4.7 Article

X-ray diffraction analysis of lactose crystallization in freeze-dried lactose-whey protein systems

Journal

FOOD RESEARCH INTERNATIONAL
Volume 67, Issue -, Pages 1-11

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.foodres.2014.10.023

Keywords

Crystallization; Protein inhibition; Crystallization kinetics; Glass transition; XRD patterns

Funding

  1. China Scholarship Council (CSC) [201306780016]

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Water sorption, time-dependent crystallization and XRD patterns of lactose and lactose-WPI mixtures were studied with glass transition data. The results indicated that the sorbed water of lactose-WPI mixtures was fractional and water content of individual amorphous components in lactose-WPI mixtures at each a(w) from 25 degrees C to 45 degrees C could be calculated. Crystallization occurred in pure lactose whereas partial crystallization was typical of lactose-WPI mixtures (protein content <= 50%) at intermediate and high a(w) (>0.44 a(w)) from 25 degrees C to 45 degrees C. The extents of crystallization were significantly delayed by WPI. The T-g values of lactose-WPI systems showed the composition-dependent property in systems and might indicate the occurrence of phase separation phenomena during 240 h storage. XRD showed no anhydrous beta-lactose and mixed alpha-/beta-lactose with molar ratios of 4:1 crystals in crystallized lactose-WPI systems (70:30 and 50:50 solids ratios). Reduced crystallization in the presence of WPI was more pronounced possibly because of reduced nucleation and diffusion during crystalgrowth. The present study showed that WPI could present an important role in preventing sugar crystallization. (C) 2014 Elsevier Ltd. All rights reserved.

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