4.5 Article

Experimental Study of the Pore Structure and Permeability of Coal by Acidizing

Journal

ENERGIES
Volume 11, Issue 5, Pages -

Publisher

MDPI
DOI: 10.3390/en11051162

Keywords

acidizing; coal; specific surface area; pore volume; permeability; HCl-HF system

Categories

Funding

  1. National Key Research and Development Pro-gram [2016YFC0801402-4]
  2. National Natural Science Foundation of China [51574280, 51774319]
  3. Chongqing Frontiers and Application based Research Program [cstc2015jcyjBX0076]
  4. Chongqing science and technology innovation leader talent support program [CSTCKJCXLJRC14]

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The permeability of coal reservoirs prominently determines methane flow in reservoirs. A large amount of coal reservoirs containing methane, however, have low permeability because pores in reservoirs are sealed. To solve this issue, we investigated the pore structure and permeability law of coal through contrastive analysis of the microstructure and macrostructure before and after acidizing, using ASAP 2020 and triaxial servo-controlled seepage equipment. An analysis of the experimental data revealed the mechanism and the key parameters of acidizing, such as acid mass fraction and acidizing time. In addition, we hold that the optimal mass fraction for the test specimens is about 12 similar to 15%. Furthermore, the acid reaction is divided into three stages according to characteristics of the reaction progress. An analysis of the reaction kinetics of HCl-HF states that the significant factors will impact the process of reaction, like the composition of coal, surface area of the acid-coal reaction, mass fraction of acids, and environment of the reaction system. The results provide a new idea and research method for further enhancing permeability and gas extraction.

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