. The results show that both PC and PEC can achieve high MG removal rates of 98.65% and 99.89%, respectively, under optimal operating conditions. It was also found that pH and current density have a significant influence on the removal efficiency.
CLEANER ENGINEERING AND TECHNOLOGY
(2023)
Article
Environmental Sciences
Basima Abbas Jabir Al-humairi, Nadhum Shamkhi Rahal, Hayder A. Alalwan
Summary: This research used 11 years of climate data from a metrological directorate to predict the relationship between surface water runoff and infiltration rate. Statistical analysis was performed using data fit software package to study the correlation between surface water runoff and temperature, rainfall, relative humidity, wind speed, and infiltration rate index. Parameters like coefficient of determination, standard estimated error, root mean squared error, mean absolute error, and relative error were calculated to verify the generated model and determine the coefficient of runoff to precipitation.
INTERNATIONAL JOURNAL OF HYDROLOGY SCIENCE AND TECHNOLOGY
(2023)
Article
Environmental Sciences
Hayder Abdulkhaleq Alalwan, Alaa Hani Alminshid, Malik Mustafa Mohammed, Mohammed Fakhir Mohammed, Mohanad Hatem Shadhar
Summary: Increasing water pollution is a severe global issue. Adsorption, particularly using nanomaterials, has gained interest due to its low cost and high efficiency. However, there are limitations to the commercial-scale application of nanomaterials in water treatment.
Article
Environmental Sciences
Nisreen Sabti Mohammed Ali, Hayder A. Alalwan, Alaa H. Alminshid, Malik M. Mohammed
Summary: In this study, Fe3O4-SiO2 nanoparticles were synthesized and used as an adsorbent material for the removal of methyl blue stain from water. The nanoparticles were characterized and the influence of various parameters on the removal percentage and adsorption capacity was investigated. The results showed that the prepared material had excellent surface area and pore volume, resulting in high adsorption efficiency under optimal operating conditions.
Article
Chemistry, Multidisciplinary
Malik M. Mohammed, Nisreen Sabti Mohammed Ali, Hayder A. Alalwan, Alaa H. Alminshid, Haydar A. S. Aljaafari
Summary: ZnO-CoO/Al2O3 nanoparticles were synthesized as a catalyst for ethanol dehydrogenation to produce acetone, with optimal conditions identified as a temperature of 400 degrees C, a water/ethanol molar ratio of 7:1, and a liquid hourly space velocity of 1.2 hr(-1), resulting in ethanol conversion of 97% and the highest acetone yield of 45%. The catalyst was characterized using various techniques to determine particle size, surface area, and crystallinity.
RESULTS IN CHEMISTRY
(2021)
Article
Engineering, Multidisciplinary
Shaalan G. Afluq, Majid F. Hachim, Zaman K. Ibrahim, Hayder A. Alalwan
Summary: This research focuses on enhancing the mechanical properties of windshields, with results showing that adding 5% polycarbonates resin can achieve the best effect. However, UV exposure can deteriorate the performance of the glass.
JOURNAL OF ENGINEERING SCIENCE AND TECHNOLOGY
(2021)