Catalytic Exhaust Gas Recirculation-Loop Reforming for High Efficiency in a Stoichiometric Spark-Ignited Engine through Thermochemical Recuperation and Dilution Limit Extension, Part 1: Catalyst Performance

The use of fuel reformate from catalytic processes is known to have beneficial effects on the spark-ignited combustion process through enhanced dilution tolerance and decreased combustion duration, but, in many cases, reformate generation can incur a significant fuel penalty. In this two-part investigation, we demonstrate that efficient catalytic fuel reforming can result in improved brake engine efficiency while maintaining stoichiometric exhaust under the right conditions. In Part 1 of this investigation, we used a combination of thermodynamic equilibrium calculations and experimental fuel catalytic reforming measurements on an engine to characterize the best possible reforming performance and energetics over a range of equivalence ratios and O-2 concentrations. Ideally, one might expect the highest levels of thermochemical recuperation for the highest catalyst equivalence ratios. However, reforming under these conditions is highly endothermic, and the available enthalpy for reforming is constrained. Thus, for relatively high equivalence ratios, more methane and less H-2 and CO are produced. Our experiments revealed that this suppression of H-2 and CO could be countered by adding small amounts of O-2, yielding as much as 15 vol % H-2 at the catalyst outlet for 4 < Phi(catalyst) < 7 under quasi-steady-state conditions. Under these conditions, the H-2 and CO yields were highest and there was significant water consumption, confirming the presence of steam reforming reactions. Analyses of the experimental catalyst measurements indicated the possibility of both endothermic and exothermic reaction stages and global reaction rates sufficient to enable the utilization of higher space velocities than those employed in our experiments. In a companion paper detailing Part 2 of this investigation, we present results for the engine dilution tolerance and brake engine efficiency impacts of the reforming levels achieved.