4.7 Article

Effect of Al2O3/SiO2 ratio on ye'elimite production on CSA cement

Journal

CONSTRUCTION AND BUILDING MATERIALS
Volume 168, Issue -, Pages 512-521

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.conbuildmat.2018.02.153

Keywords

CSA cement; Al2O3/SiO2 ratio; Gehlenite; Ye'elimite; Ye'elimite polymorphs

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Many raw materials have not been considered for the production of CSA cement due to their SiO2 content, which affects both the formation and composition of the crystalline phases of the CSA cement, competing for the available aluminum and calcium, thus affecting the ye'elimite content and the performace of CSA cement as well. This work analyzes the effects of the Al2O3/SiO2 (A/S) ratio on the mechanical properties of a series of formulations of CSA cements evaluated at two different temperatures (1250 and 1300 degrees C). In these formulations a limit of chemical composition was determined to reach percentages of ye'elimite that allow to produce a CSA cement with good performance, taking advantage of available raw materials in high ratios in the nature. Among the most relevant findings, the determination of the minimum and maximum limits in the ASS ratio in order to maximize the ye'elimite content, is highlighted. In addition, correlations between the higher strengths and shorter setting time and higher hydration heat fluxes with the greatest ye'elimite content, were determined. Both the effect of the ratio of ye'elimite polymorphs present on the cement and the effect of the greater A/S ratio on the fluid and hardening performance of CSA cement were identified. (C) 2018 Elsevier Ltd. All rights reserved.

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