Journal
ELECTROCHIMICA ACTA
Volume 283, Issue -, Pages 1300-1312Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2018.07.047
Keywords
Ti-10V-2Fe-3Al titanium alloy; Passive film; Nanocrystal; Electrochemical test; XPS
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Funding
- National Key Technology R&D Program of China [2015BAG20B04, 2015BAF06B01-3]
- National Key Research and Development Program of China [2016YFC0801903, 2017YFF0210002]
- National Natural Science Foundation of China [51175023, U1537212]
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Present research reports the effect of nano-scale martensite (alpha) and beta phase on the passive film formation and electrochemical corrosion behaviour of Ti-10V-2Fe-3Al alloy in the 3.5% NaCl solution. Nanocrystals with different alpha/beta phase proportion were obtained by room temperature (RT) and Low temperature (LT) burnishing processing. The results show that nano-scale martensite and beta phase could promote the growth of passive film and the diffusion of element V, respectively. Corrosion resistance of Ti-10V-2Fe-3Al alloy was enhanced due to the presence of passive film with large thickness and stability, resulting from nano-scale martensite and more beta phase in the alloy. Combined with the results of passive film and electrochemical corrosion, a probable mechanism is proposed to interpret the influence of nano-scale martensite (alpha) and beta phase on the passive film formation and corrosion behaviour of Ti-lOV-2Al-3Fe titanium alloy. (C) 2018 Elsevier Ltd. All rights reserved.
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