Article
Energy & Fuels
Guangchun Song, Yuxing Li, Amadeu K. Sum
Summary: This study systematically analyzed the thermal properties of hydrate deposits formed on pipe walls, revealing their insulating effects and potential for blockages in oil and gas production flowlines. By conducting experiments and calculations on the hydrate deposit thickness and thermal conductivity, valuable insights were gained for managing hydrates in deadlegs and flowlines.
Article
Energy & Fuels
Yue Xu, Jialu Zhang, Kunming Song, Xin Geng, Yuxing Li, Wuchang Wang
Summary: The decomposition process of the hydrate deposition layer in the gas-water system was studied using a high-pressure transparent rock-flow cell. It was found that the decomposition rate was faster when using the depressurization method compared to the heating method. An electrical signal-based method for monitoring the decomposition of the hydrate layer on the pipe wall was proposed. Different decomposition mechanisms were observed depending on the heating or depressurization method.
Article
Energy & Fuels
Zhiyuan Wang, Pengfei Li, Shikun Tong, Jianbo Zhang, Chenru Zhou, Jihao Pei, Hemin Yang, Chenwei Liu
Summary: In this study, a high-pressure visualization microscopic force testing system was used to investigate the adhesion force between methane hydrate particles and wall droplets. The results showed that the adhesion force reached the lowest value at a QAs1 solution concentration of 0.2 wt% (CMC), with values of 589.81 mN/m and 1123.63 mN/m under 1 and 10 subcooling conditions, respectively. The mechanism of QAs1 in reducing adhesion force was found to be mainly through the reduction of gas-water interfacial tension under lower subcooling conditions and the steric hindrance effect of QAs1 molecules under higher subcooling conditions.
Article
Energy & Fuels
Zhiming Liu, Xin Geng, Yan Gao, Haiyuan Yao, Haihong Chen, Zhigang Li, Guangchun Song, Wuchang Wang, Yuxing Li
Summary: This study explored the effect of wax content on hydrate formation and deposition, and observed the macroscopic and microscopic morphology of the hydrate deposit layer. The study found that wax influenced the morphology and growth pattern of hydrate, and proposed corresponding mechanisms. Additionally, the adhesive force of hydrate formed in different wax content was measured. This work provides insights on the interaction of hydrate and wax, and can improve flow-assurance strategies in oil-gas production.
Article
Thermodynamics
Juan He, Xiaosen Li, Zhaoyang Chen, Xiaoliang Huang, Pengfei Shen
Summary: This study investigates the effect of heterogeneous hydrate distribution on hydrate production. The results show that the heterogeneity degree of hydrate distribution influences water and gas production, as well as the temperature loss and sensible heat use ratio. The impact is most significant when the hole combination is 1-2 holes.
Article
Thermodynamics
Lanyun Wang, Yajuan Zhang, Huilong Xie, Xiaoran Lu, Xinglin Wen, Zhen Liu, Huajian Zhou, Zejian Liu, Yongliang Xu
Summary: The experimental study showed that varying voltage and initial temperature conditions can affect key parameters of CO2 hydrate, such as morphology, phase equilibrium temperature, induction time, and rapid growth time. Among the voltage conditions, 1.0 KV demonstrated the most significant impact on CO2 hydrate performance.
Article
Energy & Fuels
Evgeny Chuvilin, Valentina Ekimova, Dinara Davletshina, Boris Bukhanov, Ekaterina Krivokhat
Summary: Permafrost composed of sand with silt and clay components may store stable and metastable gas hydrates, which can lose stability under dissolved salts. The effect of silt and clay percentage and mineralogy on salt and water transport and gas hydrate dissociation in frozen sand is studied in laboratory experiments. Sediments with higher clay percentages show slower salt migration and higher critical salt concentration, while salt migration is slower in sand with montmorillonite and faster in sand with higher silt contents.
Article
Energy & Fuels
Qiang Gao, Jianzhong Zhao, Jian Guan, Chi Zhang
Summary: The study examines the memory effect on the synthesis of CO2/CH4 mixed gas hydrate and its impact on factors such as induction time, gas consumption rate, change of gas components, and separation factor. The memory effect shortens the induction time of the second synthesis and is influenced by decomposition time and pressure. It improves the nucleation rate and CO2 selectivity, providing a novel approach for mixed gas separation via hydrate method.
Article
Engineering, Environmental
Yu-Hsuan Ho, Yau Zu Khoo, Yan-Ping Chen, Ryo Ohmura, Li-Jen Chen
Summary: This study investigates the thermodynamic and kinetic influence of polyethylenimine (PEI) on the formation of methane and carbon dioxide hydrates. It is found that PEI acts as a thermodynamic inhibitor, inhibiting the formation of hydrates. However, it has different effects on methane and carbon dioxide hydrates kinetically, inhibiting methane hydrate formation and promoting carbon dioxide hydrate formation.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Energy & Fuels
Yu Wei, Maeda Nobuo
Summary: This study investigates the nucleation kinetics of CO2 hydrate and compares it to the nucleation kinetics of methane/propane mixed gas hydrate. The results show that stainless-steel walls promote the nucleation of CO2 hydrate and CO2 hydrate has higher nucleation rates than methane/propane mixed gas hydrate.
Article
Energy & Fuels
Xuemin Zhang, Mengjun Zhang, Pengyu Li, Jinping Li, Yingmei Wang, Qingbai Wu
Summary: This study investigated the formation characteristics of CO2 hydrate in porous media with the addition of Sodium Dodecyl Sulfate (SDS). The results showed that surfactant can promote the formation process of CO2 hydrate and increase the gas storage capacity. Temperature and SDS concentration also play a role in hydrate formation.
Article
Environmental Sciences
Fengyi Mi, Zhongjin He, Guosheng Jiang, Fulong Ning
Summary: This study investigates the formation of CH4 hydrates in clay nanopores under the influence of marine environmental factors such as seawater salinity, pressure, and temperature. The results reveal that high salinity hinders diffusion, high pressure promotes diffusion, and high temperature causes phase separation.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Energy & Fuels
Gabriel Santos, Nagu Daraboina, Cem Sarica
Summary: This study investigates the influence of wall temperature on the wax particulate deposition mechanism. Higher wall temperature leads to lower growth rate and thinner deposit thicknesses, especially in laminar cases. Wall temperature also affects the size of agglomerates, with higher wall temperature resulting in smaller agglomerates.
Article
Energy & Fuels
Caifeng Yang, Mucong Zi, Guozhong Wu, Xue Zou, Kai Liu, Daoyi Chen
Summary: This study evaluated the influence of kinetic hydrate inhibitor (KHI) on methane - propane hydrate formation kinetics under different subcooling and concentration conditions. It proposed a "concentration effect" concept that highlighted the nonmonotonic relationship between KHI performance and concentration. Two hypotheses were proposed to explain this phenomenon, and the results showed that the concentration effect became less obvious under certain experimental conditions.
Article
Energy & Fuels
Yau Zu Khoo, Yu-Hsuan Ho, Kuang-Yu Chang, Yan-Ping Chen, Li-Jen Chen
Summary: This study determined the dissociation conditions of methane hydrates influenced by reline DES, urea, and choline chloride, and found that these additives demonstrated an inhibitory effect on methane hydrate formation.
Article
Engineering, Chemical
Carlos L. Bassani, Jean-Michel Herri, Ana Cameirao, Rigoberto E. M. Morales, Amadeu K. Sum
Summary: This study proposes a criterion for safely transporting gas hydrate slurries in oil-dominant flowlines. The criterion emphasizes the importance of factors such as subcooling of crystallization, water cut, mixture velocity, and oil-water interfacial tension, and introduces a simple chart for ensuring safe slurry flow. The study also discusses scaling up laboratory measurements to field conditions using a new dimensionless group, the Bassani number.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2021)
Editorial Material
Chemistry, Multidisciplinary
Fei Wang, Amadeu K. Sum, Bei Liu
FRONTIERS IN CHEMISTRY
(2021)
Article
Energy & Fuels
Gustavo A. B. Sandoval, Marcio Couto Ozorio, Monica F. Naccache, Paulo R. de Souza Mendes, Amadeu K. Sum, Leandro Valim, Adriana Teixeira
Summary: This work presents a rheological analysis of cyclopentane hydrates formed in water-in-oil emulsions, investigating the influence of parameters such as pretreatment temperatures and cooling/heating rates. The study shows that the resulting hydrate slurry exhibits elasticity and shear thinning behavior, likely caused by breakdown of hydrate structures and alignment of hydrate agglomerates to the flow.
Article
Energy & Fuels
Mucong Zi, Xianwei Zhang, Luqman Mahir, Khalid Mateen, Thierry Palermo, Amadeu K. Sum
Summary: Wax deposition is a common flow assurance issue in oil/gas production and transportation, and can be measured and characterized using a new experimental system. The study finds that the deposition process involves time variation and different mechanisms.
Article
Energy & Fuels
Celina Kakitani, Daniela C. Marques, Adriana Teixeira, Leandro Valim, Moises A. Marcelino Neto, Amadeu K. Sum, Rigoberto E. M. Morales
Summary: This study focused on identifying parameters that influence hydrate formation in shut-in and restart conditions in offshore oil production. Results showed that shear rate and subcooling are key parameters, and the addition of anti-agglomerant reduces water-oil interfacial tension, promoting water/hydrate dispersion.
Article
Engineering, Chemical
Daniela C. Marques, Carlos L. Bassani, Celina Kakitani, Moises A. Marcelino Neto, Amadeu K. Sum, Rigoberto E. M. Morales
Summary: Measurements of gas hydrate deposition under sheared conditions are analyzed in this study. The experiments focus on methane hydrates and methane-ethane mixtures, examining wall deposition and gas consumption during hydrate formation, and providing mathematical insights.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Chemistry, Multidisciplinary
Kwangbum Kim, Sang-Gyu Cho, Jeong-Hoon Sa
Summary: Carbon capture and sequestration using gas hydrates is a clean process gaining attention. Amino acids, with their unique hydrogen-bonding and hydrophilic properties, show promise as effective inhibitors for CO2 hydrates, lowering water activity, delaying formation kinetics, and surpassing traditional inhibitors in some cases. Their use minimizes environmental risks and corrosion issues, making them ideal for a wide range of temperature and pressure conditions required for carbon capture and sequestration processes.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Energy & Fuels
Wonjung Choi, Junghoon Mok, Jonghyuk Lee, Yohan Lee, Jaehyoung Lee, Amadeu K. Sum, Yongwon Seo
Summary: In this study, the guest exchange behaviors in hydrate-bearing sediment during depressurization-assisted replacement were experimentally investigated. The results showed that the replacement efficiency and CH4 production rate were significantly enhanced through depressurization-assisted replacement. Additionally, a larger amount of CO2 could be stored in the hydrate-bearing sediment.
Article
Energy & Fuels
Yohan Lee, Taras Y. Makogon, Amadeu K. Sum
Summary: In this study, the growth of hydrate deposits from water-saturated gas in a vertical pipe system under temperature and pressure conditions representative of a well shutdown was investigated. The study found that gas convection and water condensation affect the growth rate and morphology of hydrate deposits.
Article
Chemistry, Physical
Yong Chen, Satoshi Takeya, Amadeu K. Sum
Summary: This study reports the observation of a hidden clathrate structure, the tetragonal structure (TS-I), in gas hydrates. The TS-I forms as a cocrystal when two or more sI crystal grains with different growth directions come into contact or when the growth of an sI crystal encounters geometrical frustration. The results imply that TS-I may play an important role in the combination and/or transition between sI and sII.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2022)
Article
Multidisciplinary Sciences
Yong Chen, Satoshi Takeya, Amadeu K. Sum
Summary: Clathrate hydrates are ordered structures stabilized by hydrophobic interactions between water and guest molecules. In this study, an alternative method is proposed to understand the complex structures of clathrate hydrates, revealing the diverse crystalline hydrogen-bonded networks that can be formed. The topological dual relations between clathrate hydrate networks and tetrahedrally close-packed structures provide insights into their nucleation, phase transition, and co-existence mechanisms. Molecular dynamics simulations are employed to explore the intrinsic structural relationships of clathrate hydrates and other unrelated ordered materials.
NATURE COMMUNICATIONS
(2023)
Article
Thermodynamics
Kwangbum Kim, Hai Son Truong-Lam, Ju Dong Lee, Jeong-Hoon Sa
Summary: This article presents a method for achieving the highest CO2 and CH4 gas uptake kinetics in clathrate hydrates without any chemical additives or mechanical mixing. Using surface-modified silica sand in a fixed-bed reactor greatly enhances mass transfer. This method has significant implications for energy storage and carbon capture.
Article
Energy & Fuels
Yohan Lee, Taras Y. Makogon, Amadeu K. Sum
Summary: In this study, the deposition kinetics and morphology of methane hydrates were investigated at 10 MPa. It was found that non-volatile thermodynamic hydrate inhibitors (THIs) were ineffective in preventing hydrate formation near the wellhead, while volatile THIs could prevent hydrate deposition even under cold conditions. However, volatile THIs only delayed the growth of hydrate deposits in warm wellheads. The study provides insight into better management strategies for THI usage to mitigate hydrate blockage risk near the wellhead.
Article
Engineering, Chemical
Kwangbum Kim, Jeong-Hoon Sa
Summary: Capturing CO2 from exhaust gases by forming clathrate hydrates has great potential due to its mild operating conditions, economic feasibility, and environmental friendliness. However, the slow CO2 uptake kinetics and separation efficiency have hindered the realization of hydrate-based CO2 capture. In this study, the effect of the water-to-gas molar ratio (W/G ratio) on pre-combustion capture using clathrate hydrates was investigated, along with the use of residual liquid water and limiting the concentration of tetrahydrofuran (THF) to improve separation efficiency. Through a comprehensive evaluation, the optimal condition was determined to be 3 mol% THF + high W/G ratio. These findings emphasize the importance of considering the W/G ratio and its combined effects with other parameters for advanced pre-combustion capture using clathrate hydrates towards carbon neutrality.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Energy & Fuels
Ana C. G. A. Rebello, Gustavo A. B. Sandoval, Monica F. Naccache, Paulo R. de Souza Mendes, Amadeu K. Sum, Adriana Teixeira, Leandro Valim
Summary: This research investigates the formation of ethane gas hydrates in water-in-model oil emulsions. The results show that increasing the subcooling, water cut, and shear rate can reduce the induction period of the hydrates. The amount of water converted to hydrate can be estimated by analyzing the viscosity and pressure curves.
GEOENERGY SCIENCE AND ENGINEERING
(2023)