Article
Materials Science, Ceramics
Xin Geng, Yujuan Xu, Peng Wang, Mingwei Zhang, Guangwu Wen
Summary: Mesocrystals of (NH4)2Ta2O3F6 were successfully constructed through oriented self-assembly and calcination processes, with the formation factors investigated under hydrothermal conditions. The addition of acetic acid altered the morphology evolution of mesocrystals, and sample (NH4)2Ta2O3F6-160 exhibited the highest photocatalytic activity in the degradation of methylene blue.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Physical
Yanting Tang, Jielin Huang, Shuaifei Liu, Dandan Xiang, Xinqi Ma, Xin Yu, Mingxue Li, Quanhui Guo
Summary: Mesocrystals are fascinating multifunctional materials that can create rapid charge transport pathways, and surface engineering plays a significant role in boosting charge separation for efficient photocatalytic application. In this study, surface-engineered Ta2O5-x mesocrystals were synthesized, leading to enhanced visible light photocatalytic activity. The increased surface areas and surface hydroxyl groups compared to commercial Ta2O5 and pristine Ta2O5-x mesocrystals provide more surface reactive sites and high electron density centers for trapping photo-generated holes.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Materials Science, Multidisciplinary
Jieying He, Tongsheng Chen
Summary: Synthesis of cross-like anatase TiO2 structures with excellent photocatalytic activity through thermal treatment of precursors synthesized in an electrochemical cell is studied. The obtained anatase TiO2 products can maintain their original morphologies and structures until 750 degrees C and show good thermal and structural stability. Anatase TiO2 mesocrystals calcined at 600 degrees C exhibit the highest photocatalytic performance.
ELECTRONIC MATERIALS LETTERS
(2023)
Article
Materials Science, Ceramics
Xin Geng, Wenzhe Xu, Peng Wang, Qingyang Du, Haibin Sun, Haoqing Li, Guangwu Wen
Summary: Carbon-coated tantalum-based oxides photocatalysts were synthesized through annealing in argon, demonstrating excellent photocatalytic activity in degrading methylene blue under visible light, indicating their promising potential for wide-ranging photocatalytic applications.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Multidisciplinary
Xinqiang Cao, Yan Gu, Yanfen Fang, David Johnson, Chuncheng Chen, Junsong Chen, Hailin Tian, Yingping Huang
Summary: Microsphere-like bismuth vanadate mesocrystals were synthesized using a simple solvothermal method and applied to the photocatalytic degradation of microcystin-LR. The results showed that these mesocrystals exhibited enhanced photocatalytic activity and stable dispersion and photostability during the degradation process. This study is significant for the development of efficient methods for removing microcystins.
ENVIRONMENTAL CHEMISTRY LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Fenghua Chen, Maosen Yang, Xiangdong Shi, Xiaoyun Qin, Qingtao Chen, Liying Jiang, Chunxiao Jia
Summary: In this study, a ternary photocatalyst of g-C3N4/Ag-TMCs was prepared by photodepositing Ag nanoparticles on the surface of titanium dioxide mesocrystals followed by loading them on g-C3N4. The prepared photocatalyst exhibited excellent photocatalytic activity and the deposited Ag content positively influenced the photocatalytic degradation efficiency. The improved photocatalytic properties were attributed to the synergistic effect created by the LSPR effect of Ag, electron-conduction bridge role of Ag, and the heterojunction structure formed between Ag, TMCs, and g-C3N4.
RESEARCH ON CHEMICAL INTERMEDIATES
(2023)
Article
Environmental Sciences
Giuseppe Vitiello, Giuseppina Iervolino, Claudio Imparato, Ilaria Rea, Fabio Borbone, Luca De Stefano, Antonio Aronne, Vincenzo Vaiano
Summary: Diclofenac is a common emerging contaminant that can be effectively removed from water through photocatalysis. Fluorine-doped ZnO shows good photocatalytic activity for the degradation of diclofenac, primarily due to its high efficiency in generating hydroxyl radicals.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Engineering, Environmental
Xin Yu, Jielin Huang, Jingjing Zhao, Shuaifei Liu, Dandan Xiang, Yanting Tang, Juan Li, Quanhui Guo, Xinqi Ma, Junwei Zhao
Summary: Efficient visible light photocatalytic elimination of pharmaceutical factory wastewater was achieved by introducing hybrid Ag/AgCl nanoparticles into Ti3+ self-doped TiO2 mesocrystals. The Ag/AgCl@Ti3+-TiO2 mesocrystals showed superior performance in degrading tetracycline under visible light, mainly attributed to the continuous attacks of photo-generated holes and radicals on tetracycline molecules.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Xing Gao, Ying Zhang, Bin Yin, Yufei Liu, Tat Thang Nguyen, Shuo Zhang, Yaru Wei, Chunhua Du, Li Li, Minghui Guo
Summary: This study synthesized a new bismuth molybdate photocatalyst, P-Bi2MoO6, using wood waste from sports equipment, which exhibited higher photodegradation efficiency compared to conventional bismuth molybdate. The improved efficiency can be attributed to the decrease in crystallite size, enrichment in surface-active oxygen species, enhanced light absorption, efficient carrier separation, and strengthened charge transfer.
COLLOID AND INTERFACE SCIENCE COMMUNICATIONS
(2021)
Article
Energy & Fuels
Ayat N. El-Shazly, Aiat H. Hegazy, E. T. El Shenawy, Mahmoud A. Hamza, Nageh K. Allam
Summary: The facile synthesis of anatase multi-doped TiO2 mesocrystals with highly energetic {001} facets and their outstanding photocatalytic activity is reported in this study. Various techniques were used to investigate the structural and compositional properties, revealing the fabrication of single crystal-like mesocrystals. The Co-doped C/Ti3+ TiO2 mesocrystals showed an unprecedented hydrogen production rate in water splitting, making them promising candidates for various photocatalytic applications.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2021)
Article
Nanoscience & Nanotechnology
Ali Margot Huerta-Flores, Francisco Ruiz-Zepeda, Cavit Eyovge, Jedrzej P. Winczewski, Matthias Vandichel, Miran Gaberscek, Nicolas D. Boscher, Han J. G. E. Gardeniers, Leticia M. Torres-Martinez, Arturo Susarrey-Arce
Summary: This study synthesized a new RuO2/CuxO/Ta2O5/SrZrO3 heterostructure that achieved a high H-2 production of 5164 mu mol g(-1) h(-1) under simulated solar light, which was significantly higher than other heterostructures. The addition of the binary catalyst CuxO resulted in higher H-2 production. The presence of the binary catalyst improved the charge carrier transport and the solar to hydrogen conversion efficiency.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Environmental Sciences
Esmail Doustkhah, Mohamed Esmat, Naoki Fukata, Yusuke Ide, Dorian A. H. Hanaor, M. Hussein N. Assadi
Summary: We found that MOF-5 can transform into distinct zinc oxide nanostructures, and this transformation can be controlled by temperature and structure-directing agent. A synthesis temperature of 180 degrees C resulted in high crystallinity and superior photocatalytic activity in degrading methylene blue.
Article
Chemistry, Physical
Xinwei Guan, Mohammed Fawaz, Ranjini Sarkar, Chun-Ho Lin, Zhixuan Li, Zhihao Lei, Panangattu Dharmarajan Nithinraj, Prashant Kumar, Xiangwei Zhang, Jae-Hun Yang, Long Hu, Tom Wu, Sudip Chakraborty, Jiabao Yi, Ajayan Vinu
Summary: Graphitic carbon nitrides (g-C3N4) suffer from narrow absorption ranges and high carrier recombination rates in photocatalysis applications. In this work, sulfur-doped high nitrogen containing carbon nitrides (C3N5, SCNs) are prepared by self-assembly of 5-amino-1,3,4-thiadiazole-2-thiol (5-ATDT). The resulting SCNs exhibit an enhanced H-2-generation rate of 486 mu mol g(-1) h(-1), thanks to the enlarged light absorption range and enhanced charge carrier transfer rate. This work provides a unique approach for designing novel sulfur-doped carbon nitrides with unprecedented functionalities.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Spectroscopy
G. Gnanamoorthy, Huma Ali, Virendra Kumar Yadav, Daoud Ali, Gokhlesh Kumar, V. Narayanan
Summary: alpha-NH4(VO2)(HPO4) nanosheets were successfully synthesized by hydrothermal method and characterized by various analysis techniques. The nanosheets exhibited orthorhombic crystalline phase and good thermal stability, making them suitable for applications such as dye degradation.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2022)
Article
Chemistry, Physical
Cheng Cheng, Jian Wang, Zhihao Zhao, Changchun Chen, Sheng Cui, Yifeng Wang, Lin Pan, Yaru Ni, Chunhua Lu
Summary: In this study, a new S-scheme SrTiO3/porous ZnO composite with superior photocatalytic activity was successfully designed and prepared. The composite showed a porous structure, tight contact, and a heterojunction between SrTiO3 and porous ZnO, resulting in higher light absorption and photocatalytic efficiency compared to other samples. The utilization of an S-scheme charge migration process was found to explain the enhanced photocatalytic activity of the composite.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Review
Chemistry, Multidisciplinary
Jia Zhang, Biying Tan, Xin Zhang, Feng Gao, Yunxia Hu, Lifeng Wang, Xiaoming Duan, Zhihua Yang, PingAn Hu
Summary: Atomically thin hexagonal boron nitride (h-BN) is a promising 2D material with unique properties for applications in optoelectronics and electronics. Chemical vapor deposition (CVD) is considered a promising method for producing large-scale, high-quality h-BN films and heterostructures. The epitaxial growth of 2D materials onto h-BN and building heterostructures can lead to novel properties.
ADVANCED MATERIALS
(2021)
Article
Engineering, Electrical & Electronic
Reza Sedehi, David Budgett, Jincheng Jiang, Xia Ziyi, Xin Dai, Aiguo Patrick Hu, Daniel McCormick
Summary: This article presents a capacitively coupled conductive power transfer method for deeply implanted biomedical devices, which ensures safe power transfer into the body with minimal implant volume. The proposed method has been validated through experimental measurements, demonstrating its effectiveness and safety.
IEEE TRANSACTIONS ON POWER ELECTRONICS
(2021)
Article
Chemistry, Multidisciplinary
Feng Gao, Hongyu Chen, Wei Feng, Yunxia Hu, Huiming Shang, Bo Xu, Jia Zhang, Cheng-Yan Xu, PingAn Hu
Summary: By systematically investigating the control of barrier height in vdWHs MIS photodetectors, the optimized graphene/h-BN/SnS2 devices show superior photodetection performance with high photoresponsivity, detectivity, and photocurrent/dark current ratio.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Energy & Fuels
Shuwei Hao, Yunfei Shang, Yuedan Hou, Tong Chen, Weiqiang Lv, Pingan Hu, Chunhui Yang
Summary: The use of a BiOCl shell on upconversion materials can reduce the photoelectron trapping loss on TiO2 photoanodes and enhance the efficiency of dye-sensitized solar cells. This structure also allows for the generation of additional photoelectrons into the photoanode film, leading to a significant increase in power conversion efficiency.
Article
Chemistry, Multidisciplinary
Yunxia Hu, Mingjin Dai, Wei Feng, Xin Zhang, Feng Gao, Shichao Zhang, Biying Tan, Jia Zhang, Yong Shuai, YongQing Fu, PingAn Hu
Summary: In this study, a novel artificial synaptic device is proposed to achieve ultra-low power consumption by increasing channel conductivity and reducing power consumption. The multilayer and polycrystalline MoS2 film demonstrates persistent photoconductivity performance, supporting short-term plasticity and long-term plasticity effectively, with great potential for applications.
ADVANCED MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Shichao Zhang, Feng Gao, Wei Feng, Huihui Yang, Yunxia Hu, Jia Zhang, Haiying Xiao, Zhonghua Li, PingAn Hu
Summary: In this paper, a new MoS2-based hybrid nanoscrolls device is introduced, which effectively enhances the photodetection performance. The photoresponsivity and detectivity values of the MoS2/CQDs-NS photodetectors are significantly higher than those of the pristine MoS2. This research represents a significant progress in fabricating high-performance MoS2 photodetectors.
Article
Chemistry, Multidisciplinary
Feng Gao, Xin Zhang, Biying Tan, Shichao Zhang, Jia Zhang, Dechang Jia, Yu Zhou, PingAn Hu
Summary: The authors have developed an optoelectronic memory based on SnS2/h-BN/graphene heterostructure with an extremely low photo-generated hole tunneling barrier. This floating gate memory exhibits high switching ratio and large memory window range, capable of achieving multilevel storage states under low power light pulses.
Article
Nanoscience & Nanotechnology
Bo Xu, Yang Li, Zhao-Yuan Sun, Ze Zhao, Li Yang, Feng Gao, Ping-An Hu, Liang Zhen, Cheng-Yan Xu
Summary: The charge transfer at the hetero-interface in the WSe2/InSe heterostructure serves as an efficient doping strategy to modulate carrier densities and create lateral homo-junctions with promising rectification, photovoltaic, and photodetection abilities. Device physics of lateral homo-junctions, including potential distribution, band diagram, and photocurrent generation mechanisms, is revealed using scanning probe and scanning photocurrent techniques.
ADVANCED ELECTRONIC MATERIALS
(2021)
Article
Materials Science, Multidisciplinary
Huihui Yang, Lili Wang, Heyan Wang, Yilei Zhang, Zhen Su, Ziyi Su, Jia Zhang, Zhengang Lu, Dechang Jia, PingAn Hu
Summary: The authors have successfully developed a flexible transparent EMI film with ultrahigh electromagnetic shielding effectiveness using large-area single crystal graphene, which surpasses the performance of other known materials.
ADVANCED MATERIALS TECHNOLOGIES
(2022)
Article
Chemistry, Multidisciplinary
Xuxuan Yang, Xin Liu, Lihang Qu, Feng Gao, Yi Xu, Mengqi Cui, Huan Yu, Yunxia Wang, PingAn Hu, Wei Feng
Summary: This study demonstrates high-performance self-powered photoelectrochemical (PEC) photodetectors based on ultrathin InSe nanosheets. The electrical properties and photoresponse of the photodetectors are improved by annealing treatment. The self-powered PEC photodetectors show broadband photoresponse, high responsivity, fast response speed, and good stability under UV-NIR irradiation. The photoresponse can be effectively tuned by the concentration and kind of electrolyte.
Article
Chemistry, Multidisciplinary
Shichao Zhang, You Wu, Feng Gao, Huiming Shang, Jia Zhang, Zhonghua Li, YongQing Fu, PingAn Hu
Summary: This study presents a new strategy to improve the performance of 2D material-based devices by combining metallic and semiconducting polymorphs of transition-metal dichalcogenides. The phase engineering method successfully achieves heterophase-based FETs with low contact resistance, which are used for detecting NH3 gas concentration.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Physical
Huiming Shang, Feng Gao, Mingjin Dai, YunXia Hu, Shuai Wang, Bo Xu, Peng Wang, Bo Gao, Jia Zhang, PingAn Hu
Summary: A self-powered photodetector with light-induced electric field enhancement based on a 2D InSe/WSe2/SnS2 van der Waals heterojunction is designed, which achieves high responsivity and fast response speed by utilizing the light-induced electric field.
Article
Chemistry, Multidisciplinary
Hongying Yang, Yunxia Hu, Xin Zhang, Yanan Ding, Shuai Wang, Zhen Su, Yong Shuai, Pingan Hu
Summary: A two-terminal NIR synaptic device based on a multilayer MoSe2 moiré superlattice is reported in this study, demonstrating strong sensing and storage functions similar to the human visual system. The interlayer coupling of multilayer MoSe2 is significantly enhanced by the moiré structure, enabling NIR light response and absorption. This research opens up new possibilities for the realization of NIR artificial retina and bionic eye based on 2D materials.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Proceedings Paper
Energy & Fuels
Shaoge Zang, Christina Kexin Yuan, Connor James, Aiguo Patrick Hu
Summary: This paper introduces a modular-based solar PV system with the integration of a capacitive power transfer (CPT) interface, allowing for multiple modules to be connected in series. A centralised Maximum Power Point Tracking (MPPT) controller coordinates the control of multiple PV modules, improving the system's power transfer capability.
2021 IEEE PELS WORKSHOP ON EMERGING TECHNOLOGIES: WIRELESS POWER TRANSFER (WOW 2021)
(2021)
Review
Biochemical Research Methods
Yong-Qing Fu, Hua-Feng Pang, Hamdi Torun, Ran Tao, Glen McHale, Julien Reboud, Kai Tao, Jian Zhou, Jingting Luo, Desmond Gibson, Jikui Luo, PingAn Hu
Summary: Different acoustic wave modes are required for effective biosensing and liquid actuation functions in an acoustic wave-based lab-on-a-chip. The paper discusses the challenges and theoretical constraints in generating various wave modes in the inclined films and techniques to efficiently produce inclined columnar and inclined crystalline piezoelectric films. Applications of different wave modes in the inclined film-based lab-on-chips with multiple sensing and acoustofluidic functions are also presented.
Article
Chemistry, Inorganic & Nuclear
Vaibhav Bedi, Dipendu Mandal, Zahid Hussain, Shi-Ming Chen, Yile Wu, Zheng-Wang Qu, Stefan Grimme, Douglas W. Stephan
Summary: The reaction of (tBuO(2)CN)(2) with 9-BBN leads to the formation of a bicyclic heterocyclic compound, while its reactions with BF3 or [Et3Si][B(C6F5)(4)] result in the isolation of different compounds. Computational studies reveal that the steric and electronic properties of the Lewis acid are important in the formation of one of the compounds.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chisa Itoh, Haruka Yoshino, Taku Kitayama, Wataru Kosaka, Hitoshi Miyasaka
Summary: A new synthetic route for constructing functional paddlewheel diruthenium(II,II) complexes was developed, utilizing Schiff base condensation reactions. The attached Schiff base groups significantly affected the electronic states of the resulting complexes, as revealed by cyclic voltammetry and DFT calculations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Danrui Ni, Haozhe Wang, Xianghan Xu, Weiwei Xie, Robert J. Cava
Summary: A layered rhombohedral polymorph of indium(iii) triiodide is synthesized at high pressure and temperature. It has an orange color, which is different from ambient pressure InI3, which has a monoclinic molecular structure and a light-yellow color.
DALTON TRANSACTIONS
(2024)
Review
Chemistry, Inorganic & Nuclear
Juan Carlos Perez-Sanchez, Raquel P. Herrera, M. Concepcion Gimeno
Summary: Gold(II) complexes have been less utilized in catalysis compared to their gold(I) and gold(III) counterparts. However, gold(II) complexes offer potential in homo-coupling and cross-coupling reactions, as they are more easily accessible through simplified oxidation and reduction processes. Gold(II) exhibits characteristics of both soft acid gold(I) and hard acid gold(III). This review explores the unique reactivity and potential applications of gold(II) species, highlighting their significance in catalytic transformations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Nighat Yousuf, Yanping Ma, Qaiser Mahmood, Wenjuan Zhang, Yizhou Wang, Hassan Saeed, Wen-Hua Sun
Summary: In this study, a series of structurally rigid cyclooctyl-fused iminopyridine iron complexes were synthesized and used with methylaluminoxane for isoprene polymerization. The extent of steric hindrance of the ligand framework was found to significantly affect catalytic performance, with less hindrance leading to better activity and stability.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chenghao Song, Huiwei Du, Menglei Xu, Jie Yang, Xinyu Zhang, Jungan Wang, Yuanfang Zhang, Chengjun Gu, Rui Li, Tao Hong, Jingji Zhang, Jiangying Wang, Yongchun Ye
Summary: This study improves the performance of perovskite solar cells by using a dual-hole transport layer strategy. This strategy enhances the charge transfer efficiency of the transport layer, reduces charge recombination, and improves the quality of the perovskite film layer. Ultimately, the stability of the device is enhanced.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mahender Singh, Aakash Yadav, Ranjit Singh, Chullikkattil P. Pradeep
Summary: A new aryl selenonium polyoxometalate hybrid was developed and compared with an aryl sulfonium polyoxometalate hybrid in terms of their photocatalytic properties. It was found that the aryl selenonium hybrid exhibited better catalytic performance, which could be attributed to the larger atomic radii of selenium stabilizing the photogenerated electron-hole pair more efficiently. Additionally, the generation of elemental selenium through cleavage of C-Se bonds during catalysis was observed.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Yuhan Xie, Boyu Dong, Xuemin Wang, Siyuan Wang, Jinxi Chen, Yongbing Lou
Summary: This study successfully fabricated visible-light-responsive three-dimensional core-shell CoSe2/ZnIn2S4 heterostructures and achieved attractive activity in photocatalytic hydrogen evolution. The presence of CoSe2 improved light absorption and accelerated charge transfer kinetics. The strong interaction between CoSe2 and ZnIn2S4 reduced charge recombination, further enhancing photocatalytic activity for hydrogen evolution.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Andre L. de O. Batista, Joao Marcos T. Palheta, Mauricio J. Piotrowski, Celso R. C. Rego, Diego Guedes-Sobrinho, Alexandre C. Dias
Summary: This study presents a simulation protocol that provides a solid foundation for exploring two-dimensional materials. Using the TiBr2 2H monolayer as an example, the study reveals its promising properties for optoelectronic and valleytronic applications, including its stability, spin-orbit coupling effects, and optical helicity selection rule.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Jiang Jiang, Zi-Wei Li, Zhi-Zhuan Zhang, Bin Tan, Zhao-Feng Wu, Xiao-Ying Huang
Summary: In this work, two metal organic frameworks (MOFs) containing {Cu2I2} clusters, Eu-CuI-INA and Sr-K-CuI-INA, were synthesized and characterized. Both materials have a three-dimensional structure with {Cu2I2} clusters coordinated by INA(-) ligands and Eu3+ or Sr2+ ions. The Sr-K-CuI-INA material exhibited sensitive fluorescence sensing behaviors towards cysteine and nitro-bearing molecules, showing potential applications in bio and explosive molecule sensing. This work provides a good reference for designing fluorescent MOF probes containing CuI molecules.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhiya Lin, Jiasheng Wu, Qianwen Ye, Yulong Chen, Hai Jia, Xiaohui Huang, Shaoming Ying
Summary: Na-ion batteries (NIBs) have attracted great interest as a potential technology for grid-scale energy storage due to the wide distribution, low cost, and environmental friendliness of sodium resources. However, their implementation is hindered by low rate capability and cycling stability caused by the large ionic size of Na+. In this study, a three-dimensional nanoarchitectured coral-like CoSe2@N-doped carbon (CL-CoSe2@NC) was synthesized, and it exhibited improved sodium storage properties with better electrode kinetics and a stable SEI film.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Ya-Qiong Zhang, Yu Zhang, Guoping Zeng, Rong-Zhen Liao, Man Li
Summary: The mechanism and selectivity of CO2 reduction under visible light were investigated using density functional calculations. The results showed that a tetradentate PNNP-type Iridium(III) complex exhibited high activity and selectivity in the reaction.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Sanyukta Ghosh, Shubhanth Jain, Soumya Ranjan Mishra, Gerda Rogl, Peter Rogl, Ernst Bauer, B. S. Murty, A. Govindaraj, Ramesh Chandra Mallik
Summary: In this study, reduced graphene oxide (rGO) was uniformly dispersed in the In0.5Co4Sb12 bulk material by ultrasonication, which effectively reduced the lattice thermal conductivity and improved the thermoelectric efficiency.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mika Takeuchi, Yutaka Amao
Summary: This study developed an effective visible-light driven system for fumaric acid production using renewable resources such as biomass derivatives, providing an alternative to the current petroleum-based synthesis methods.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Juan Jian, Meiting Wang, Zhuo Wang, Jingwen Meng, Yuqin Yang, Limin Chang
Summary: Developing low-cost and self-supported bifunctional catalysts is crucial for highly efficient water splitting devices. In this study, nano-NiFe2O4 was directly grown onto iron foil surface and Sn4+ was introduced into the NiFe2O4. The resulting Sn-NiFe2O4/IF showed low overpotentials and high current densities during oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), making it a promising catalyst for large-scale hydrogen production.
DALTON TRANSACTIONS
(2024)