4.6 Article

A FeP powder electrocatalyst for the hydrogen evolution reaction

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 92, Issue -, Pages 33-38

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2018.05.020

Keywords

Iron phosphide; Hydrogen evolution reaction; Water electrolysis

Funding

  1. National Natural Science Foundation of China [21603041]
  2. Priority Academic Program Development of Jiangsu Higher Education Institution
  3. Top-notch Academic Programs Project of Jiangsu Higher Education Institutions [PPZY2015B112]

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Petaloid FeP powder is an efficient and robust catalyst for electrochemical hydrogen evolution reaction ( HER) both in the acid and alkaline electrolyte. The whiskers and defects in the petaloid structure can extend the surface area and avoid particles aggregation, thus high electrochemical activity and mechanical structure stability are guaranteed for the HER. Specifically, it needs an overpotential of 110 mV and 185 mV at 10 mA cm(-2) in acid solution and alkaline solution respectively. This powder FeP catalyst is promising in PEM water electrolysis.

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