4.6 Article

Ultra-thin bacterial cellulose/poly(ethylenedioxythiophene) nanofibers paper electrodes for all-solid-state flexible supercapacitors

Journal

ELECTROCHIMICA ACTA
Volume 271, Issue -, Pages 624-631

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2018.03.155

Keywords

Bacterial cellulose; Polyethylenedioxythiophene; Ultra-thin electrodes; All-solid-state flexible supercapacitor

Funding

  1. NSFC International (Regional) Joine Research Project NSFC-SNSF [51661135023]
  2. NSFC [21103057]
  3. 973 Program of China [2014CB643506]
  4. Fundamental Research Funds for the Central Universities [HUST: 2016YXMS031]
  5. WNLO
  6. Open Funds of the State Key Laboratory of Electroanalytical Chemistry [SKLEAC201607]

Ask authors/readers for more resources

Ultra-thin, flexible supercapacitors for portable energy storage devices and intermittent electronic applications are closer to reality. This study developed a kind of thin flexible nanofibers paper electrodes (only about 12 mm in thickness) for all-solid-state supercapacitors, which combines the features of three-dimensional porous structure from bacterial cellulose (BC) and the advantages of highly ordered conductive polymer chains from polyethylenedioxythiophene (PEDOT). The capacity and conductivity of the conductive polymer PEDOT, which was coated evenly on the surface of BC nanofibers, were exploited sufficiently. And the flexible symmetric supercapacitors device assembled with the paper electrodes demonstrated an attractive electrochemical performance (a specific volumetric capacitance of 106.3 F cm(-3) at a current density of 0.83 A cm(-3)) and an excellent cyclic stability. The electrical and mechanical properties of the devices still keep stable under various flexible conditions. So this material maybe a new choice for flexible energy-storage devices. (C) 2018 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Multidisciplinary

Large-Area Flexible Organic Solar Cells with a Robust Silver Nanowire-Polymer Composite as Transparent Top Electrode

Cong Xie, Yang Liu, Wanxia Wei, Yinhua Zhou

Summary: This study reports a strategy to improve the upscaling efficiency of flexible organic solar cells by switching electrode design to avoid the negative effects of the high surface roughness of silver nanowire electrodes. The mechanical robustness of the nanowires is enhanced by introducing a cross-linked poly(sodium 4-styrenesulfonate) layer, and a transparent film is fabricated as the top electrode using water transfer printing.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Chemistry, Multidisciplinary

Improved Molecular Ordering in a Ternary Blend Enables All-Polymer Solar Cells over 18% Efficiency

Yunhao Cai, Cong Xie, Qian Li, Chunhui Liu, Jiaxin Gao, Min Hun Jee, Jiawei Qiao, Yun Li, Jiali Song, Xiaotao Hao, Han Young Woo, Zheng Tang, Yinhua Zhou, Chunfeng Zhang, Hui Huang, Yanming Sun

Summary: Although all-polymer solar cells (all-PSCs) have great commercial potential, their power conversion efficiencies (PCEs) lag behind small molecule acceptor-based counterparts. Achieving optimized morphology and high molecular ordering in all-polymer blends is challenging due to competition between the crystallinity of the polymer donor and acceptor during film formation. In this study, a ternary strategy is employed to modulate the morphology and molecular crystallinity of an all-polymer blend, resulting in improved PCEs and performance.

ADVANCED MATERIALS (2023)

Article Chemistry, Multidisciplinary

Fabrication of High-Quality CsPbI3 Perovskite Films with Phosphorus Pentachloride Additive for Highly Stable Solar Cells

Wanpeng Yang, Haixuan Yu, Letian Dai, Zhiguo Zhang, Anjie Gu, Huaxia Ban, Qiang Sun, Shuangyin Chen, Yan Shen, Mingkui Wang

Summary: This study proposes an effective method using phosphorus pentachloride as an additive to fabricate high-quality and stable CsPbI3 films. The method has great potential in photovoltaic applications.

CHEMSUSCHEM (2023)

Article Chemistry, Multidisciplinary

Organic iodides in efficient and stable perovskite solar cells: strong surface passivation and interaction

Guanhua Ren, Zhiguo Zhang, Yanyu Deng, Zhuowei Li, Chunyu Liu, Mingkui Wang, Wenbin Guo

Summary: Surface passivation with organic iodides is crucial for high-performance perovskite solar cells (PSCs), but it often leads to stability degradation due to migration of iodine interstitial (I-i) defects. We found that untreated surface treatment can induce I-i formation and subsequent migration. Cation selection for organic iodides is important, as a strong cation-perovskite surface interaction can suppress I-i migration by increasing the migration energy barrier. Phenylpropylammonium iodide-treated PSCs achieve enhanced efficiency and stability, with a champion efficiency of 24.20% and retaining about 92% of their initial efficiency after 240 hours of continuous illumination.

ENERGY & ENVIRONMENTAL SCIENCE (2023)

Article Chemistry, Physical

A residual strain regulation strategy based on quantum dots for efficient perovskite solar cells

Yinyan Xu, Yingke Ren, Sheng Cheng, Lun Zhang, Pujun Niu, Mei Lyu, Hongbo Lu, Mingkui Wang, Jun Zhu

Summary: Lead halide perovskite films with excellent optoelectronic properties are prepared using a residual strain regulation strategy. By adding ligand-capped CsPbI3 quantum dot solution as an antisolvent, lattice-matching CsPbI3 QDs act as heterogeneous nucleation centers and ligands regulate the crystallization kinetics, reducing residual strain. This strategy improves the film's performance by increasing grain size, decreasing defects, reducing nonradiative recombination, and improving charge transfer efficiency.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Materials Science, Multidisciplinary

Stitching Perovskite Grains with Perhydropoly(Silazane) Anti-Template-Agent for High-Efficiency and Stable Solar Cells Fabricated in Ambient Air

Ting Wang, Qu Yang, Yanli Chen, Qiong Peng, Xiaosi Qi, Hui Shen, Xuncheng Liu, Shaohui Li, Haixuan Yu, Yan Shen, Mingkui Wang, Xiu Gong

Summary: Inorganic CsPbI3 perovskite solar cells (PSCs) with high photoelectric properties face the challenge of phase instability against moisture. A curing-anti-solvent strategy is developed using an inorganic polymer (PHPS) to form a stable black-phase CsPbI3 perovskite film. The PHPS reduces moisture erosion and controls crystal growth, while a polycondensation adduct forms a shield layer to prevent phase transition. These PSCs achieve an efficiency of 19.17% and retain 90% of the initial efficiency after 1000 hours under 30% RH.

ENERGY & ENVIRONMENTAL MATERIALS (2023)

Article Chemistry, Multidisciplinary

Understanding the Composition of Layer-by-Layer Deposited Active Layer at Buried Bottom Surface

Kai Feng, Linya Chen, Jingyu Cheng, Wanxia Wei, Yang Liu, Cong Xie, Xin Lu, Honggang Gu, Sixing Xiong, Yinhua Zhou

Summary: Layer-by-layer (LbL) coating is a widely used method for nonfullerene active layer films in organic solar cells. However, the vertical compositional distribution of the LbL-coated active layer, particularly at the buried bottom surface, is unclear. This study shows that the LbL active layer is a vertical donor-acceptor mixture without a pure polymer donor layer at the bottom surface. The study also reveals that inserting thin polymer layers at the bottom surface significantly deteriorates the device's performance.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Chemistry, Multidisciplinary

A Polymer Defect Passivator for Efficient Hole-Conductor-Free Printable Mesoscopic Perovskite Solar Cells

Junwei Xiang, Chuanzhou Han, Jianhang Qi, Yanjie Cheng, Kai Chen, Yongming Ma, Jiayu Xie, Yue Hu, Anyi Mei, Yinhua Zhou, Hongwei Han

Summary: Printable mesoscopic perovskite solar cells (p-MPSCs) have gained attention due to their low cost and potential for mass production. However, their low open-circuit voltage (V-OC) limits their power conversion efficiency (PCE). In this study, a polymeric Lewis base polysuccinimide (PSI) was added to the perovskite precursor solution as an additive to improve perovskite crystallization, passivate defects, and enhance PCE. The fabricated p-MPSCs achieved a champion device with a PCE of 18.84% and an increased V-OC from 973 to 1030 mV, offering a new strategy for efficient p-MPSC fabrication.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Computer Science, Interdisciplinary Applications

Disclosing the interactive mechanism behind scientists' topic selection behavior from the perspective of the productivity and the impact

Shengzhi Huang, Yong Huang, Yi Bu, Zhuoran Luo, Wei Lu

Summary: This study analyzes the publication sequence of over 20,000 scientists in the computer science field using Microsoft Academic Graph. It confirms the relationship between productivity and impact with the evolution of scientists' research interests. The study proposes a Q seashore walk model based on the interactive mechanism hypothesis to explore how these factors affect topic selection behavior, and finds evidence for the interactive mechanism.

JOURNAL OF INFORMETRICS (2023)

Article Computer Science, Interdisciplinary Applications

Understanding the domain development through a word status observation model

Tongyang Zhang, Ran Sun, Julia Fensel, Andrew Yu, Yi Bu, Jian Xu

Summary: For accurate scientific evaluation and advancement, understanding the development state of a disciplinary domain is crucial. Existing comprehension methods focus on quantitatively analyzing subject trends without considering the underlying complex attributes of supporting words. This study deepens the examination of domain development by using Word2vec to identify semantic neighbors of domain-specific words and classifying their roles as tree structures. The study provides insights into the organizational composition and maturing status, as well as the historical development changes in the domain. The empirical study using attention in psychology as a case reveals different word positions and development trends, indicating areas of thriving, becoming obsolete, precipitating, and irregularly developing within the domain.

JOURNAL OF INFORMETRICS (2023)

Article Computer Science, Interdisciplinary Applications

Analyzing research diversity of scholars based on multi-dimensional calculation of knowledge entities

Chao Yu, Chuhan Wang, Tongyang Zhang, Yi Bu, Jian Xu

Summary: This study proposes using entitymetrics analysis for measuring diversity at the scholar level. Compared to disciplines or topics, entities have advantages in portraying subject categories, detecting content disparities, and characterizing research content distribution patterns, providing a more granular reflection of scholars' research diversity.

SCIENTOMETRICS (2023)

Article Computer Science, Information Systems

Monodisciplinary collaboration disrupts science more than multidisciplinary collaboration

Xin Liu, Yi Bu, Ming Li, Jiang Li

Summary: Collaboration across disciplines is critical for solving complex problems and making innovative contributions. This study examines the relationship between multidisciplinary collaboration in publications and the disruption of science. The findings show that articles with monodisciplinary collaboration are more disruptive than those with multidisciplinary collaboration. The mechanism behind this phenomenon is explored through analysis of the sampled publications' references.

JOURNAL OF THE ASSOCIATION FOR INFORMATION SCIENCE AND TECHNOLOGY (2023)

Article Computer Science, Interdisciplinary Applications

What makes a successful rebuttal in computer science conferences?: A perspective on social interaction

Junjie Huang, Win-bin Huang, Yi Bu, Qi Cao, Huawei Shen, Xueqi Cheng

Summary: This paper conducts an empirical study using over 3000 papers and 13,000 reviews from the prestigious computer science conference ICLR2022 to determine the factors contributing to a successful rebuttal. The study finds that social interactions between authors and reviewers play a crucial role in paper acceptance, and a successful rebuttal often leads to an increased review score.

JOURNAL OF INFORMETRICS (2023)

Article Materials Science, Multidisciplinary

Symmetry breaking: an efficient structure design of nonfullerene acceptors to reduce the energy loss in organic solar cells

Tianyi Liu, Hui Zheng, Xinyu Yu, Shengwei Shi, Yinhua Zhou, Zhong'an Li

Summary: In recent years, the innovative design of small-molecule non-fullerene acceptors (NFAs), particularly fused ring electron acceptors (FREAs), has significantly advanced the development of organic solar cells (OSCs), achieving power conversion efficiencies (PCEs) higher than 19%. However, compared to inorganic and perovskite solar cells, OSCs still exhibit a certain efficiency gap, mainly due to the large energy loss (E-loss). Recently, breaking the symmetry of FREAs has emerged as an effective molecular design strategy to greatly reduce the E-loss to a remarkably low value of 0.44 eV. In this perspective, we summarize the recent progress in asymmetric FREAs and explore the relationship between asymmetric molecular structure, E-loss, and device performance, providing molecular insights for future development of high-performance asymmetric NFAs.

JOURNAL OF MATERIALS CHEMISTRY C (2023)

Article Chemistry, Multidisciplinary

Two-in-one alcohol-processed PEDOT electrodes produced by solvent exchange for organic solar cells

Xinyun Dong, Xianmin Zhou, Yang Liu, Sixing Xiong, Jingyu Cheng, Youyu Jiang, Yinhua Zhou

Summary: In this study, a solvent exchange method was used to prepare alcohol-processed PEDOT:PSS, which showed good wetting ability and high electronic conductivity. The work function of the obtained e-PEDOT:PSS was tuned by adding an alcohol-based fluorinated formulation. The 2-in-1 electrodes fabricated using e-PEDOT:PSS showed an efficiency of 14.02%.

ENERGY & ENVIRONMENTAL SCIENCE (2023)

Article Electrochemistry

Recent advances in Bio-mass by electrochemically strategies generated hydrogen gas production: Environmentally sustainable technologies innovation

Abdul Qayoom Mugheri, Shaista Khan, Ali Asghar Sangah, Aijaz Ahmed Bhutto, Muhammad Younis Laghari, Nadeem Ahmed Mugheri, Asif Ali Jamali, Arsalan Ahmed Mugheri, Nagji Sodho, Abdul Waheed Mastoi, Aftab Kandhro

Summary: Green hydrogen has the potential to transition to a pollution-free energy infrastructure. This study proposes a solution to produce hydrogen during the photoelectrochemical process, offering greater stability and control over chemical reactions. Techno-economic assessments show the efficiency and economic feasibility of co-producing value-added chemicals to enhance green hydrogen production.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

ACGNet: An interpretable attention crystal graph neural network for accurate oxidation potential prediction

Danpeng Cheng, Wuxin Sha, Qigao Han, Shun Tang, Jun Zhong, Jinqiao Du, Jie Tian, Yuan-Cheng Cao

Summary: LiNixCoyMn1-x-yO2 (NCM) is a critical cathode material for lithium-ion batteries in electric vehicles. The aging of cathode/electrolyte interfaces leads to capacity degradation and long-term cycle instability. A novel neural network model called ACGNet is developed to predict electrochemical stability windows of crystals, allowing for high-throughput screening of coating materials. LiPO3 is identified as a promising coating material with high oxidation voltage and low cost, which significantly improves the cycle stability of NCM batteries. This study demonstrates the accuracy and potential of machine learning in battery materials.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Enhanced electrochemical performance of CuO/NiO/rGO for oxygen evolution reaction

P. Mohana, R. Yuvakkumar, G. Ravi, S. Arunmetha

Summary: This study successfully fabricates a non-noble CuO/NiO/rGO nanocomposite and investigates its electrocatalytic performance for oxygen evolution reaction in alkaline environment. The experimental results demonstrate that the electrocatalyst exhibits high activity and good stability, offering a new synthetic approach for sustainable energy production.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Carbon nanofibers implanted porous catalytic metal oxide design as efficient bifunctional electrode host material for lithium-sulfur battery

Qiong Qu, Jing Guo, Hongyu Wang, Kai Zhang, Jingde Li

Summary: In this study, a bifunctional electrode host design consisting of carbon nanofibers implanted ordered porous Co-decorated Al2O3 supported on carbon nanotube film (CNTF) was proposed to address the shuttling effect of lithium polysulfides (LiPSs) and dendrite formation of metal lithium anode in lithium-sulfur (Li-S) batteries. The electrode exhibited excellent conductivity, efficient confinement of LiPSs, and catalytic conversion performance, resulting in high initial capacity and good capacity retention during cycling. As an anode, the electrode showed excellent Li+ diffusion performance and uniform lithium growth behavior, achieving a dendrite-free lithium electrode. The flexible pack cell assembled from these electrodes delivered a specific capacity of 972 mAh g(-1) with good capacity retention.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Spray coating of carbon nanoparticles as an effective and scalable method to enhance the performance of stainless steel anode in microbial electrochemical systems

Hong Zhang, Jin-Peng Yu, Chen Chen, Cheng-Yong Shu, Guang-Yu Xu, Jie Ren, Kai Cui, Wen-Fang Cai, Yun-Hai Wang, Kun Guo

Summary: Spray coating of acetylene black nanoparticles onto stainless steel mesh can enhance its biofilm formation ability and current density, making it a promising electrode material for microbial electrochemical systems. The spray coating method is simple, cost-effective, and suitable for large-size stainless steel electrodes.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Electrochemical properties of Li-rich ternary cathode material Li1.20Mn0.44Ni0.32Co0.04O2 and its oxygen-deficient phase

Binpeng Hou, Jingjin Chen, Li-Hong Zhang, Xiaowen Shi, Zizhong Zhu

Summary: The electrochemical performance of Li1.20Mn0.44Ni0.32Co0.04O2 and its oxygen-deficient phase Li1.20Mn0.44Ni0.32Co0.04O1.83 was studied through first-principles calculations. The results show that the oxygen-deficient phase has a higher theoretical capacity but lower voltage platform and higher chemical activity compared to the pristine phase.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Post-mortem analysis of the Li-ion battery with charge/discharge deterioration in high- and low-temperature environments

Yating Du, Sayoko Shironita, Daisuke Asakura, Eiji Hosono, Yoshitsugu Sone, Yugo Miseki, Eiichi Kobayashi, Minoru Umeda

Summary: This study investigates the effect of high- and low-temperature environments on the charge-discharge performance of a Li-ion battery. The deterioration mechanisms of the battery at different temperatures are analyzed through various characterization techniques. The results indicate that the battery performance deteriorates more significantly at a low-temperature environment of 5 degrees C compared to higher temperatures. The understanding of the deterioration mechanisms can contribute to the development of safer battery usage methods.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

A Co3O4-x/Co nanocomposite with synergistically enhanced electrochemical activity for reduction of nitrite to ammonia

Si-Si Shi, Zhi-Xiang Yuan, Fei Zhang, Ping Chen

Summary: In this study, a new nano-electrocatalyst was prepared, which exhibited superior electrocatalytic activity for the reduction of NO2- to ammonia in a neutral electrolyte, potentially due to the synergistic enhancement between Co3O4-x and Co.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Facile fabrication of NaOH nanorods on pencil graphite electrode for simultaneous electrochemical detection of natural antioxidants by deep eutectic solvent

Berna Dalkiran, Havva Bekirog

Summary: This study reports the use of deep eutectic solvents (DES) based on ethylene glycol and urea as low-cost and green electrolytes for enhancing electrochemical detection of natural antioxidants. The study successfully developed a disposable and effective electrochemical sensing platform for simultaneous determination of ascorbic acid (AA) and gallic acid (GA) using NaOH nanorods on a pencil graphite electrode. The proposed electrode showed improved analytical performance, with higher peak currents and shifted oxidation potentials in DES compared to BR buffer medium.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

A three-dimensional fibrous tungsten-oxide/carbon composite derived from natural cellulose substance as an anodic material for lithium-ion batteries

Sijun Ren, Jianguo Huang

Summary: In this study, a novel bio-inspired nanofibrous WO3/carbon composite was synthesized using a facile hydrothermal method. The three-dimensional network structure of the composite alleviated the volume expansion of WO3 nanorods and enhanced the charge-transport kinetics. The optimized composite exhibited superior lithium storage properties.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Stabilizing the dissolution kinetics by interstitial Zn cations in CoMoO4 for oxygen evolution reaction at high potential

Zhilong Zheng, Yu Chen, Hongxia Yin, Hengbo Xiao, Xiangji Zhou, Zhiwen Li, Ximin Li, Jin Chen, Songliu Yuan, Junjie Guo, Haibin Yu, Zhen Zhang, Lihua Qian

Summary: This study found that interstitial Zn cations in CoMoO4 can modulate the dissolution kinetics of Mo cations and improve the OER performance. The interstitial Zn cations can prevent the dissolution of Co cations at high potential, enhancing the durability of the catalyst.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Molecular insights on optimizing nanoporous carbon-based supercapacitors with various electrolytes

Xiaobo Lin, Shern R. Tee, Debra J. Searles, Peter T. Cummings

Summary: Molecular dynamics simulations using the constant potential method were used to investigate the charging dynamics and charge storage of supercapacitors. The simulations revealed that the water-in-salt electrolyte exhibited the highest charge storage and significantly higher capacitance on the negative electrode. The varying contributions of different electrode regions to supercapacitor performance were also demonstrated.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Interaction between bilirubin oxidase and Au nanoparticles distributed over dimpled titanium foil towards oxygen reduction reaction

Wiktoria Lipinska, Vita Saska, Katarzyna Siuzdak, Jakub Karczewski, Karol Zaleski, Emerson Coy, Anne de Poulpiquet, Ievgen Mazurenko, Elisabeth Lojou

Summary: The spatial distribution of enzymes on electrodes is important for bioelectrocatalysis. In this study, controlled spatial distribution of gold nanoparticles on Ti nanodimples was achieved. The efficiency of enzymatic O2 reduction was found to be influenced by the size of the gold nanoparticles and their colocalization with TiO2. The highest stability of enzymatic current was observed with the largest gold nanoparticles.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Electrochemical supercapacitor and water splitting electrocatalysis applications of self-grown amorphous Ni(OH)2 nanosponge-balls

Tariq M. Al-Hejri, Zeenat A. Shaikh, Ahmed H. Al-Naggar, Siddheshwar D. Raut, Tabassum Siddiqui, Hamdan M. Danamah, Vijaykumar V. Jadhav, Abdullah M. Al-Enizi, Rajaram S. Mane

Summary: This study explores a promising self-growth approach for the synthesis of nickel hydroxide (Ni(OH)2) nanosponge-balls on the surface of a nickel-foam (NiF) electrode. The modified NiF electrode, named Ni(OH)2@NiF, shows distinctive nanosponge-ball morphology and demonstrates excellent energy storage capability and electrocatalytic performance in both hydrogen and oxygen evolution reactions.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Versatile mixed ionic-electronic conducting binders for high-power, high-energy batteries

Rafael Del Olmo, Gregorio Guzman-Gonzalez, Oihane Sanz, Maria Forsyth, Nerea Casado

Summary: The use of Lithium-Ion Batteries (LIBs) is becoming increasingly extensive, and it is important to optimize the devices to achieve their maximum practical specific capacity. In this study, mixed ionic-electronic conducting (MIEC) binders based on PEDOT:PSS and PEDOT: PDADMA-TFSI were developed for Li-ion cathodes, and their performance was compared with conventional formulations. The influence of electrode formulations, including the addition of conducting carbon and an Organic Ionic Plastic Cristal (OIPC), was also analyzed. The proposed binders showed improved performance compared to conventional formulations with different electrolyte types and active materials.

ELECTROCHIMICA ACTA (2024)